Abstract
Monitoring and removing the hazardous gases (such as radioactive gases and hydrogen) in the nuclear islands are full with enormous challenges, although the two methods can improve the safety level of the nuclear power plant. Due to its excellent electronic and chemical properties, two dimensional materials are considered as the candidate for monitoring and removing the hazardous gases in the nuclear islands. In this paper, the adsorption of the hazardous gases on monolayer \(\text {MoS}_2\) sheet was investigated by using the first principles calculation method. The adsorption energy, total charge transfer, and density of states (DOS) were calculated to understand the adsorption mechanism and sensing performance of the monolayer \(\text {MoS}_2\) sheet to the hazardous gases. The results show that an attractive interaction exists between the hazardous gases and the monolayer \(\text {MoS}_2\) sheet. The magnitude of the adsorption energy demonstrates that physisorption dominates the adsorption of the hazardous gas molecules on the monolayer \(\text {MoS}_2\) sheet, but the adsorption of the dissociated H/I atom belongs to chemisorption. The DOS shows that the orbitals, H 1s and I 5p, play a crucial role in the adsorption, and the change of the electronic structure indicates that the monolayer \(\text {MoS}_2\) sheet might be a promising material which is used for monitoring the gaseous radioactive iodine in the nuclear islands.
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Adamyan, A.Z., Adamyan, Z.N., Aroutiounian, V.M., Arakelyan, A.H., Touryan, K.J., Turner, J.A.: Sol-gel derived thin-film semiconductor hydrogen gas sensor. Int. J. Hydrog. Energy 32(16), 4101 (2007). https://doi.org/10.1016/j.ijhydene.2007.03.043
Aghagoli, M.J., Shemirani, F.: Hybrid nanosheets composed of molybdenum disulfide and reduced graphene oxide for enhanced solid phase extraction of Pb(II) and Ni(II). Microchim. Acta 184(1), 237 (2017). https://doi.org/10.1007/s00604-016-2000-7
Ai, Y.J., Liu, Y., Lan, W.Y., Jin, J.R., Xing, J.L., Zou, Y.D., Zhao, C.F., Wang, X.K.: The effect of pH on the U(VI) sorption on graphene oxide (GO): a theoretical study. Chem. Eng. J. 343, 460 (2018). https://doi.org/10.1016/j.cej.2018.03.027
Akhmat, G., Zaman, K., Shukui, T., Sajjad, F., Khan, M.A., Khan, M.Z.: The challenges of reducing greenhouse gas emissions and air pollution through energy sources: evidence from a panel of developed countries. Environ. Sci. Pollut. Res. 21(12), 7425 (2014). https://doi.org/10.1007/s11356-014-2693-2
Ataca, C., Ciraci, S.: Functionalization of Single-Layer \(\text{ MoS }_2\) honeycomb structures. J. Phys. Chem. C 115(27), 13303 (2010). https://doi.org/10.1021/jp2000442
Böker, T., Severin, R., Müller, A., Janowitz, C., Manzke, R., Voß, D., Krüger, P., Mazur, A., Pollmann, J.: Band structure of \(\text{MoS}_2\), \(\text{MoSe}_2\), and alpha-\(\text{MoTe}_2\): angle-resolved photoelectron spectroscopy and ab-initio calculations. Phys. Rev. B 64(23), 235305 (2001). https://doi.org/10.1103/PhysRevB.64.235305
Brosi, A.R., Dewitt, T.W., Zeldes, H.: Decay of 8-day iodine131 to a metastable state of Xenon131. Phys. Rev. 75, 1615 (1949). https://doi.org/10.1103/PhysRev.75.1615.2
Burke, K., Perdew, J.P., Wang, Y.: Derivation of a generalized gradient approximation: the PW91 density functional. In: Dobson, J.F., Vignale, G., Das, M.P. (eds.) Electronic Density Functional Theory, pp. 88–111. Springer, Boston (1998). https://doi.org/10.1007/978-1-4899-0316-7-7
Butler, M.A.: Optical fiber hydrogen sensor. Appl. Phys. Lett. 45(10), 1007 (1984). https://doi.org/10.1063/1.95060
Calaprice, F.P., Happer, W., Schreiber, D.F., Lowry, M.M., Miron, E., Zeng, X.: Nuclear alignment and magnetic moments of \(\text{ Xe }^{133}\), \(\text{ Xe }^{133m}\), and \(\text{ Xe }^{131m}\) by spin exchange with optically pumped \(\text{ Rb }^{87}\). Phys. Rev. Lett 54(3), 174 (1985). https://doi.org/10.1103/PhysRevLett.54.174
Cao, R., Zhou, B., Jia, C., Zhang, X., Jiang, Z.: Theoretical study of the NO, \(\text{ NO }_2\), CO, \(\text{ SO }_2\), and \(\text{ NH }_3\) adsorptions on multi-diameter single-wall \(\text{ MoS }_2\) nanotube. J. Phys. D Appl. Phys. 49(4), 045106 (2016). https://doi.org/10.1088/0022-3727/49/4/045106
Cao, J., Zhou, J., Zhang, Y., Liu, X.: Theoretical study of \(\text{ H }_2\) adsorbed on monolayer \(\text{ MoS }_2\) doped with N, Si, P. Microelectron. Eng. 190, 63 (2018). https://doi.org/10.1016/j.mee.2018.01.012
Chen, D., Zhang, X., Tang, J., Cui, H., Li, Y.: Noble metal (Pt or Au)-doped monolayer \(\text{ MoS }_2\) as a promising adsorbent and gas-sensing material to \(\text{ SO }_2\), \(\text{ SOF }_2\), and \(\text{ SO }_2\text{ F }_2\): a DFT study. Appl. Phys. A 124(2), 194 (2018). https://doi.org/10.1007/s00339-018-1629-y
Cho, S.Y., Kim, S.J., Lee, Y., Kim, J.S., Jung, W.B., Yoo, H.W., Kim, J., Jung, H.T.: Highly enhanced gas adsorption properties in vertically aligned \(\text{ MoS }_2\) layers. ACS Nano 9(9), 9314 (2015). https://doi.org/10.1021/acsnano.5b04504
Clark, S.J., Segall, M.D., Pickard, C.J., Hasnip, P.J., Probert, M.I.J., Refson, K., Payne, M.C.: First principles methods using CASTEP. Z. Kristallogr. 220(5/6), 567 (2005). https://doi.org/10.1524/zkri.220.5.567.65075
Corner, A., Dan, V., Spence, A., Poortinga, W., Demski, C., Pidgeon, N.: Nuclear power, climate change and energy security: exploring british public attitudes. Energy Policy 39(9), 4823 (2011). https://doi.org/10.1016/j.enpol.2011.06.037
Ding, K., Lin, Y., Huang, M.: The enhancement of NO detection by doping strategies on monolayer \(\text{ MoS }_2\). Vacuum 130, 146 (2016). https://doi.org/10.1016/j.vacuum.2016.05.005
Du, Y., Wang, J., Zou, Y., Yao, W., Hou, J., Xia, L., Peng, A., Alsaedi, A., Hayat, T., Wang, X.: Synthesis of molybdenum disulfide/reduced graphene oxide composites for effective removal of Pb(II) from aqueous solutions. Sci. Bull. 62(13), 913 (2017). https://doi.org/10.1016/j.scib.2017.05.025
Elder, R., Allen, R.: Nuclear heat for hydrogen production coupling a very high/high temperature reactor to a hydrogen production plant. Prog. Nucl. Energy 51(3), 500 (2009)
Ewing, R.C.: Nuclear fuel cycle: environmental impact. MRS Bull. 33(4), 338 (2008). https://doi.org/10.1557/mrs2008.68
Ferreira, F., Carvalho, A., Moura, I.J., Coutinho, J., Ribeiro, R.: Adsorption of \(\text{ H }_2\), \(\text{ O }_2\), \(\text{ H }_2\)O, OH and H on monolayer \(\text{ MoS }_2\). J. Phys. Condens. Mat. 30(3), 035003 (2017). https://doi.org/10.1088/1361-648X/aaa03f
Goncharov, B.I., Kozyr, V.N., Nosovskii, A.V., Oskolkov, B.Y., Fomin, V.V., Ivanov, E.A.: Effective decrease of radioactive inert gas emissions from nuclear power plants with RBMK reactors. Atom Energy 79(4), 722 (1995). https://doi.org/10.1007/BF02415398
Hao, L., Liu, Y., Du, Y., Chen, Z., Han, Z., Xu, Z., Zhu, J.: Highly enhanced \(\text{ H }_2\) sensing performance of few-layer \(\text{ MoS }_2\)/\(\text{ SiO }_2\)/Si heterojunctions by surface decoration of Pd nanoparticles. Nanoscale Res. Lett. 12(1), 567 (2017). https://doi.org/10.1186/s11671-017-2335-y
Hao, L., Liu, Y., Gao, W., Liu, Y., Han, Z., Yu, L., Xue, Q., Zhu, J.: High hydrogen sensitivity of vertically standing layered \(\text{ MoS }_2\)/Si heterojunctions. J. Alloys Compd. 682, 29 (2014). https://doi.org/10.1016/j.jallcom.2016.04.277
Heck, R., Kelber, G., Schmidt, K., Zimmer, H.J.: Hydrogen reduction following severe accidents using the dual recombiner-igniter concept. Nucl. Eng. Des. 157(3), 311 (1995). https://doi.org/10.1016/0029-5493(95)01009-7
Hirshfeld, F.L.: Bonded-atom fragments for describing molecular charge densities. Theor. Chim. Acta 44(2), 129 (1977). https://doi.org/10.1007/BF00549096
Hohenberg, P., Kohn, W.: Inhomogeneous electron gas. Phys. Rev. 136(3), B864 (1964). https://doi.org/10.1103/PhysRev.136.B864
Kohn, W., Sham, L.J.: Self-consistent equations including exchange and correlation effects. Phys. Rev. 140(4A), A1133 (1965). https://doi.org/10.1103/PhysRev.140.A1133
Komesu, T., Le, D., Tanabe, I., Schwier, E.F., Kojima, Y., Zheng, M.T., Taguchi, K., Miyamoto, K., Okuda, T., Iwasawa, H., Shimada, K., Rahman, T.S., Dowben, P.A.: Adsorbate doping of \(\text{ MoS }_2\) and \(\text{ WSe }_2\): the influence of Na and CO. J. Phys. Condens. Mat. 29(28), 285501 (2017). https://doi.org/10.1088/1361-648X/aa7482
Kumar, A., Ahluwalia, P.K.: Electronic structure of transition metal dichalcogenides monolayers 1H-\(\text{ MX }_2\) (M = Mo, W; X = S, Se, Te) from ab-initio theory: new direct band gap semiconductors. Eur. Phys. J. B 85(6), 186 (2012). https://doi.org/10.1140/epjb/e2012-30070-x
Lauritsen, J.V., Kibsgaard, J., Helveg, S., Topsoe, H., Clausen, B.S., Laegsgaard, E., Besenbacher, F.: Size-dependent structure of \(\text{ MoS }_2\) nanocrystals. Nat. Nanotechnol. 2(1), 53 (2007). https://doi.org/10.1038/nnano.2006.171
Lebegue, S., Eriksson, O.: Electronic structure of two-dimensional crystals from ab-initio theory. Phys. Rev. B 79(11), 5409 (2009). https://doi.org/10.1103/PhysRevB.79.115409
Li, H., Chi, Z., Li, J.: Covalent bonding synthesis of magnetic graphene oxide nanocomposites for Cr(III) removal. Desalin. Water Treat. 52(10–12), 1937 (2014). https://doi.org/10.1080/19443994.2013.806224
Li, X.D., Fang, Y.M., Wu, S.Q., Zhu, Z.Z.: Adsorption of alkali, alkaline-earth, simple and 3d transition metal, and nonmetal atoms on monolayer \(\text{MoS}_2\). AIP Adv. 5(5), 057143 (2015). https://doi.org/10.1063/1.4921564
Li, H., Huang, M., Cao, G.: Markedly different adsorption behaviors of gas molecules on defective monolayer \(\text{ MoS }_2\): a first-principles study. Phys. Chem. Chem. Phys. 18(22), 15110 (2016). https://doi.org/10.1039/C6CP01362G
Li, K., Zhao, Y., Deng, J., He, C., Ding, S., Shi, W.: Adsorption of radioiodine on \(\text{Cu}_2\)O surfaces: a first-principles density functional study. Acta Phys. Chim. Sin. 32(9), 2264 (2016). https://doi.org/10.3866/PKU.WHXB201606141
Liu, Y., Hao, L., Gao, W., Wu, Z., Lin, Y., Li, G., Guo, W., Yu, L., Zeng, H., Zhu, J., Zhang, W.: Hydrogen gas sensing properties of \(\text{MoS}_2\)/Si heterojunction. Sens. Actuators B Chem. 211, 537 (2015). https://doi.org/10.1016/j.snb.2015.01.129
Liu, X., Li, L., Wei, Y., Zheng, Y., Xiao, Q., Feng, B.: Facile synthesis of boron- and nitride-doped \(\text{ MoS }_2\) nanosheets as fluorescent probes for the ultrafast, sensitive, and label-free detection of \(\text{ Hg }^{2+}\). Analyst 140(13), 4654 (2015). https://doi.org/10.1039/C5AN00641D
Liu, X., Wang, X., Li, J., Wang, X.: Ozonated graphene oxides as high efficient sorbents for Sr(II) and U(VI) removal from aqueous solutions. Sci. China Chem. 59(7), 869 (2016). https://doi.org/10.1007/s11426-016-5594-z
Liu, X., Xu, X.T., Sun, J., Alsaedi, A., Hayat, T., Li, J.X., Wang, X.K.: Insight into the impact of interaction between attapulgite and graphene oxide on the adsorption of U(VI). Chem. Eng. J. 343, 217 (2018). https://doi.org/10.1016/j.cej.2018.02.113
Lu, N., Guo, H., Li, L., Dai, J., Wang, L., Mei, W.N., Wu, X., Zeng, X.C.: \(\text{ MoS }_2\)/\(\text{ MX }_2\) heterobilayers: bandgap engineering via tensile strain or external electrical field. Nanoscale 6(5), 2879 (2014). https://doi.org/10.1039/c3nr06072a
Luo, H., Cao, Y.J., Zhou, J., Feng, J.M., Cao, J.M., Guo, H.: Adsorption of \(\text{ NO }_2\), \(\text{ NH }_3\) on monolayer \(\text{ MoS }_2\) doped with Al, Si, and P: a first-principles study. Chem. Phys. Lett. 643, 27 (2016). https://doi.org/10.1016/j.cplett.2015.10.077
Ma, D., Ju, W., Li, T., Zhang, X., He, C., Ma, B., Lu, Z., Yang, Z.: The adsorption of CO and NO on the \(\text{ MoS }_2\) monolayer doped with Au, Pt, Pd, or Ni: a first-principles study. Appl. Surf. Sci. 383, 98 (2016). https://doi.org/10.1016/j.apsusc.2016.04.171
Martin, L.P., Pham, A.Q., Glass, R.S.: Electrochemical hydrogen sensor for safety monitoring. Solid State Ionics 175(1-4), 527 (2003). https://doi.org/10.1016/j.ssi.2004.04.042
Matsui, K., Ujita, H., Tashimo, M.: Role of nuclear energy in environment, economy and energy issues of the 21st century green house gas emission constraint effects. Prog. Nucl. Energy 50(2–6), 97 (2008). https://doi.org/10.1016/j.pnucene.2007.10.010
Mellouki, A., George, C., Chai, F., Mu, Y., Chen, J., Li, H.: Sources, chemistry, impacts and regulations of complex air pollution: preface. J. Environ. Sci. 40(2), 1 (2016). https://doi.org/10.1016/j.jes.2015.11.002
Menyah, K., Wolde-Rufael, Y.: CO2 emissions, nuclear energy, renewable energy and economic growth in the US. Energy Policy 38(6), 2911 (2010). https://doi.org/10.1016/j.enpol.2010.01.024
Mu, X.L., Gao, X., Zhao, H.T., George, M., Wu, T., Zhejiang, J.: Density functional theory study of the adsorptionof elemental mercury on a 1T-\(\text{ MoS }_2\) monolayer. Univ. Sci. A 19(1), 60 (2018). https://doi.org/10.1631/jzus.A1700079
Nikiforov, A.S., Zhikharev, M.I., Zemlyanukhin, V.I., Kulichenko, V.V., Nakhutin, I.E., Polyakov, A.S., Rakov, N.A.: Handling radioactive wastes from nuclear power plants and reprocessing spent nuclear fuel. Sov. At. Energy 50(2), 116 (1981). https://doi.org/10.1007/BF01121166
Ogata, Y., Yamasaki, T., Hanafusa, R.: High sensitive airborne radioiodine monitor. Appl. Radiat. Isot. 81(11), 119 (2013). https://doi.org/10.1016/j.apradiso.2013.03.067
Pei, H., Wang, J., Yang, Q., Yang, W., Hu, N., Suo, Y., Zhang, D., Li, Z., Wang, J.: Interfacial growth of nitrogen-doped carbon with multi-functional groups on the \(\text{ MoS }_2\)skeleton for efficient Pb(II) removal. Sci. Total Environ. 631–632, 912 (2018). https://doi.org/10.1016/j.scitotenv.2018.02.324
Perdew, J.P., Burke, K., Ernzerhof, M.: Generalized gradient approximation made simple. Phy. Rev. Lett. 77(18), 3865 (1996). https://doi.org/10.1103/physrevlett.77.3865
Perdew, J.P., Yue, W.: Accurate and simple density functional for the electronic exchange energy: generalized gradient approximation. Phys. Rev. B 33(12), 8800 (1986). https://doi.org/10.1103/physrevb.33.8800
Pfrommer, B.G., Cote, M., Louie, S.G., Cohen, M.L.: Relaxation of crystals with the quasi-Newton method. J. Comput. Phys. 131, 233 (1997). https://doi.org/10.1006/jcph.1996.5612
Pick, M.A., Sonnenberg, K.: A model for atomic hydrogen-metal interactions-application to recycling, recombination and permeation. J. Nucl. Mater. 131(2), 208 (1985). https://doi.org/10.1016/0022-3115(85)90459-3
Rothwell, E.: The release of \(\text{ Kr }^{85}\) from irradiated uranium dioxide on post-irradiation annealing. J. Nucl. Mater. 5(2), 241 (1962). https://doi.org/10.1016/0022-3115(62)90105-8
Rudenko, A.N., Keil, F.J., Katsnelson, M.I., Lichtenstein, A.I.: Adsorption of diatomic halogen molecules on graphene: a van der Waals density functional study. Phys. Rev. B 82(3), 035427 (2010). https://doi.org/10.1103/PhysRevB.82.035427
Saha, N., Sarkar, A., Ghosh, A.B., Mondal, P., Satra, J., Adhikary, B.: Advanced catalytic performance of amorphous \(\text{ MoS }_2\) for degradation/reduction of organic pollutants in both individual and simultaneous fashion. Ecotox. Environ. Safe. 160, 290 (2018). https://doi.org/10.1016/j.ecoenv.2018.05.023
Sakama, M., Nagano, Y., Kitade, T., Shikino, O., Nakayama, S.: Correlation between Asian dust and specific radioactivities of fission products included in airborne samples in Tokushima, Shikoku Island, Japan, due to the Fukushima nuclear accident. Nucl. Data Sheets 120(2), 250 (2014). https://doi.org/10.1016/j.nds.2014.07.059
Schweiger, L.: An effective technique for the storage of short lived radioactive gaseous waste. Appl. Radiat. Isot. 69(9), 1185 (2011). https://doi.org/10.1016/j.apradiso.2011.04.030
Shinohara, N., Yoshida-Ohuchi, H.: Radiocesium contamination in house dust within evacuation areas close to the Fukushima Daiichi nuclear power plant. Environ. Int. 114, 107 (2018). https://doi.org/10.1016/j.envint.2018.02.015
Singh, N., Jabbour, G., Schwingenschlögl, U.: Optical and photocatalytic properties of two-dimensional \(\text{ MoS }_2\). Eur. Phys. J. B 85(11), 392 (2012). https://doi.org/10.1140/epjb/e2012-30449-7
Splendiani, A., Sun, L., Zhang, Y., Li, T., Kim, J., Chim, C.Y., Galli, G., Wang, F.: Emerging photoluminescence in monolayer \(\text{ MoS }_2\). Nano Lett. 10(4), 1271 (2010). https://doi.org/10.1021/nl903868w
Subrahmanyam, K.S., Malliakas, C.D., Debajit, S., Armatas, G.S., Wu, J., Kanatzidis, M.G.: Ion-exchangeable molybdenum sulfide porous chalcogel: gas adsorption and capture of iodine and mercury. J. Am. Chem. Soc. 137(43), 13943 (2015). https://doi.org/10.1021/jacs.5b09110
Sun, Y., Wang, X., Song, W., Lu, S., Chen, C., Wang, X.: Mechanistic insights on the decontamination of Th(IV) on graphene oxide-based composites by EXAFS and modeling techniques. Environ. Sci. Nano 4(1), 222 (2016). https://doi.org/10.1039/c6en00470a
Tapper, D.N., Comar, C.L.: Extrathyroidal gamma dose form the intake of milicurie levels of iodine-131. Health Phys. 9(8), 817 (1963). https://doi.org/10.1097/00004032-196308000-00003
Tong, Y., Liu, Y., Zhao, Y., Daniel, T., Chan, S.H., Zhu, C.: Selectivity of \(\text{ MoS }_2\) gas sensors based on a time constant spectrum method. Sens. Actuators A 255, 28 (2017). https://doi.org/10.1016/j.sna.2016.12.024
Tristant, D., Puech, P., Gerber, I.C.: Theoretical study of graphene doping mechanism by iodine molecules. J. Phys. Chem. C 119(21), 150513144947007 (2015). https://doi.org/10.1021/acs.jpcc.5b03246
Wang, Y., Shang, X., Wang, X., Tong, J., Xu, J.: Density functional theory calculations of NO molecule adsorption on monolayer \(\text{ MoS }_2\) doped by Fe atom. Mod. Phys. Lett. B 29(27), 1550160 (2015). https://doi.org/10.1142/S0217984915501602
Wang, Y., Wang, B., Huang, R., Gao, B., Kong, F., Zhang, Q.: First-principles study of transition-metal atoms adsorption on \(\text{ MoS }_2\) monolayer. Phys. E 63(9), 276 (2014). https://doi.org/10.1016/j.physe.2014.06.017
Wang, H., Wen, F., Li, X., Gan, X., Yang, Y., Chen, P., Zhang, Y.: Cerium-doped \(\text{ MoS }_2\) nanostructures: efficient visible photocatalysis for Cr(VI) removal. Sep. Purif. Technol. 170, 190 (2016). https://doi.org/10.1016/j.seppur.2016.06.049
Wang, W., Yang, C., Bai, L., Li, M., Li, W.: First-principles study on the structural and electronic properties of monolayer \(\text{ MoS }_2\) with S-vacancy under uniaxial tensile strain. Nanomaterials 8(2), 74 (2018). https://doi.org/10.3390/nano8020074
Wei, H., Gui, Y., Kang, J., Wang, W.B., Tang, C.: A DFT study on the adsorption of \(\text{ H }_2\text{ S }\) and \(\text{ SO }_2\) on Ni doped \(\text{ MoS }_2\) monolayer. Nanomaterials 8(9), 646 (2018). https://doi.org/10.3390/nano8090646
Wu, D., Lou, Z., Wang, Y., Xu, T., Shi, Z., Xu, J., Tian, Y., Li, X.J.: Construction of \(\text{ MoS }_2\)/Si nanowire array heterojunction for ultrahigh-sensitivity gas sensor. Nanotechnology 28(43), 435503 (2017). https://doi.org/10.1088/1361-6528/aa89b5
Wu, P., Yin, N.Q., Li, P., Cheng, W.J., Huang, M.: The adsorption and diffusion behavior of noble metal adatoms (Pd, Pt, Cu, Ag and Au) on a \(\text{ MoS }_2\) monolayer: a first-principles study. Phys. Chem. Chem. Phys. 19(31), 20713 (2015). https://doi.org/10.1039/C7CP04021K
Xu, Z., Lv, X., Chen, J., Jiang, L., Lai, Y., Li, J.: First principles study of adsorption and oxidation mechanism of elemental mercury by HCl over \(\text{ MoS }_2\)(1 0 0) surface. Chem. Eng. J. 308, 1225 (2017). https://doi.org/10.1016/j.cej.2016.10.059
Yue, Q., Chang, S., Qin, S., Li, J.: Functionalization of monolayer \(\text{ MoS }_2\) by substitutional doping: a first-principles study. Phys. Lett. A 377(19–20), 1362 (2013). https://doi.org/10.1016/j.physleta.2013.03.034
Zhang, Y.H., Chen, J.L., Yue, L.J., Zhang, H.L., Li, F.: Tuning CO sensing properties and magnetism of \(\text{MoS}_2\) monolayer through anchoring transition metal dopants. Comput. Theor. Chem. 1104, 12 (2017). https://doi.org/10.1016/j.comptc.2017.01.026
Zhang, S.L., Yue, H., Liang, X., Yang, W.C.: Liquid-phase co-exfoliated graphene/\(\text{MoS}_2\) nanocomposite for methanol gas sensing. J. Nanosci. Nanotechnol. 15(10), 8004 (2015). https://doi.org/10.1166/jnn.2015.11254
Zhang, Z., Zhao, Q., Huang, M., Zhang, X., Ouyang, X.: Chemisorption of metallic radionuclides on a monolayer \(\text{ MoS }_2\) nanosheet. Nanoscale Adv. (2018). https://doi.org/10.1039/c8na00057
Zhao, G., Wen, T., Yang, X., Yang, S., Liao, J., Hu, J., Shao, D., Wang, X.: Preconcentration of U(VI) ions on few-layered graphene oxide nanosheets from aqueous solutions. Dalton Trans. 41(20), 6182 (2012). https://doi.org/10.1039/C2DT00054G
Zhao, Q., Zhang, Z., Ouyang, X.: Adsorption of radionuclides on the monolayer \(\text{ MoS }_2\). Mater. Res. Express 5, 045506 (2018). https://doi.org/10.1088/2053-1591/aaba90
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This work was supported by the Fundamental Research Funds for the Central Universities under Grant Nos. 2017MS079 and 2018ZD10, and the National Natural Science Foundation of China under Grant No. 11705059.
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Zhang, Z., Zhao, Q., Huang, M. et al. Adsorption of hazardous gases in nuclear islands on monolayer MoS2 sheet. Adsorption 25, 159–171 (2019). https://doi.org/10.1007/s10450-018-9999-1
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DOI: https://doi.org/10.1007/s10450-018-9999-1