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Enhanced catalytic activity of ternary NiCoPd nanocatalyst dispersed on carbon nanotubes toward methanol oxidation reaction in alkaline media

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Abstract

Ternary NiCoPd nanocatalyst dispersed on multi-walled carbon nanotubes (CNTs), NiCoPd/CNTs, was synthesized using a simple and green sonochemical method. The as-prepared NiCoPd/CNT hybrids were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma-atomic emission spectrometry (ICP-AES). The electrochemical measurements revealed that the ternary NiCoPd/CNTs exhibited an enhanced electrocatalytic activity for the methanol oxidation reaction (MOR), much superior to those of the binary NiPd/CNT and CoPd/CNT, as well as monometallic Pd/CNT counterparts, which likely resulted from the synergistic function of the dopant metals of Ni and Co.

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Acknowledgments

The work is supported by the Fundamental Research Funds for the Central Universities (nos. EG2015020, 2232014D3-11).

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Authors and Affiliations

  1. College of Chemistry, Chemical Engineering & Biotechnology, Donghua University, Shanghai, 201620, China

    Jia-Wei Zhang, Bei Zhang & Xuan Zhang

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  1. Jia-Wei Zhang
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  2. Bei Zhang
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  3. Xuan Zhang
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Correspondence to Xuan Zhang.

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Jia-Wei Zhang and Bei Zhang contributed equally.

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Zhang, JW., Zhang, B. & Zhang, X. Enhanced catalytic activity of ternary NiCoPd nanocatalyst dispersed on carbon nanotubes toward methanol oxidation reaction in alkaline media. J Solid State Electrochem 21, 447–453 (2017). https://doi.org/10.1007/s10008-016-3331-3

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  • DOI: https://doi.org/10.1007/s10008-016-3331-3

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