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Electrodeposition of Al, Zn, and Pt on silver-coated textile fibres from ionic liquids

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Abstract

In the present paper, we report on the electrodeposition of aluminium, zinc and platinum on silver-coated textile fibres from ionic liquids. For electrodeposition of Al, the 60:40 mol% mixture of AlCl3/1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) and 1.7 M AlCl3 in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide ([Py1,4]TFSA) were employed. It was observed that microcrystalline aluminium was electrodeposited on the textile fibres in 60:40 mol% AlCl3/[EMIm]Cl. The deposited Al layers either on single fibres or on textile assemblies are well adherent and uniform. An adherent, homogeneous and nanocrystalline Al layer was obtained on the silver-coated textile samples from 1.7 M AlCl3/[Py1,4]TFSA at 75 °C. The obtained Al layers from 60:40 mol% AlCl3/[EMIm]Cl on the textile fibres exhibit a good corrosion resistance in an aqueous iodide/iodine electrolyte. Furthermore, we obtain Al microtubes from the investigated ionic liquids after dissolving the textile fibres. In addition, zinc electrodeposition was carried out on the textile samples from 60:40 mol% ZnCl2/[EMIm]Cl at 80 °C. The electrodeposition of platinum on the textiles was done from 50 mM PtCl2 in 1-butyl-1-methylpyrrolidinium dicyanamide ([Py1,4]DCA).

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Authors and Affiliations

  1. Clausthal University of Technology, Clausthal-Zellerfeld, Germany

    Yasin Cengiz Celik, Giridhar Pulletikurthi & Frank Endres

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  1. Yasin Cengiz Celik
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  2. Giridhar Pulletikurthi
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  3. Frank Endres
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Correspondence to Frank Endres.

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Celik, Y.C., Pulletikurthi, G. & Endres, F. Electrodeposition of Al, Zn, and Pt on silver-coated textile fibres from ionic liquids. J Solid State Electrochem 20, 2781–2790 (2016). https://doi.org/10.1007/s10008-016-3276-6

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  • DOI: https://doi.org/10.1007/s10008-016-3276-6

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