Skip to main content
SpringerLink
Log in

Solid-contact Cu(II) ion-selective electrode based on 1,2-di-(o-salicylaldiminophenylthio)ethane

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

The development of Cu(II) solid-contact ion-selective electrodes, based on 1,2-di-(o-salicylaldiminophenylthio)ethane as a neutral carrier, is presented. For the electrodes construction, unmodified carbon ink (type 1 electrode) and polymer membrane-modified carbon ink (type 2 electrode) were used as solid support and transducer layer. Also, carbon ink composite polymer membrane electrode (type 3 electrode) was prepared. The analytical performance of the electrodes was evaluated with potentiometry, while bulk and interfacial electrode features were provided with electrochemical impedance spectroscopy. It is shown that modification of carbon ink with polymer membrane cocktail decreases the bulk contact resistance of the transducer layer and polymer membrane, thus enhancing the analytical performance of the electrode in terms of sensitivity, linear range, and stability of potential. The optimized electrodes of types 2 and 3 exhibit a wide linear range with detection limits of 1.8 × 10−6 and 1.6 × 10−6 M, respectively. They are suitable for determination of Cu2+ in analytical measurements by direct potentiometry and in potentiometric titrations, within pH between 2.3 and 6.5. The electrodes are selective for Cu2+ over a large number of tested transition and heavy metal ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Bakker E, Diamond D, Lewenstam A, Pretsch E (1999) Anal Chim Acta 391:11–18

    Article  Google Scholar 

  2. Pretsch E, Trends (2007) Anal Chem 26:46-51

  3. Cattrall RW, Freiser H (1971) Anal Chem 43:1905–1906

    Article  CAS  Google Scholar 

  4. Cattrall RW, Drew DW, Hamilton IC (1975) Anal Chim Acta 76:269–277

    Article  CAS  Google Scholar 

  5. Liu D, Meruva RK, Brown RB, Meyerhoff ME (1996) Anal Chim Acta 321:173–183

    Article  CAS  Google Scholar 

  6. Sutter J, Radu A, Peper S, Bakker E, Pretsch E (2004) Anal Chim Acta 523:53–59

    Article  CAS  Google Scholar 

  7. Pandey PC, Prakash R (1998) Sens Actuators B 46:61–65

    Article  Google Scholar 

  8. Lindfors T, Sjöberg P, Bobacka J, Lewenstam A, Ivaska A (1999) Anal Chim Acta 385:163–173

    Article  CAS  Google Scholar 

  9. Marques de Oliveira IA, Pla-Roca M, Escriche L, Casabó J, Zine N, Bausells J, Teixidor F, Crespo E, Errachid A, Samitier J (2006) Electrochim Acta 51:5070–5074

    Google Scholar 

  10. Zine N, Bausells J, Teixidor F, Viñas C, Masalles C, Samitier J, Errachid A (2006) Mat Sci Eng C 26:399–404

    Article  CAS  Google Scholar 

  11. Ocypa M, Michalska A, Maksymiuk K (2006) Electrochim Acta 51:2298–2305

    Article  CAS  Google Scholar 

  12. Gyurcsanyi RE, Rangisetty, Clifton N, Pendley BD, Lindner E (2004) Talanta 63:89-99

  13. Grygolowicz-Pawlak E, Plachecka K, Brzózka Z, Malinowska E (2007) Sens Actuators B 123:480–487

    Article  Google Scholar 

  14. Grygołowicz-Pawlak E, Wyglądacz K, Sęk S, Bilewicz R, Brzózka Z, Malinowska E (2005) Sens Actuators B 111:310–316

    Article  Google Scholar 

  15. Fibbioli M, Bandyopadhyay K, Liu SG, Echogoyen L, Enger O, Diederich F, Buhlmann P, Pretsch E (2000) Chem Commun 5:339–340

    Article  Google Scholar 

  16. Martínez-Barrachina S, Alonso J, Matia L, Prats R, del Valle M (2001) Talanta 54:811–820

    Article  Google Scholar 

  17. Isildak I (2000) Turk J Chem 24:389–394

    CAS  Google Scholar 

  18. Puig-Lleixà C, Jiménez C, Fàbregas E, Bartrolí J (1998) Sens Actuators B 49:211–217

    Article  Google Scholar 

  19. Górski L, Matusevich A, Pietrzak M, Wang L, Meyerhoff ME (2009) J Solid State Electroc 13:157–164

    Article  Google Scholar 

  20. Gismera MJ, Sevilla MT, Procopio JR (2007) Talanta 74:190–197

    Article  CAS  Google Scholar 

  21. Abbaspour A, Mirahmadi, Khalafi-Nezhad EA, Babamohammadi S (2010) J Hazard Mater 174:656–661

  22. Abbaspour A, Refahi M, Khalafi-Nezhad A, Soltani Rad N, Behrouz S (2010) J Hazard Mater 184:20–25

    Article  CAS  Google Scholar 

  23. Koncki R, Głąb S, Dziwulska J, Palchetti I, Mascini M (1999) Anal Chim Acta 385:451–459

    Article  CAS  Google Scholar 

  24. Mohamed GG, Ali TA, El-Shahat MF, Al-Sabagh AM, Migahed MA, Khaled E (2010) Anal Chim Acta 673:79–87

    Article  CAS  Google Scholar 

  25. Khaled E, Mohamed GG, Awad T (2008) Sens Actuators B 135:74–80

    Article  Google Scholar 

  26. Khaled E, Hassan HNA, Girgis A, Metelka R (2008) Talanta 77:737–743

    Article  CAS  Google Scholar 

  27. Veltsistas PG, Prodromidis MI, Efstathiou CE (2004) Anal Chim Acta 502:15–22

    Article  CAS  Google Scholar 

  28. Crespo GA, Macho S, Rius X (2008) Anal Chem 80:1316–1322

    Article  CAS  Google Scholar 

  29. Crespo GA, Macho S, Bobacka J, Rius X (2009) Anal Chem 81:676–681

    Article  CAS  Google Scholar 

  30. Ganjali MR, Khoshsafar H, Shirzadmehr A, Javanbakht M, Faridbod F (2009) Int J Electrochem Sci 4:435–443

    CAS  Google Scholar 

  31. Faridbod F, Ganjali MR, Larijani B, Norouzi P (2009) Electrochim Acta 55:234–239

    Article  CAS  Google Scholar 

  32. Khani H, Rofouei MK, Arab P, Gupta VK, Vafaei Z (2010) J Hazard Mater 183:402–409

    Article  CAS  Google Scholar 

  33. Peng B, Zhu J, Liu X, Qin Y (2008) Sens Actuators B 133:308–314

    Article  Google Scholar 

  34. Ganjali MR, Poursaberi T, Khoobi M, Shafiee A, Adibi M, Pirali-Hamedani M, Norouzi P (2011) Int J Electrochem Sci 6:717–726

    CAS  Google Scholar 

  35. Ganjali MR, Motakef-Kazami N, Faridbod F, Khoee S, Norouzi P (2010) J Hazard Mater 17:415–419

    Article  Google Scholar 

  36. Ahuja T, Kumar D, Singh N, Biradar AM, Rajesh (2010) Mat Sci Eng C 31(2011):90–94

    Google Scholar 

  37. Mashhadizadeh MH, Khani H (2010) Anal Methods 2:24–31

    Article  CAS  Google Scholar 

  38. Mashhadizadeh MH, Khani H, Foroumadi A, Sagharichi P (2005) Anal Chim Acta 665:208–214

    Article  Google Scholar 

  39. Mashhadizadeh MH, Khani H, Shochravi A (2010) J Incl Phenom Macrocycl Chem 68:219–227

    Article  CAS  Google Scholar 

  40. Mashhadizadeh MH, Eskandari K, Foroumadi A, Shafiee A (2008) Talanta 76:497–502

    Article  CAS  Google Scholar 

  41. Brinić S, Buzuk M, Generalić E, Bralić M (2010) Acta Chim Slov 57:318–324

    Google Scholar 

  42. Rajsekhar G, Rao CP, Saarenketo PK, Kolehmainen E, Rissanen K (2002) Inorg Chem Comm 5:649–652

    Article  CAS  Google Scholar 

  43. Buck RP, Lindner E (1994) Pure Appl Chem 66:2527–2536

    Article  CAS  Google Scholar 

  44. Buzuk M, Brinić S, Generalić E, Bralić M (2009) Croat Chem Acta 82:801–806

    CAS  Google Scholar 

  45. Marco R, Jee E, Prince K, Pretsch E, Bakker E (2009) J Solid State Electrochem 13:137–148

    Article  CAS  Google Scholar 

  46. Marco R, Veder JP, Clarke G, Nelson A, Prince K, Pretsch E, Bakker E (2008) Phys Chem Chem Phys 10:73–76

    Article  Google Scholar 

  47. Chester RT (2007) Thesis, Curtin University of Technology, Perth, Australia

  48. Horvai G, Graf E, Toth K, Pungor E, Buck RP (1986) Anal Chem 58:2735–2740

    Article  CAS  Google Scholar 

  49. Lindner E, Umezawa Y (2008) Pure Appl Chem 80:85–104

    Article  CAS  Google Scholar 

  50. Krzewska S (1997) Electrochim Acta 42:3531–3540

    Article  CAS  Google Scholar 

  51. Umezawa Y, Bühlmann P, Umezawa K, Tohda K, Amemiya S (2000) Pure Appl Chem 2:1851–2082

    Article  Google Scholar 

  52. Shamsipur M, Javanbakht M, Mousavi MF, Ganjali MR, Lippolis V, Garau A, Tei L (2001) Talanta 55:1047–1054

    Article  CAS  Google Scholar 

  53. Abbaspour A, Moosavi SMM (2002) Talanta 56:91–96

    Article  CAS  Google Scholar 

  54. Ganjali MR, Poursaberi T, Haji-agha Babaei L, Rouhani S, Yousefi M, Kargar-Razi M, Moghimid A, Aghabozorg H, Shamsipur M (2001) Anal Chim Acta 440:81–87

    Article  CAS  Google Scholar 

  55. Firooz AR, Mazloum M, Safari J, Amini MK (2002) Anal Bioanal Chem 372:718–722

    Article  CAS  Google Scholar 

  56. Ardakani MM, Mirhoseini SH, Salavati-Niasari M (2006) Acta Chim Slov 53:197–203

    CAS  Google Scholar 

  57. Shokrollahi A, Abbaspour A, Ghaedi M, Naghashian Haghighi A, Kianfar AH, Ranjbar M (2011) Talanta 84:34–41

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of General and Inorganic Chemistry, Faculty of Chemistry and Technology, University of Split, Teslina 10/V, 21000, Split, Croatia

    Slobodan Brinić, Marijo Buzuk, Marija Bralić & Eni Generalić

Authors
  1. Slobodan Brinić
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Marijo Buzuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Marija Bralić
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Eni Generalić
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Slobodan Brinić.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Brinić, S., Buzuk, M., Bralić, M. et al. Solid-contact Cu(II) ion-selective electrode based on 1,2-di-(o-salicylaldiminophenylthio)ethane. J Solid State Electrochem 16, 1333–1341 (2012). https://doi.org/10.1007/s10008-011-1528-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-011-1528-z

Keywords

Search

Navigation