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In Search of Stable, High-Spin Polymers

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Abstract

Oligomers of poly(thiophene) and poly(ortho-phenyleneethynylene) having pendant S = 1/2 semiquinone radicals (as complexes of cobalt(III)) have been prepared and characterized by electron paramagnetic resonance (EPR) spectroscopy and magnetic measurements (superconducting quantum interferences device = SQUID magnetometry). Our results show that exchange coupling of semiquinone groups along a polythiophene backbone is greater than the corresponding coupling along a poly(ortho-phenyleneethynylene) backbone.

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Funding

DAS acknowledges financial support from NSF (CHE-1931291 and CHE-1764181).

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Authors and Affiliations

  1. Department of Chemistry, North Carolina State University, Raleigh, NC, 27695-8204, USA

    Patrick Hewitt & David A. Shultz

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  1. Patrick Hewitt
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  2. David A. Shultz
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PH and DAS wrote the manuscript. PH prepared and characterized all molecules and polymers.

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Correspondence to David A. Shultz.

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Hewitt, P., Shultz, D.A. In Search of Stable, High-Spin Polymers. Appl Magn Reson 51, 1331–1341 (2020). https://doi.org/10.1007/s00723-020-01293-z

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