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NMR Investigations of the Catalyst–Monomer Interaction and Stereochemistry of the Product in Catalytic Polymerization of 2-Hydroxyethyl Methacrylate

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Abstract

Nuclear magnetic resonance (NMR) spectroscopy has been used to study the structure of the product and possible intermediates in the polymerization of 2-hydroxyethyl methacrylate catalyzed by the oxovanadium (IV) complex. The assumption of the coordination nature of the polymerization is confirmed by noncovalent interactions between monomer and the catalyst, which has been examined by NMR on 1H, 13C, and 17O nuclei. The catalyst affects remarkably the stereospecificity of the reaction. The resulting polymer with high molecular weight Mn ≈ 200,000 has a predominantly syndiotactic structure; the chain growth is satisfactorily described by the first-order Markov model with the statistical parameters Pr/m = 0.156 and Pm/r = 0.857.

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References

  1. K.-H. Hsieh, T.-H. Young, in Polymeric Materials Encyclopedia, vol. 5, ed. by J.C. Salamon (CRC Press, Boca Raton, 1996), p. 3087

    Google Scholar 

  2. K.L. Beers, S. Boo, S.G. Gaynor, K. Matyjaszewski, Macromolecules 32, 5772 (1999)

    Article  ADS  Google Scholar 

  3. J.K. Oh, K. Matyjaszewski, J. Polym. Sci. Part A Polym. Chem. 44, 3787 (2006)

    Article  ADS  Google Scholar 

  4. S.M. Paterson, D.H. Brown, T.V. Chirila, I. Keen, A.K. Whittaker, M.V. Baker, J. Polym. Sci. Part A Polym. Chem. 48, 4084 (2010)

    Article  ADS  Google Scholar 

  5. N.H. Nguyen, X. Leng, V. Percec, Polym. Chem. 4, 2760 (2013)

    Article  Google Scholar 

  6. S.N. Kholuiskaya, V.V. Minin, A.A. Gridnev, in Applied Chemistry and Chemical Engineering, ed. by A.K. Haghi, D. Balköse, O.V. Mukbaniani, A.G. Mercader (Apple Acad. Press Inc., Toronto, 2018), p. 299 (ISBN: 978-1-77188-515-7)

    Google Scholar 

  7. K. Hatada, T. Kitayama,  in NMR Spectroscopy of Polymers (Springer, Berlin, 2004), p. 228

    Book  Google Scholar 

  8. F.A. Bovey, in High Resolution NMR of Macromolecules (Academic Press, New York, 1972), p. 466

    Google Scholar 

  9. R. Chujo, K. Hatada, R. Kitamaru, T. Kitayama, H. Sato, Y. Tanaka, Polym. J. 19, 413 (1987)

    Article  Google Scholar 

  10. Y. Isobe, T. Nakano, Y. Okamoto, J. Polym. Sci. Part A Polym. Chem. 39, 1463 (2001)

    Article  ADS  Google Scholar 

  11. J. Selbin, L.H. Holmes, J. Inorg. Nucl. Chem. 24, 1111 (1962)

    Article  Google Scholar 

  12. O.W. Webster, Adv. Polym. Sci. 167, 1 (2004)

    Google Scholar 

  13. S.E. Denmark, J. Fu, Chem. Rev. 103, 2763 (2003)

    Article  Google Scholar 

  14. I. Goni, M. Gurruchaga, M. Valero, G.M. Guzman, Polymer 33, 3089 (1992)

    Article  Google Scholar 

  15. Y. Miura, T. Shibata, K. Satoh, M. Komigaita, Y. Okamoto, J. Am. Chem. Soc. 128, 16026 (2006)

    Article  Google Scholar 

  16. T. Shibata, K. Satoh, M. Komigaita, Y. Okamoto, J. Polym. Sci. Part A Polym. Chem. 44, 3609 (2006)

    Article  ADS  Google Scholar 

  17. Y. Fuji, K. Watanabe, K.-Y. Baek, T. Ando, M. Kamigaito, M. Sawamoto, J. Polym. Sci. Part A Polym. Chem. 40, 2055 (2002)

    Article  ADS  Google Scholar 

  18. J. San Roman, B. Levenfeld, Macromolecules 23, 3036 (1990)

    Article  ADS  Google Scholar 

  19. Y. Inoue, A. Nishioka, R. Chujo, Polym. J. 2, 535 (1971)

    Article  Google Scholar 

  20. S. Hooda, A.K. Goyal, Indian J. Chem. 46 A, 899 (2007)

    Google Scholar 

  21. T.G. Fox, H.W. Schnecko, Polymer 3, 575 (1963)

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Federal Agency of Science and Education of the Russian Federation (Theme V. 45.11, 0082-2014-0009, № AAAA-A17-117040610309-0).

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 Kosygina St, Moscow, 119991, Russia

    Svetlana Kholuiskaya

  2. N. M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 4 Kosygina St, Moscow, 119991, Russia

    Lidiya Kurkovskaya

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  1. Svetlana Kholuiskaya
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  2. Lidiya Kurkovskaya
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Correspondence to Svetlana Kholuiskaya.

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Kholuiskaya, S., Kurkovskaya, L. NMR Investigations of the Catalyst–Monomer Interaction and Stereochemistry of the Product in Catalytic Polymerization of 2-Hydroxyethyl Methacrylate. Appl Magn Reson 50, 63–72 (2019). https://doi.org/10.1007/s00723-018-1033-y

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  • DOI: https://doi.org/10.1007/s00723-018-1033-y

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