Skip to main content
SpringerLink
Log in

The Use of 1H NMR and PCA for Quality Assessment of Gasoline of Different Octane Number

  • Published:
Applied Magnetic Resonance Aims and scope Submit manuscript

Abstract

In this study, successful discrimination between two types of gasoline of different octane number (90 and 95) was achieved. 24 samples of each type of gasoline were collected and analyzed with 1H NMR and processed with PCA and kNN. Uncovering adulterated gasoline 95 samples with gasoline 90 of different composition ratios of gasoline 90 (2.5, 5, 10, 20)  % v/v have also been achieved by preparing 12 adulterated sample and applying the resulted 1H nuclear magnetic resonance (NMR) data to the original PCA model. The determination of adulteration composition was achieved using the 1H NMR spectra quantitatively through the least square linear regression analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2 
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. M.R. Monteiro, A. Ambrozin, L.M. Lião, L.A. Boffo, M.M. Tavares, F.A. Ferreira, Energy Fuels 23, 272–279 (2009)

    Article  Google Scholar 

  2. L.S.M. Wiedemann, L.A. d’Avila, D.A. Azevedo, Fuel 84, 467–473 (2005)

    Article  Google Scholar 

  3. P. Ghosh, K.J. Hickey, S.B. Jaffe, Ind. Eng. Chem. Res. 45, 337–345 (2006)

    Article  Google Scholar 

  4. P.P. Marcio, A.F.G. Luiz, C.F. Ernesto, J. Chromatogr. A 1201, 176–182 (2008)

    Article  Google Scholar 

  5. R. Sukhdev, Sensor. Actuator B 55, 212–216 (1999)

    Article  Google Scholar 

  6. F. Oliveira, L.S.G. Teixeira, M.C.U. Araujo, M. Korn, Fuel 83, 917–923 (2004)

    Article  Google Scholar 

  7. M.B. Roman, Z.S. Ravilya, I.L. Ekaterina, Microch. J. 98, 121–128 (2011)

    Article  Google Scholar 

  8. A.A. Mohammad, S.A. Yahya, A. Mohammad, Talanta 76, 1105–1112 (2008)

    Article  Google Scholar 

  9. S.G. Leonardo, Fuel 87, 346–352 (2008)

    Article  Google Scholar 

  10. M. Bassbasi, A. Hafid, S. Platikanov, R. Tauler, A. Oussama, Fuel 104, 798–804 (2013)

    Article  Google Scholar 

  11. V. Gaydou, J. Kister, N. Dupuy, Chemometr. Intell. Lab. 106, 190–197 (2011)

    Article  Google Scholar 

  12. F.C.C. Oliveira, C.R.R. Brandão, H.F. Ramalho, L.A.F. da Costa, P.A.Z. Suarez, J.C. Rubim, Anal. Chim. Acta 587, 194–199 (2007)

    Article  MATH  Google Scholar 

  13. P. Digambara, A.K. Mishra, Anal. Bioanal. Chem. 373, 304–309 (2002)

    Article  Google Scholar 

  14. K. Keshav, K.M. Ashok, J. Fluoresc. 22, 339–347 (2012)

    Article  Google Scholar 

  15. S. Obeidat, M. Al-Ktash, I. Al-Momani, Energy Fuels 28(8), 4889–4894 (2014)

    Article  MATH  Google Scholar 

  16. O. Divya, A. Mishra, Anal. Chim. Acta 592, 82–90 (2007)

    Article  ADS  Google Scholar 

  17. P. Digambara, S.K. Lakshmi, A.K. Mishra, Indian J. Chem A 40, 374–379 (2001)

    Google Scholar 

  18. P. Digambara, A.K. Mishra, Anal. Chim. Acta 454, 209–215 (2002)

    Article  Google Scholar 

  19. S.K. Bharti, R. Roy, Trend. Anal. Chem. 35, 5–26 (2012)

    Article  Google Scholar 

  20. N. Nakatani, S. Kayano, H. Kikuzaki, K. Sumino, K. Katagiri, T. Mitani, J. Agric. Food Chem. 48(11), 5512–5516 (2000)

    Article  Google Scholar 

  21. U. Holzgrabe, R. Deubner, R. Schollmayer, B. Waibel, J. Pharm. Biomed. Anal. 38(5), 806–812 (2005)

    Article  Google Scholar 

  22. B. Wise, N. Gallagher, S. Butler, D. White, G. Barna, J. Chemom. 13, 379–385 (1999)

    Article  Google Scholar 

  23. D. Anderson, G. Rayson, S. Obeidat, M. Ralphs, R. Estell, E. Fredrickson, E. Parker, Rangel. Ecol. Manage 59, 557–563 (2006)

    Article  Google Scholar 

  24. S. Obeidat, B. Al-Tayyem, Jordan J. Chem. 9(3), 158–168 (2014)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Yarmouk University, Irbid, Jordan

    Safwan M. Obeidat

Authors
  1. Safwan M. Obeidat
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Safwan M. Obeidat.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Obeidat, S.M. The Use of 1H NMR and PCA for Quality Assessment of Gasoline of Different Octane Number. Appl Magn Reson 46, 875–883 (2015). https://doi.org/10.1007/s00723-015-0692-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00723-015-0692-1

Keywords

Search

Navigation