Summary.
The synthesis and stereochemistry of new 1,3-dioxane derivatives of 1,4-diacetylbenzene are reported. The anancomeric structure of these compounds, the axial orientation of the aryl group for both 1,3-dioxane rings, and the cis and trans isomerism of some of these compounds is discussed considering data of conformational analysis, NMR investigations, and single crystal X-ray diffractometry.
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Received September 12, 2001. Accepted (revised) November 5, 2001
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Grosu, I., Muntean, L., Toupet, L. et al. Synthesis and Stereochemistry of Some New 1,3-Dioxane Derivatives of 1,4-Diacetylbenzene. Monatshefte fuer Chemie 133, 631–641 (2002). https://doi.org/10.1007/s007060200035
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DOI: https://doi.org/10.1007/s007060200035