Skip to main content
SpringerLink
Log in

Samarium(II) Iodide Promoted Tandem Reductive Fragmentation and Aldol Reaction

  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 We report a new reductive fragmentation/aldol tandem reaction in a 1,4-diketone induced by samarium(II) iodide. Due to the particular stereoelectronic situation in the molecule, an alternative pathway was avoided despite the fact that it would have greatly reduced the strain in the tricyclic molecule.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Author information

Authors and Affiliations

  1.  Institut für Organische Chemie, Universität Wien, A-1090 Wien, Austria, , , , , , AT

    Alexander Schwartz

  2.  Institut für Pharmazeutische Chemie, Karl Franzens – Universität Graz, A-8010 Graz, Austria, , , , , , AT

    Christoph Seger

Authors
  1. Alexander Schwartz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Christoph Seger
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Received February 23, 2001. Accepted March 7, 2001

Rights and permissions

Reprints and permissions

About this article

Cite this article

Schwartz, A., Seger, C. Samarium(II) Iodide Promoted Tandem Reductive Fragmentation and Aldol Reaction. Monatshefte fuer Chemie 132, 855–858 (2001). https://doi.org/10.1007/s007060170074

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s007060170074

Search

Navigation