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Analysis of halogens in wastewater with a new prepared ion selective electrode

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Abstract

Ion selective electrode can rapidly, sensitively detect their corresponding ions and are suitable for field testing. Chloride, fluoride, iodide and bromide ions were analyzed using the ion selective electrodes in previous studies and a new membrane electrode for bromide ion. The bromide selective electrode has a composition of 25% tridodecylmethylammonium bromide, 55% polyvinyl chloride, and 20% dibutyl phthalate and has a slope of 57.4 ± 0.3 mV against 1 × 10–6 − 0.1 mol dm−3 bromide ion. It works in a wide pH range. Response time is 20 s, lifetime is 5 months. It is not sensitive to any other ion. The analytical performances of the electrodes were investigated. Cl−, F−, I−, Br− ions in the samples taken from Ankara tea were measured and their selectivity was found to be good compared to the selective electrodes in the literature.

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Acknowledgements

This study was carried out in Gazi University Chemical Technology research laboratory. I would like to thank my esteemed teacher Prof. Dr. Guler Somer, whose knowledge and experience I benefited from and whom we lost recently.

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  1. Chemistry Department, Gazi University, 06500, Ankara, Turkey

    Sukru Kalayci

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  1. Sukru Kalayci
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Correspondence to Sukru Kalayci.

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Kalayci, S. Analysis of halogens in wastewater with a new prepared ion selective electrode. Monatsh Chem 153, 1137–1141 (2022). https://doi.org/10.1007/s00706-022-02987-9

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  • DOI: https://doi.org/10.1007/s00706-022-02987-9

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