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Electrochemical reactivity of thin film of plumbagin at ionic liquid | water interface

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Abstract

The electrochemical behavior of plumbagin at the glassy carbon electrode modified by a thin film of tetraoctylphosphonium bromide has been investigated using cyclic and square-wave voltammetry. It was found that the redox transformation of plumbagin gives rise to two dependent systems, I/I’ and, II/II’, which are monoelectronic and resulting likely, respectively, in the formation of a monoanionic radical end of a dianion radical. The two systems were quasi-reversible. The formation of ion pairs was the main effect governing the observed redox processes and the obtained system was influenced by the scan rate as well as the scan frequency.

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Authors and Affiliations

  1. Laboratoire de Chimie Minérale, Faculté Des Sciences, Université de Douala, B.P. 24157, Douala, Cameroun

    Jules-Blaise Mabou Leuna & Suzanne Makota

  2. Laboratoire de Chimie Analytique, Faculté Des Sciences, Université de Yaoundé 1, B.P. 812, Yaoundé, Cameroun

    Achille Nassi, Sergeot Delor Kungo Sop, Martin Pengou & Emmanuel Ngameni

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  1. Achille Nassi
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  2. Sergeot Delor Kungo Sop
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  3. Jules-Blaise Mabou Leuna
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  4. Suzanne Makota
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  5. Martin Pengou
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  6. Emmanuel Ngameni
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Correspondence to Achille Nassi.

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Nassi, A., Sop, S.D.K., Leuna, JB.M. et al. Electrochemical reactivity of thin film of plumbagin at ionic liquid | water interface. Monatsh Chem 153, 569–576 (2022). https://doi.org/10.1007/s00706-022-02940-w

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  • DOI: https://doi.org/10.1007/s00706-022-02940-w

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