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Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands

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Abstract

A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger–Akahira–Sunose’s method, and further analysis of these results was performed by Vyazovkin’s algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.

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Acknowledgments

This work was supported by the Ministry of Education and Science of the Republic of Serbia, Grant No. 172055.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Belgrade, Studentski trg 16, 11000, Belgrade, Serbia

    Maja Šumar Ristović, Maja Gruden Pavlović & Katarina Anđelković

  2. Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Belgrade, Serbia

    Matija Zlatar

  3. Department of Chemistry, University of Fribourg, Fribourg, Switzerland

    Matija Zlatar

  4. Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000, Belgrade, Serbia

    Dejan Poleti

  5. Faculty of Physical Chemistry, University of Belgrade, Studentski trg 16, 11000, Belgrade, Serbia

    Vladimir Blagojević & Dragica M. Minić

Authors
  1. Maja Šumar Ristović
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  2. Maja Gruden Pavlović
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  3. Matija Zlatar
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  4. Vladimir Blagojević
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  5. Katarina Anđelković
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  6. Dejan Poleti
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  7. Dragica M. Minić
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Correspondence to Dragica M. Minić.

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Šumar Ristović, M., Gruden Pavlović, M., Zlatar, M. et al. Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands. Monatsh Chem 143, 1133–1139 (2012). https://doi.org/10.1007/s00706-012-0793-6

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  • DOI: https://doi.org/10.1007/s00706-012-0793-6

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