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Synthesis, characterization, and optical properties of 2-amino-4-aryl-6-(9,9′-spirobifluoren-2-yl)pyrimidines

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Abstract

A series of 2-amino-4-aryl-6-(9,9′-spirobifluoren-2-yl)pyrimidines have been synthesized by the reaction of guanidine and chalcones under basic conditions. The physical and optical properties indicated that these compounds generally show good blue light emissions and excellent thermal stabilities. Intermolecular hydrogen bonds and interactions have strong influences on their properties.

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Acknowledgments

We are grateful to Shanghai Natural Science Foundation (09ZR1409400), Shanghai Committee of Science and Technology of China (10520710100), and the Sino-French Institute of ECNU for financial support.

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Authors and Affiliations

  1. Department of Chemistry, East China Normal University, Shanghai, 200062, China

    Yingbo Shi, Qiancai Liu & Jie Tang

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  1. Yingbo Shi
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  2. Qiancai Liu
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  3. Jie Tang
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Correspondence to Qiancai Liu.

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Shi, Y., Liu, Q. & Tang, J. Synthesis, characterization, and optical properties of 2-amino-4-aryl-6-(9,9′-spirobifluoren-2-yl)pyrimidines. Monatsh Chem 142, 907–916 (2011). https://doi.org/10.1007/s00706-011-0507-5

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  • DOI: https://doi.org/10.1007/s00706-011-0507-5

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