Abstract
A novel rhodamine-based chemosensor has been designed and synthesized. The chemosensor, a colorless and nonfluorescent compound, exhibited remarkable fluorescent and colorimetric response toward Fe3+ in aqueous media with high selectivity and sensitivity, and no significant response toward other metal ions such as Hg2+, Ag+, Pb2+, Sr2+, Ba2+, Cd2+, Ni2+, Co2+, Fe2+, Mn2+, Cu2+, Zn2+, Ce3+, Mg2+, K+, and Na+.
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Prodi L, Bolletta F, Montalti M, Zaccheroni N (2000) Coord Chem Rev 205:59
Amendola V, Fabbrizzi L, Foti F, Licchelli M, Mangano C, Pallavicini P, Poggi A, Sacchi D, Taglietti A (2006) Coord Chem Rev 250:273
Rurack K, Resch-Genger U (2002) Chem Soc Rev 31:116
Martínez-Máñez R, Sancenón F (2003) Chem Rev 103:4419
Sessler JL, Davis JM (2001) Acc Chem Res 34:989
Yang Y-K, Yook K-J, Tae J (2005) J Am Chem Soc 127:16760
Aisen P, Wessling-Resnick M, Leibold EA (1999) Curr Opin Chem Biol 3:2000
Weizman H, Ardon O, Mester B, Libman J, Dwir O, Hadar Y, Chen Y, Shanzer A (1996) J Am Chem Soc 118:12386
Touati D (2000) Arch Biochem Biophys 373:1
Zhang M, Gao Y-H, Li M-Y, Yu M-X, Li F-Y, Li L, Zhu M-W, Zhang J-P, Yi T, Huang C-H (2007) Tetrahedron Lett 48:3709
Xiang Y, Tong A-J (2006) Org Lett 8:1549
Bricks JL, Kovalchuk A, Trieflinger C, Nofz M, Büschel M, Tolmachev AI, Daub J, Rurack K (2005) J Am Chem Soc 127:13522
Mao J, Wang L-N, Dou W, Tang X-L, Yan Y, Liu W-S (2007) Org Lett 9:4567
Fan L-J, Jones WE Jr (2006) J Am Chem Soc 128:6784
Kim H-N, Lee M-H, Kim H-J, Kim J-S, Yoon J (2008) Chem Soc Rev 37:1465
Huang J-H, Xu Y-F, Qian X-H (2009) J Org Chem 74:2167
Wu H-M, Zhou P, Wang J, Zhao L, Duan C-Y (2009) New J Chem 33:653
Lee M-H, Wu J-S, Lee J-W, Jung J-H, Kim J-S (2007) Org Lett 9:2501
Wu D-Y, Huang W, Duan C-Y, Lin Z-H, Meng Q-G (2007) Inorg Chem 46:1538
Shiraishi Y, Sumiya S, Kohno Y, Hirai T (2008) J Org Chem 73:8571
Wu J-S, Hwang I-C, Kim KS, Kim JS (2007) Org Lett 9:907
Cunha S, Costa MB, Napolitano HB, Lariucci C, Vencato I (2001) Tetrahedron 57:1671
Lee M, Cho B-K, Yoon J, Kim JS (2007) Org Lett 9:4515
Liu B, Tian H (2005) Chem Commun 3156
Leng B, Zou L, Jiang J-B, Tian H (2009) Sens Actuators B 140:162
Soh JH, Swamy KMK, Kim SK, Kim S, Lee S-H, Yoon J (2007) Tetrahedron Lett 48:5966
Connors KA (1987) Binding constants—the measurement of molecular complex stability. Wiley, New York
Acknowledgments
We are grateful to the Foundation of the Educational Department of Liaoning Province for financial support (no. 2008T002).
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Tang, L., Li, Y., Nandhakumar, R. et al. An unprecedented rhodamine-based fluorescent and colorimetric chemosensor for Fe3+ in aqueous media. Monatsh Chem 141, 615–620 (2010). https://doi.org/10.1007/s00706-010-0311-7
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DOI: https://doi.org/10.1007/s00706-010-0311-7