Abstract
Multi-walled carbon nanotubes (MWCNTs) were decorated with magnetite (Fe3O4) nanoparticles and then used to modify a stainless steel electrode. The Fe3O4/MWCNTs composite was characterized by scanning electron microscopy, transmission electron microscopy, Raman spectroscopy and X-ray diffraction patterns. Electrochemical properties of the modified electrode revealed a substantial catalytic activity for the reduction of hydrogen peroxide. The relationship between peak current and the concentration of hydrogen peroxide was linear in the range from 0.06 mmol L−1 to 0.36 mmol L−1, and the lowest detectable concentration is 0.01 mmol·L−1 (S/N = 3). The modified stainless steel electrode displays excellent stability.
Similar content being viewed by others
References
Wang HY, Park SM (2007) Polypyrrole-based optical probe for a hydrogen peroxide assay. Anal Chem 79:240–245
Yang YF, Mu SL (2005) Determination of hydrogen peroxide using amperometric sensor of polyaniline doped with ferrocenesulfonic acid. Biosens Bioelectron 21:74–78
Chang MCY, Pralle A, Isacoff EY, Chang CJ (2004) A selective, cell-permeable optical probe for hydrogen peroxide in living cells. J Am Chem Soc 126:15392–15393
Miller EW, Albers AE, Pralle A, Isacoff EY, Chang CJ (2005) Boronate-based fluorescent probes for imaging cellular hydrogen peroxide. J Am Chem Soc 127:16652–16659
Ricci F, Palleschi G (2005) Sensor and biosensor preparation, optimisation and applications of Prussian Blue modified electrodes. Biosens Bioelectron 21:389–407
Xu Q, Zhu JJ, Hu XY (2007) Ordered mesoporous polyaniline film as a new matrix for enzyme immobilization and biosensor construction. Anal Chim Acta 597:151–156
Chen HJ, Dong SJ (2007) Direct electrochemistry and electrocatalysis of horseradish peroxidase immobilized in sol–gel-derived ceramic–carbon nanotube nanocomposite film. Biosens Bioelectron 22:1811–1815
Lei CX, Hu SQ, Gao N, Shen GL, Yu RQ (2004) An amperometric hydrogen peroxide biosensor based on immobilizing horseradish peroxidase to a nano-Au monolayer supported by sol–gel derived carbon ceramic electrode. Bioelectrochemistry 65:33–39
Zhang HL, Lai GS, Han DY, Yu AM (2008) An amperometric hydrogen peroxide biosensor based on immobilization of horseradish peroxidase on an electrode modified with magnetic dextran microspheres. Anal Bioanal Chem 390:971–977
Kafi AKM, Wu GS, Chen AC (2008) A novel hydrogen peroxide biosensor based on the immobilization of horseradish peroxidase onto Au-modified titanium dioxide nanotube arrays. Biosens Bioelectron 24:566–571
Zhao GC, Xu MQ, Zhang Q (2008) A novel hydrogen peroxide sensor based on the redox of ferrocene on room temperature ionic liquid film. Electrochem Commun 10:1924–1926
Schäferling M, Grögel DBM, Schreml S (2011) Luminescent probes for detection and imaging of hydrogen peroxide. Microchim Acta 174:1–18
Kotouček M, Opravilová M (1996) Voltammetric behaviour of some nitropesticides at the mercury drop electrode. Anal Chim Acta 329:73–81
Guiberteau A, Díaz TG, Salinas F, Ortiz JM (1995) Indirect voltammetric determination of carbaryl and carbofuran using partial least-squares calibration. Anal Chim Acta 305:219–226
Švancara I, Vytřas K, Barek J, Zima J (2001) Carbon paste electrodes in modern electroanalysis. Crit Rev Anal Chem 31:311–345
Zima J, Svancara I, Barek J, Vytras K (2009) Recent advances in electroanalysis of organic compounds at carbon paste electrodes. Crit Rev Anal Chem 39:204–227
Li JN, Liu SM, Mao X, Gao P, Yan ZH (2004) Trace determination of rare earths by adsorption voltammetry at a carbon paste electrode. J Electroanal Chem 561:137–142
Welch CM, Banks CE, Simm AO, Compton RG (2005) Silver nanoparticle assemblies supported on glassy-carbon electrodes for the electro-analytical detection of hydrogen peroxide. Anal Bioanal Chem 382:12–21
Zhang LH, Zhai YM, Gao N, Wen D, Dong SJ (2008) Sensing H2O2 with layer-by-layer assembled Fe3O4–PDDA nanocomposite film. Electrochem Commun 10:1524–1526
Wang Q, Zheng J (2010) Electrodeposition of silver nanoparticles on a zinc oxide film: improvement of amperometric sensing sensitivity and stability for hydrogen peroxide determination. Microchim Acta 169:361–365
Li J, Yuan R, Chai Y, Zhang T, Che X (2010) Direct electrocatalytic reduction of hydrogen peroxide at a glassy carbon electrode modified with polypyrrole nanowires and platinum hollow nanospheres. Microchim Acta 171:125–131
Wang AJ, Zhang PP, Li YF, Feng JJ, Dong WJ, Liu XY (2011) Hydrogen peroxide sensor based on glassy carbon electrode modified with β-manganese dioxide nanorods. Microchim Acta 175:31–37
Mosbach K, Anderson L (2007) Magnetic ferrofluids for preparation of magnetic polymers and their application in affinity chromatography. Nature 270:259–261
Yang XY, Zhang XY, Ma YF, Huang Y, Wang YS, Chen YS (2009) Superparamagnetic graphene oxide–Fe3O4 nanoparticles hybrid for controlled targeted drug carriers. J Mater Chem 19:2710–2714
Ito A, Shinkai M, Honda H, Kobayashi T (2001) Heat-inducible TNF-α gene therapy combined with hyperthermia using magnetic nanoparticles as a novel tumor-targeted therapy. Cancer Gene Ther 8:649–654
Katz E, Weizmann Y, Willner I (2005) Magnetoswitchable reactions of DNA monolayers on electrodes: gating the processes by hydrophobic magnetic nanoparticles. J Am Chem Soc 127:9191–9200
Cheng GF, Zhao J, Tu YH, He PG, Fang YZ (2005) A sensitive DNA electrochemical biosensor based on magnetite with a glassy carbon electrode modified by muti-walled carbon nanotubes in polypyrrole. Anal Chim Acta 533:11–16
Costa RCC, Lelis MFF, Oliveira LCA, Fabris JD, Ardisson JD, Rios RRVA, Silva CN, Lago RM (2006) Novel active heterogeneous Fenton system based on Fe3-xMxO4(Fe, Co, Mn, Ni): the role of M2+ species on the reactivity towards H2O2 reactions. J Hazard Mater B129:171–178
Wang J (2005) Carbon-nanotube based electrochemical biosensors: a review. Electroanalysis 17:7–14
Kim JH, Nam K-W, Ma SB, Kim KB (2006) Fabrication and electrochemical properties of carbon nanotube film electrodes. Carbon 44:1963–1968
Lin Y, Watson KA, Ghose S, Smith JG, Williams TV, Crooks RE, Cao W, Connell JW (2009) Direct mechanochemical formation of metal nanoparticles on carbon nanotubes. J Phys Chem C 113:14858–14862
Bui M-PN, Lee S, Han KN, Pham X-H, Li CA, Choo J, Seong GH (2009) Electrochemical patterning of gold nanoparticles on transparent single-walled carbon nanotube films. Chem Commun 45:5549–5551
Hu XB, Liu BZ, Deng YH, Cheng HZ, Luo S, Sun C, Yang P, Yang SG (2011) Adsorption and heterogeneous Fenton degradation of 17α-methyltestosterone on nano Fe3O4/MWCNTs in aqueous solution. Appl Catal B Environ 107:274–283
Liu Y, Jiang W, Wang Y, Zhang XJ, Song D, Li FS (2009) Synthesis of Fe3O4/CNTs magnetic nanocomposites at the liquid–liquid interface using oleate as surfactant and reactant. J Magn Magn Mater 321:408–412
Tiwari S, Phase DM, Choudhary RJ (2008) Probing antiphase boundaries in Fe3O4 thin films using micro-Raman spectroscopy. Appl Phys Lett 93:234108
Qian WZ, Liu T, Wei F, Wang ZW, Luo GH, Yu H, Li ZF (2003) The evaluation of the gross defects of carbon nanotubes in a continuous CVD process. Carbon 41:2613–2617
Kim UJ, Furtado CA, Liu XM, Chen GG, Eklund PC (2005) Raman and IR spectroscopy of chemically processed single-walled carbon nanotubes. J Am Chem Soc 127:15437–15445
Mishra AK, Ramaprabhu S (2010) Magnetite decorated Multiwalled carbon nanotube based supercapacitor for arsenic removal and desalination of seawater. J Phys Chem C 114:2583–2590
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hu, X., Wang, C. Hydrogen peroxide sensor based on a stainless steel electrode coated with multi-walled carbon nanotubes modified with magnetite nanoparticles. Microchim Acta 179, 329–335 (2012). https://doi.org/10.1007/s00604-012-0899-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00604-012-0899-x