13C isotope depletion in ikaite crystals: evidence for methane release from the Siberian shelves ?

Abstract

 Ikaite crystals (CaCO₃×6H₂O) have been found at 232- to 238-cm sediment depth in R/V Polarstern core PS2460-4 from the Laptev Sea continental margin in a water depth of 204 m. δ¹³C values of this phase average −36.3±0.4‰ PDB (N=2), which is significantly outside the range of normal marine carbonates. The CO₂ involved in the precipitation of the ikaite is most probably derived from methane, which has extremely depleted ¹³C isotope values. Two possible sources of methane in these sediments are: (1) methanogenesis (decomposition of organic matter under anaerobic conditions); and (2) gas hydrates, which are known to occur in the Siberian shelf regions.