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Studies on dielectric features of Li2O-Ga2O3-SiO2: Cr2O3/MoO3/WO3 glass systems

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Abstract

This investigation consists of results of the studies on dielectric properties and a.c. conductivity of Li2O-Ga2O3-SiO2 (LGS) glass with 2.0 mol% of Cr2O3, MoO3, WO3 across 0.01 Hz to 1 MHz and 20 °C to 240 °C. Structural analysis using optical absorption and IR spectra indicated dopant ions predominantly in Cr3+, Mo6+/Mo5+, W6+ states, and occupied Td and Oh positions. Dielectric constant and conductivity were found to be the maximal for LGSMo glass, with the lowest impedance, while LGSCr glass exhibited the opposite trend. From the analysis of dipolar relaxation effects probable dipoles were identified in each glass. Studies on conductivity revealed that contribution of ionic components is very low and a substantial polaronic contribution in LGSMo glass, whereas, LGSCr glass showed a larger ionic component, specifically Li+ ion diffusion and hence more useful material for solid-state batteries with respect to the other two glasses.

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Acknowledgements

J.P. acknowledges the support of project CIuK co-financed by the Croatian Government and the European Union through the European Regional Development Fund-Competitiveness and Cohesion Operational Programme (Grant KK.01.1.1.02.0016.).

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Authors and Affiliations

  1. Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar, 522 510, India

    S. Vijaya Krishna, D. Bhadrarao, Y. Dana Rao, A. Venkata Sekhar, V. Ravi Kumar & N. Veeraiah

  2. Division of Materials Chemistry, Ruđer Bošković Institute, 10000, Zagreb, Croatia

    L. Pavić

  3. Faculty of Chemical Engineering and Technology, University of Zagreb, 10000, Zagreb, Croatia

    A. Bafti

  4. Department of Chemistry, Faculty of Science, University of Zagreb, 10000, Zagreb, Croatia

    J. Pisk

  5. Department of Nanotechnology, Acharya Nagarjuna University, Nagarjuna Nagar, 522 510, India

    A. Venkata Sekhar

  6. Department of Physics, Andhra Loyola College (Autonomous), Vijayawada, A.P., India

    N. Veeraiah

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  1. S. Vijaya Krishna
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Contributions

S. Vijayakrishna: Conceptualization, Methodology, Investigation. L. Pavić: Data curation, Formal analysis, Software, Writing – original draft. A. Bafti: Data curation, Formal analysis, Software. J. Pisk: Methodology, Data curation, Formal analysis. D. Bhadrarao: Methodology, Data curation, Formal analysis. Y. Dana Rao: Methodology, Data curation, Formal analysis. A. Venkata Sekhar: Methodology, Data curation, Formal analysis. V. Ravi Kumar: Supervision, Writing—original draft, Writing—review and editing. N. Veeraiah: Supervision, Writing—review and editing.

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Correspondence to L. Pavić or V. Ravi Kumar.

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Krishna, S.V., Pavić, L., Bafti, A. et al. Studies on dielectric features of Li2O-Ga2O3-SiO2: Cr2O3/MoO3/WO3 glass systems. Appl. Phys. A 130, 380 (2024). https://doi.org/10.1007/s00339-024-07518-3

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