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Influence of phosphorus pentoxide on structural, dielectric, and mechanical properties of borosilicate glasses for sealant applications

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Abstract

Herein, a glassy system 40SiO2–35H3BO3-(25–x)PbO-xP2O5 was fabricated with increasing concentration of P2O5 (x = 0, 0.5, 1, 1.5 and 2) via a melt-quenching method. Structural and morphological analyses confirmed the non-crystalline nature of the synthesized glassy system. Spectroscopic studies revealed that the doping of P2O5 within the glass compositions highly affected the peak positions of the recorded spectra. The dielectric constant and dielectric loss values for undoped glass was found to be 64.37 and 0.0626. Also, the highest compressive mechanical strength is that of undoped glass is 355 MPa. Increase in doping concentration of P2O5 within the glasses showed a negative effect on their dielectric and mechanical properties. Further, synthesized P2O5-doped lead borosilicate glasses revealed significant dielectric and mechanical properties which makes them a potential contender for engineering materials, energy storage devices and insulating materials. Glass sample, SHPbP2 (2% P2O5) was further tested for sealant applications which successfully demonstrated a sealing between two borosilicate glass plates at 770 °C.

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Acknowledgements

The authors are thankful to the funding agency for the financial support under SERB-DST project (File. No. EEQ/2018/000647) New Delhi India.

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  1. Advanced Glass and Glass Ceramics Research Laboratory, Department of Physics, University of Lucknow, Lucknow, 226007, India

    Zaireen Fatima, Chandkiram Gautam,  Shweta, Sarvesh Kumar Avinashi & Rajat Kumar Mishra

  2. Department of Physics, Integral University, Lucknow, 226026, India

    Zaireen Fatima

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CG: conceptualization; formal analysis; validation; visualization; supervision; writing—original draft; writing—review and editing and funding acquisition. ZF: investigation; visualization; data curation; formal analysis; methodology and writing—original draft. S: writing—original draft; investigation and data curation. SKAm RKM: investigation and writing—original draft.

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Correspondence to Chandkiram Gautam.

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Fatima, Z., Gautam, C., Shweta et al. Influence of phosphorus pentoxide on structural, dielectric, and mechanical properties of borosilicate glasses for sealant applications. Appl. Phys. A 129, 486 (2023). https://doi.org/10.1007/s00339-023-06768-x

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