Abstract
Nb-Si based alloys are considered as a potential candidates to substitute for Ni-based super alloys. However, its poor mechanical properties and high temperature oxidation resistance greatly limit its development and application. Alloying can effectively improve the mechanical properties and oxidation resistance of Nb-Si based alloy. In this work, the effects of Al, Cr, B elements addition on the mechanical properties and oxidation resistance of niobium-silicon ternary alloys are summarized. The microstructure, oxidation behavior and mechanical properties of various alloys were analyzed and compared. Moreover, the fracture and oxidation failure mechanism of the alloys are also summarized. Finally, the development trend of ternary Nb-Si based oxidation-resistant alloys in the future has been prospected.
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Y. Pan, W. Guan, The hydrogenation mechanism of PtAl and IrAl thermal barrier coatings from first-principles investigations. Int. J. Hydrogen Energy. 45, 20032–20041 (2020)
D. Zoia, K. Volodymyr, K. Taras, V. Bogdan, K. Andrii, Synthesis of functional surface layers on stainless steels by laser alloying. Metals. 11, 434–453 (2021)
Y. Zhang, K. Cui, T. Fu, J. Wang, F. Shen, X. Zhang, L. Yu, Formation of MoSi2 and Si/MoSi2 coatings on TZM (Mo-0.5Ti-0.1Zr-0.02C) alloy by hot dip silicon-plating method. Ceram. Int. 47, 23053–23065 (2021)
Y. Pan, Role of hydrogen on the structural stability, mechanical and thermodynamic properties of thecubic TM3Si silicides. Int. J. Hydrogen Energy. 46, 28338–28345 (2021)
L. Yu, Y. Zhang, T. Fu, J. Wang, K. Cui, F. Shen, Rare earth elements enhanced the oxidation resistance of Mo-Si-Based alloys for high temperature application: A review. Coatings. 11, 1144 (2021)
Y. Zhang, K. Cui, T. Fu, J. Wang, J. Qie, X. Zhang, Synthesis WSi2 coating on W substrate by HDS method with various deposition times. Appl. Surf. Sci. 511, 145551 (2020)
L. Yu, F. Shen, T. Fu, Y. Zhang, K. Cui, J. Wang, X. Zhang, Microstructure and oxidation behavior of metal-modified Mo-Si-B alloys: A review. Coatings. 11, 1256 (2021)
T. Fu, K. Cui, Y. Zhang, J. Wang, F. Shen, L. Yu, J. Qie, X. Zhang, Oxidation protection of tungsten alloys for nuclear fusion applications: A comprehensive review. J. Alloy. Compd. 884, 161057 (2021)
S. Wang, Y. Pan, Insight into the structures, melting points, and mechanical properties of NbSi2 from first-principles calculations. J. Am. Ceram. Soc. 102, 4822–4834 (2019)
T. Fu, K. Cui, Y. Zhang, J. Wang, X. Zhang, F. Shen, L. Yu, H. Mao, Microstructure and oxidation behavior of anti-oxidation coatings on Mo-based alloys through HAPC process: A review. Coatings. 11, 883 (2021)
Y. Zhang, J. Zhao, H. Li, J. Lei, X. Cheng, Effect of hot-dip siliconizing time on phase composition and microstructure of Mo-MoSi2 high temperature structural materials. Ceram. Int. 45, 5588–5593 (2019)
D. Pu, Y. Pan, Influence of high pressure on the structure, hardness and brittle-to-ductile transition of NbSi2 ceramics. Ceram. Int. 47, 2311–2318 (2021)
X. Zhang, T. Fu, K. Cui, Y. Zhang, F. Shen, J. Wang, L. Yu, H. Mao, The protection, challenge, and prospect of anti-oxidation coating on the surface of niobium alloy. Coatings. 11, 742 (2021)
Y. Zhang, Y. Li, C. Bai, Microstructure and oxidation behavior of Si-MoSi2 functionally graded coating on Mo substrate. Ceram. Int. 43, 6250–6256 (2017)
K. Cui, Y. Zhang, T. Fu, S. Hussain, T. Saad Algarni, J. Wang, X. Zhang, S. Ali, Effects of Cr2O3 contents on microstructure and mechanical properties of Al2O3 matrix composites. Coatings. 11, 234 (2021)
J. Wang, Y. Zhang, K. Cui, T. Fu, J. Gao, S. Hussain, T. AlGarni, Pyrometallurgical recovery of zinc and valuable metals from electric arc furnace dust: A review. J. Clean. Prod. 298, 126788 (2021)
Y. Pan, D. Pu, E. Yu, Structural, electronic, mechanical and thermodynamic properties of Cr-Si binary silicides from first-principles investigations. Vacuum. 185, 110024 (2021)
C. Sun, W. Jiang, M. Li, J. Sha, C. Zhou, High-throughput synthesis of oxidation-resistant Nb–Si based alloy thin film by magnetron co-sputtering. Prog. Nat. Sci.: Mater. Int. 31, 454–460 (2021)
Y. Zhang, T. Fu, K. Cui, F. Shen, J. Wang, L. Yu, H. Mao, Evolution of surface morphology, roughness and texture of tungsten disilicide coatings on tungsten substrate. Vacuum. 191, 110297 (2021)
S. Lu, H. Zheng, L. Deng, J. Yao, Effect of silicon on the fracture toughness and oxidation behavior of hot pressed NbCr2 alloys. Mater. Des. 51, 432–437 (2013)
L. Deng, S. Lu, B. Tang, Y. Li, Effect of Si on thermal stability of Nb-22.5Cr alloy. Vacuum. 152, 312–318 (2018)
S. Kashyap, C. Tiwary, K. Chattopadhyay, Microstructure and mechanical properties of oxidation resistant suction cast Nb–Si–Al alloy. Mat. Sci. Eng. A-Struct. 559, 74–85 (2013)
L. Zifu, P. Tsakiropoulos, Study of the effects of Ge addition on the microstructure of Nb–18Si in situ composites. Intermetallics. 18, 1072–1078 (2010)
N. Vellios, P. Tsakiropoulos, Study of the role of Fe and Sn additions in the microstructure of Nb-24Ti-18Si-5Cr silicide based alloys. Intermetallics. 18, 1729–1736 (2010)
Y. Murayama, S. Hanada, High temperature strength, fracture toughness and oxidation resistance of Nb-Si-Al-Ti multiphase alloys. Sci. Technol. Adv. Mater. 3, 145–156 (2002)
A. Liu, L. Sun, S. Li, Y. Han, Effect of cerium on microstructures and high temperature oxidation resistance of an Nb-Si system in-situ composite. J. Rare Earths. 25, 474–479 (2007)
T. Murakami, S. Sasaki, K. Ichikawa, A. Kitahara, Oxidation resistance of powder compacts of the Nb–Si–Cr system and Nb3Si5Al2 matrix compacts prepared by spark plasma sintering. Intermetallics 9, 629–635 (2001)
Z. Sun, Y. Ying, X. Guo, C. Zhang, Y. Chang, Experimental investigation on the phase equilibria of the Nb-Ti-Si-B System at 1500°C. J. Phase Equilib. Diffus. 32, 407–411 (2011)
J. Geng, P. Tsakiropoulos, G. Shao, The effects of Ti and Mo additions on the microstructure of Nb-silicide based in situ composites. Intermetallics. 14, 227–235 (2006)
S. Zhang, X. Guo, Effects of B addition on the microstructure and properties of Nb silicide based ultrahigh temperature alloys. Intermetallics. 57, 83–92 (2015)
L. Su, L. Jia, J. Weng, Z. Hong, C. Zhou, H. Zhang, Improvement in the oxidation resistance of Nb-Ti-Si-Cr-Al-Hf alloys containing alloyed Ge and B. Corros. Sci. 88, 460–465 (2014)
J. Cheng, S. Yi, J. Park, Oxidation behaviors of Nb-Si-B ternary alloys at 1100 °C under ambient atmosphere. Intermetallics. 23, 12–19 (2012)
K. Thomas, S. Varma, Oxidation response of three Nb-Cr-Mo-Si-B alloys in air. Corros. Sci. 99, 145–153 (2015)
K. Chan, Alloying effects on fracture mechanisms in Nb-based intermetallic in-situ composites. Materi. Sci. Eng. A 329–331, 513–522 (2002)
S. Qu, Y. Han, J. Song, Y. Kang, Effects of Cr and Al on high temperature oxidation resistance of Nb-Si system intermetallics. Int. J. Fatigue 546–549, 1485–1488 (2007)
Y. Pan, Structural prediction and overall performances of CrSi2 disilicides: DFT investigations. ACS Sustain. Chem. Eng. 8, 11024–11030 (2020)
J. Yan, H. Zhang, S. Tang, J. Xu, Room temperature mechanical properties and high temperature oxidation behavior of MoSi2 matrix composite reinforced by adding La2O3 and Mo5Si3. Mater. Charact. 60, 447–450 (2009)
L. Jia, J. Weng, Z. Li, Z. Hong, L. Su, H. Zhang, Room temperature mechanical properties and high temperature oxidation resistance of a high Cr containing Nb–Si based alloy. Mat. Sci. Eng. A-Struct. 623, 32–37 (2015)
S. Zhang, W. Liu, J. Sha, Microstructural evolution and mechanical properties of Nb-Si-Cr ternary alloys with a tri-phase Nb/Nb5Si3/Cr2Nb microstructure fabricated by spark plasma sintering. Prog. Nat. Sci-Mater. 28, 626–634 (2018)
S. Zhang, X. Guo, Alloying effects on the microstructure and properties of Nb–Si based ultrahigh temperature alloys. Intermetallics. 70, 33–44 (2016)
Z. Li, P. Tsakiropoulos, Study of the effect of Cr and Ti additions in the microstructure of Nb-18Si-5Ge based in-situ composites. Intermetallics. 26, 18–25 (2012)
P. Maji, R. Mitra, K. Ray, Effect of Cr on the evolution of microstructures in as-cast ternary niobium-silicide-based composites. Intermetallics. 85, 34–47 (2017)
G. Sun, L. Jia, Z. Hong, G. Liu, H. Zhang, Improvement of oxidation resistance of Nb-Ti-Si based alloys with additions of Al, Cr and B at different temperatures. Prog. Nat. Sci-Mater. 31, 442–453 (2021)
J. Nelson, M. Ghadyani, C. Utton, P. Tsakiropoulos, A study of the effects of Al, Cr, Hf, and Ti additions on the microstructure and oxidation of Nb-24Ti-18Si silicide based alloys. Materials. 11, 1579 (2018)
Y. Zhang, K. Cui, Q. Gao, S. Hussain, Y. Lv, Investigation of morphology and texture properties of WSi2 coatings on W substrate based on contact-mode AFM and EBSD. Surf. Coat. Tech. 396, 125966 (2020)
K. Cui, Y. Zhang, T. Fu, J. Wang, X. Zhang, Toughening mechanism of mullite matrix composites: A review. Coatings. 10, 672 (2020)
K. Cui, T. Fu, Y. Zhang, J. Wang, H. Mao, T. Tan, Microstructure and mechanical properties of CaAl12O19 reinforced Al2O3-Cr2O3 composites. J. Eur. Ceram. Soc. 41, 7935-7945 (2021)
S. Varma, F. Sanchez, C. Ramana, Microstructures in a Nb-Cr-V-W-Ta high entropy alloy during annealing. J. Mater. Sci. Technol. 53, 66–72 (2020)
J. Zhao, J. Westbrook, Ultrahigh-temperature materials for jet engines. MRS Bull. 28, 622–630 (2003)
J. Distefano, B. Pint, J. Devan, Oxidation of refractory metals in air and low pressure oxygen gas. Int. J. Refract. Met. H. 18, 237–243 (2000)
B. Voglewede, V. Rangel, S. Varma, The effects of uncommon silicides on the oxidation behavior of alloys from the Nb-Cr-Si system. Corros. Sci. 61, 123–133 (2012)
D. Yao, C. Rui, C. Zhou, J. Sha, H. Jiang, Experimental study and modeling of high temperature oxidation of Nb-base in situ composites. Corros. Sci. 51, 364–370 (2009)
K. Chan, Cyclic-oxidation resistance of niobium-base in situ composites: modeling and experimentation. Oxid. Met. 61, 165–194 (2004)
S. Zhang, L. Wei, J. Sha, Microstructural evolution and mechanical properties of Nb-Si-Cr ternary alloys with a tri-phase Nb/Nb5Si3/Cr2Nb microstructure fabricated by spark plasma sintering. Prog. Nat. Sci.: Mater. Int. 28, 626–634 (2018)
T. Thandorn, P. Tsakiropoulos, Study of the role of B addition on the microstructure of the Nb-24Ti-18Si-8B alloy. Intermetallics. 18, 1033–1038 (2010)
K. Park, J. Park, Y. Kim, J. Choi, H. Kang, J. Kang, K. Park, H. Park, Effect of the microstructure refinement by powder metallurgy on the oxidation behavior of Nb-6Mo-20Si-3Cr silicide-based alloy. Mater. Charact. 170, 110708 (2020)
W. Jiang, W. Shao, J. Sha, C. Zhou, Experimental studies and modeling for the transition from internal to external oxidation of three-phase Nb-Si-Cr alloys. Prog. Nat. Sci. Mater. Int. 28, 740–748 (2018)
C. Ma, J. Li, Y. Tan, R. Tanska, S. Hanada, Microstructure and mechanical properties of Nb/Nb5Si3 in situ composites in Nb-Mo-Si and Nb-W-Si systems. Mat. Sci. Eng. A-Struct. 386, 375–383 (2004)
J. Sha, H. Hirai, T. Tabaru, A. Kitahara, H. Ueno, S. Hanada, High-temperature strength and room-temperature toughness of Nb-W-Si-B alloys prepared by arc-melting. Mat. Sci. Eng. A-Struct. 364, 151–158 (2004)
Y. Zhang, S. Hussain, K. Cui, T. Fu, J. Wang, M. Javed, Y. Lv, B. Aslam, Microstructure and mechanical properties of MoSi2 coating deposited on Mo substrate by hot dipping processes. J. Nanoelectron. Optoelectron. 14, 1680–1685 (2019)
L. Klein, Y. Shen, M. Killian, S. Virtanen, Effect of B and Cr on the high temperature oxidation behaviour of novel γ/γ′-strengthened Co-base superalloys. Corros. Sci. 53, 2713–2720 (2011)
M. Meyer, M. Kramer, M. Akinca, Compressive creep behavior of Mo5Si3 with the addition of boron: sciencedirect. Intermetallics. 4, 273–281 (1996)
J. Cheng, S. Yi, J. Park, Simultaneous coating of Si and B on Nb-Si-B alloys by a halide activated pack cementation method and oxidation behaviors of the alloys with coatings at 1100 °C. J. Alloy. Compd. 644, 975–981 (2015)
Z. Sun, Y. Yang, X. Guo, C. Zhang, Y. Chang, Thermodynamic modeling of the Nb-rich corner in the Nb-Si-B system. Intermetallics. 19, 26–34 (2011)
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This work was supported by the Anhui Province Science Foundation for Excellent Young Scholars (2108085Y19) and National Natural Science Foundation of China (No. 51604049).
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The manuscript was written through the contributions of all authors. YYZ: Conceptualization, investigation, and supervision. YYZ and FQS: Writing original draft and image processing. FQS, LHY, KKC, and HW: Validation, resources, investigation, writing—review and editing. JW, SH and NA: Visualization, writing—review and editing. All authors have approved the final version of the manuscript.
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Shen, F., Yu, L., Fu, T. et al. Effect of the Al, Cr and B elements on the mechanical properties and oxidation resistance of Nb-Si based alloys: a review. Appl. Phys. A 127, 852 (2021). https://doi.org/10.1007/s00339-021-05013-7
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DOI: https://doi.org/10.1007/s00339-021-05013-7