Abstract
Self-assembled roselike ZnO nanostructures were synthesized via thermal evaporation of zinc powders without catalytic assistance at the relatively low temperature of 550 °C. The roselike structures consist of a large number of ZnO nanorods that uniformly arrange into hexagonal multilayers. The spontaneous nanoindentation effects under geometric constraints can be used to explain the structures. The cathodoluminescence spectra show a wide visible emission band related to Zn interstitials and oxygen vacancies. Field emission measurements demonstrate that the roselike ZnO nanostructures possess good electron emission characteristics with a turn-on field of 4.3 V/μm.
Similar content being viewed by others
References
G.Z. Shen, Y. Bando, C.J. Lee, J. Phys. Chem. B 109, 10779 (2005)
J.Y. Lao, J.Y. Huang, D.Z. Wang, Z.F. Ren, Nano Lett. 3, 235 (2003)
G.Z. Shen, J.H. Cho, C.J. Lee, Chem. Phys. Lett. 401, 415 (2005)
X.H. Sun, S. Lam, T.K. Sham, F. Heigl, A. Jürgensen, N.B. Wong, J. Phys. Chem. B 109, 3120 (2005)
X.G. Pu, Z.L. Zhong, J. Am. Chem. Soc. 125, 11299 (2003)
G.Z. Shen, Y. Bando, C.J. Lee, J. Phys. Chem. B 109, 10578 (2005)
A. Umar, S.H. Kim, Y.B. Hahn, Superlattices Microstruct. 39, 145 (2006)
P. Zhang, H. Qi, X. Zhang, Q. Zhao, Y. Tian, D. Yu, Appl. Phys. A 84, 165 (2006)
A. Umar, S. Lee, Y.H. Im, Y.B. Hahn, Nanotechnology 16, 2462 (2005)
R.C. Wang, C.P. Liu, J.L. Huang, Appl. Phys. Lett. 86, 251104 (2005)
L.W. Yang, Y.J. Gao, X.L. Wu, Y.M. Yang, G.S. Huang, Z.Y. Zhang, P.K. Chu, Appl. Phys. A 89, 173 (2007)
U. Özgür, Y. Alivov, C. Liu, A. Teke, M. Reshchikov, S. Dogan, V. Avrutin, S.J. Cho, H. Morkoc, J. Appl. Phys. 98, 041301 (2005)
M. Sun, Ph.D. thesis (University of Science and Technology of China, 2000)
Q. Zhao, H.Z. Zhang, Y.W. Zhu, S.Q. Feng, X.C. Sun, J. Xu, D.P. Yu, Appl. Phys. Lett. 86, 203115 (2005)
G.Z. Shen, Y. Bando, B.D. Liu, D. Golberg, C.J. Lee, Adv. Funct. Mater. 16, 410 (2006)
I.S. Altman, P.V. Pikhitsa, M. Choic, Appl. Phys. Lett. 84, 1126 (2004)
G.S. Huang, X.L. Wu, Y.C. Cheng, X.F. Li, S. Luo, H.T. Feng, P.K. Chu, Nanotechnology 17, 5573 (2006)
C.J. Lee, T.J. Lee, S.C. Lyu, Y. Zhang, H. Ruh, H.J. Lee, Appl. Phys. Lett. 81, 3648 (2002)
N.S. Ramgir, D.J. Late, A.B. Bhise, I.S. Mulla, M.A. More, D.S. Joag, V.K. Pillai, Nanotechnology 17, 2730 (2006)
V. Filip, D. Nicolaescu, M. Tanemura, F. Okuyama, Ultramicroscopy 89, 39 (2001)
Y.W. Zhu, H.Z. Zhang, X.C. Sun, S.Q. Feng, J. Xu, Q. Zhao, B. Xiang, R.M. Wang, D.P. Yu, Appl. Phys. Lett. 83, 144 (2003)
Author information
Authors and Affiliations
Corresponding author
Additional information
PACS
68.70.+w; 78.55.Cr; 81.05.Cy
Rights and permissions
About this article
Cite this article
Xu, L., Wu, X., Xiong, X. et al. Synthesis and field-emission properties of roselike ZnO nanostructures. Appl. Phys. A 91, 247–250 (2008). https://doi.org/10.1007/s00339-008-4423-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-008-4423-4