Skip to main content
Log in

Transparent luminescent layers via ionic liquid-based approach to LaPO4:RE (RE = Ce, Tb, Eu) dispersions

  • Rapid communication
  • Published:
Applied Physics A Aims and scope Submit manuscript

Abstract

Transparent layers containing the highly luminescent nanophosphors LaPO4:Ce,Tb and LaPO4:Eu are realized by ink-jet printing on standard transparencies and black paper. The luminescent material is non-agglomerated, 15 nm in size, and applied as a dispersion in ethanol for printing. The structured layers exhibit intense green (LaPO4:Ce,Tb) or red (LaPO4:Eu) emission. While printing on overhead transparencies, an optical transmission of about 90% is realized. This value, in fact, is limited due to the performance of the underlying polymer material. A microwave-assisted synthesis in ionic liquids as a novel concept of synthesis is prerequisite to gain the nanoscale phosphor materials.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M.A. Aegerter, J. Puetz, G. Gasparro, N. Al-Dahoudi, Opt. Mater. 26, 155 (2004)

    Article  ADS  Google Scholar 

  2. C. Meyer, M. Haase, Patent application WO 2004 096843 A1

  3. H. Schmidt, R. Kasemann, T. Burkhart, G. Wagner, E. Arpac, E. Geiter, ACS Symp. Ser. 585, 331 (1995)

    Article  Google Scholar 

  4. H.C. van de Hulst, Light Scattering by Small Particles (Dover Publications, New York, 1981)

    Google Scholar 

  5. S. Kumar, T. Nann, Small 2, 316 (2006)

    Article  Google Scholar 

  6. D. Pan, Q. Wang, S. Jiang, X. Ji, L. An, Adv. Mater. 17, 176 (2005)

    Article  Google Scholar 

  7. J.S. Steckel, J.P. Zimmer, S. Coe-Sullivan, N.E. Scott, V. Bulovic, M.G. Bawendi, Angew. Chem. Int. Edit. 43, 2154 (2004)

    Article  Google Scholar 

  8. K. Kömpe, H. Borchert, J. Storz, A. Lobo, S. Adam, T. Möller, M. Haase, Angew. Chem. Int. Edit. 42, 5513 (2003)

    Article  Google Scholar 

  9. M.T. Harrison, S.V. Kershaw, A.L. Rogach, A. Kornowski, A. Eychmüller, H. Weller, Adv. Mater. 12, 123 (2000)

    Article  Google Scholar 

  10. D. Giaume, V. Buissette, K. Lahlil, J.P. Boilot, D. Casanova, E. Beaurepaire, M.P. Sauviat, A. Alexandrou, Prog. Solid State Chem. 33, 99 (2006)

    Article  Google Scholar 

  11. M.I. Watchi, M. Duran, A. Huignard, patent application WO 2005001872

  12. M. Yu, J. Lin, J. Fu, H.J. Zhang, Y.C. Han, J. Mater. Chem. 13, 1413 (2003)

    Article  Google Scholar 

  13. G. Bühler, C. Feldmann, Angew. Chem. Int. Edit. 45, 4862 (2006)

    Google Scholar 

  14. G. Bühler, C. Feldmann, Patent application DE 10 2006 001 414.6

  15. V.K. LaMer, R.H. Dinegar, J. Am. Chem. Soc. 72, 4847 (1950)

    Article  Google Scholar 

  16. S. Shionoya, W.M. Yen (eds.), Phosphor Handbook (CRC Press, Boca Raton, 1999)

  17. C. Feldmann, T. Jüstel, C.R. Ronda, P.J. Schmidt, Adv. Funct. Mater. 13, 511 (2003)

    Article  Google Scholar 

  18. P. Wasserscheid, T. Welton (eds.), Ionic Liquids in Synthesis (Wiley-VCH, Weinheim, 2002)

  19. T.J.S. Schubert, Nachr. Chem. 53, 1222 (2005)

    Google Scholar 

  20. W. Xu, C.A. Angeli, Science 302, 422 (2003)

    Article  ADS  Google Scholar 

  21. J. Dupont, R.F. de Souza, P.A.Z. Suarez, Chem. Rev. 102, 3667 (2002)

    Article  Google Scholar 

  22. P. Wasserscheid, W. Keim, Angew. Chem. Int. Edit. 39, 3772 (2000)

    Article  Google Scholar 

  23. T. Welton, Chem. Rev. 99, 2071 (1999)

    Article  Google Scholar 

  24. D.F. Mullica, W.D. Milligan, D.A. Grossie, G.W. Beall, L.A. Boatner, Inorg. Chem. Acta 95, 231 (1984)

    Article  Google Scholar 

  25. G. Blasse, B.C. Grabmaier, Luminescent Materials (Springer, Berlin, 1994)

    Google Scholar 

  26. B.M.J. Smets, Mater. Chem. Phys. 16, 283 (1987)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to C. Feldmann.

Additional information

PACS

61.46.+w; 78.67.Bf; 81.07.-b

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bühler, G., Feldmann, C. Transparent luminescent layers via ionic liquid-based approach to LaPO4:RE (RE = Ce, Tb, Eu) dispersions. Appl. Phys. A 87, 631–636 (2007). https://doi.org/10.1007/s00339-007-3865-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00339-007-3865-4

Keywords

Navigation