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Correlation between green luminescence and morphology evolution of ZnO films

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Abstract

Photoluminescence and atomic force microscopy have been used to characterize ZnO thin films grown by metal-organic chemical vapor deposition (MOCVD) at varied growth pressures. The surface morphology with different grain structures has strong influence on the green photoluminescence of ZnO. When large discrete islands or structureless overgrowth cover the rough surface, broad green emissions around 500 nm go beyond the ultraviolet (UV) emission band; whereas, when the surface is packed closely with small grains, only weak green emission is observed with a red-shift to 528 nm. This variation of green emissions is ascribed to changes in the charge states of oxygen vacancies, which is strongly dependent on the surface morphology and grain structures. Based on the grain boundary defect model, two possible recombination processes for the green emission are proposed and discussed in detail.

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References

  1. T. Aoki, Y. Hatanaka: Appl. Phys. Lett. 76, 3257 (2000)

    Article  ADS  Google Scholar 

  2. K. Vanheusden, W.L. Warren, C.H. Seager, D.R. Tallant, J.A. Voigt, B.E. Gnade: J. Appl. Phys. 79, 7983 (1996)

    Article  ADS  Google Scholar 

  3. A. van Dijken, E.A. Meulenkamp, D. Vanmaekelbergh, A. Meijerink: J. Lumin 87, 454 (2000)

    Article  Google Scholar 

  4. M. Liu, A.H. Kitai, P. Mascher: J. Lumin. 54, 35 (1992)

    Article  Google Scholar 

  5. B. Lin, Z. Fu, Y. Jia: Appl. Phys. Lett. 79, 943 (2001)

    Article  ADS  Google Scholar 

  6. S.A. Studenikin, N. Golego, M. Cocivera: J. Appl. Phys. 84, 2287 (1998)

    Article  ADS  Google Scholar 

  7. D. Hahn, R. Nink: Phys. Cond. Mater. 3, 311 (1965)

    Google Scholar 

  8. A.F. Kohan, G. Ceder, D. Morgan: Phys. Rev. B 61, 15019 (2000)

    Article  ADS  Google Scholar 

  9. D.C. Reynolds, D.C. Look, B. Jogai: Solid State Commun. 101, 643 (1997)

    Article  ADS  Google Scholar 

  10. F.H. Leiter, H.R. Alves, A. Hofstaetter: Phys. Status Solidi B 226, R4–R5 (2001)

    Google Scholar 

  11. A. van Dijken, E.A. Meulenkamp, D. Vanmaekelbergh, A. Meijerink: J. Lumin. 90, 123 (2000)

    Article  Google Scholar 

  12. T.K. Gupta, W.D. Straub, M.S. Ramanachalam, J.P. Schaffer, A. Rohatgi: J. Appl. Phys. 66, 6132 (1989)

    Article  ADS  Google Scholar 

  13. D. Fernandez-Hevia, J. de Frutos, A.C. Caballero, J.F. Fernandez: Appl. Phys. Lett. 83, 2692 (2003)

    Article  ADS  Google Scholar 

  14. H.C. Ong, J.Y. Dai, G.T. Du: Appl. Phys. Lett. 81, 277 (2002)

    Article  ADS  Google Scholar 

  15. A. Iribarren R. Castro-Rodríguez, F. Caballero-Briones, J.L. Pena: Appl. Phys. Lett. 74, 2957 (1999)

    Article  Google Scholar 

  16. M. Godieski, E.M. Goldys, M.R. Phillips, R. Langer, A. Barski: Appl. Phys. Lett. 73, 3686 (1998)

    Article  ADS  Google Scholar 

  17. J.D. Ye, S.L. Gu, S.M. Zhu, T. Chen, F. Qin, L.Q. Hu, R. Zhang, Y. Shi, Y.D. Zheng: J. Crystal Growth 243, 151 (2002)

    Article  ADS  Google Scholar 

  18. D. Walton, T.N. Rhodin, W. Rollins: J. Chem. Phys. 38, 2698 (1963)

    Article  ADS  Google Scholar 

  19. M. Ohring: The Materials Science of Thin Films (London Academic Press, 1992), Chapts. 4 and 5

  20. Y. Sun, J.B. Ketterson, G.K.L. Wong: Appl. Phys. Lett. 77, 2322 (2000)

    Article  ADS  Google Scholar 

  21. S.B. Zhang, S.H. Wei, A. Zunger: Phys. Rev. B 63, 075205 (2001)

    Article  ADS  Google Scholar 

  22. C.H. Seager, T.G. Castner: J. Appl. Phys. 49, 3879 (1978)

    Article  ADS  Google Scholar 

  23. T. Tsurumi, S. Nishizawa, N. Ohashi, T. Ohgaki: Jpn. J. Appl. Phys. 38, 3682 (1999)

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Nanjing University, Nanjing, 210093, P.R. China

    J.D. Ye, S.L. Gu, F. Qin, S.M. Zhu, S.M. Liu, X. Zhou, W. Liu, L.Q. Hu, R. Zhang, Y. Shi & Y.D. Zheng

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  1. J.D. Ye
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  2. S.L. Gu
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  3. F. Qin
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  4. S.M. Zhu
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  5. S.M. Liu
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  6. X. Zhou
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  7. W. Liu
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  8. L.Q. Hu
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  9. R. Zhang
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  10. Y. Shi
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  11. Y.D. Zheng
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Correspondence to J.D. Ye.

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PACS

68.55.Jk; 78.55.Et; 81.05.Dz

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Ye, J., Gu, S., Qin, F. et al. Correlation between green luminescence and morphology evolution of ZnO films. Appl. Phys. A 81, 759–762 (2005). https://doi.org/10.1007/s00339-004-2996-0

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  • DOI: https://doi.org/10.1007/s00339-004-2996-0

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