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Influence of PMVEMA-ES and 4-hydroxycoumarin hydrazone dyes on the physico-optical properties of PMMA coating films

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Abstract

Organic translucent coatings with high glossiness and homogeneous colour distribution are highly sought due to their aesthetic properties. The application of such organic coatings on glass substrates such as mirrors and windows will not only to protect these surfaces from damage, but also as decorative purpose. Herein, the work described the preparation of translucent poly(methyl methacrylate), PMMA-based coatings on glass surfaces. Since PMMA has low adhesion ability onto glass, poly(methyl vinyl ether-alt-maleic acid monoethyl ester), PMVEMA-ES is proposed as an additive to promote the adhesion of PMMA onto glass surfaces. Various 4-hydroxycoumarinhydrazone derivatives (CADs) were used as dyes. The physical, optical, and thermal properties of the prepared coatings were investigated and correlated. The addition of PMVEMA-ES and CAD dyes altogether enhanced the adhesion of PMMA onto glass surfaces, as evidenced from cross-hatch adhesion tests, supported with TGA and DSC results. The presence of substituents has limited influence on the optical properties of coatings. The dyes have also contributed to the overall increased in coating glossiness, especially when alkyl groups were present in the dye. Moreover, the CAD dyes can be good candidates as colourants for translucent coating films as they have low coating opacity and high (> 90%) transmittance beyond 500 nm.

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Funding

The authors would like to express gratitude to the Ministry of Higher Education (MOHE) Malaysia for providing the Fundamental Research Grant Scheme FP031-2014B. The authors would also like to thank University of Malaya for providing the Faculty Research Grant (GPF048B-2018). We acknowledge the financial support from the Ministry of Education Malaysia and the SLAB fellowship scheme from the University of Malaya for funding the Ph. D. studies of Shameer Hisham.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

    Shameer Hisham, Hairul Anuar Tajuddin & Norazilawati Muhamad Sarih

  2. Department of Physics, Centre for Ionics, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia

    Mohamad Fitri Zaqwan Salim, Lidya Sulaiman & Zul Hazrin Zainal Abidin

  3. University of Lille Campus Scientific City, 59650, Villeneuve d’Ascq, France

    Fatima Zahra Chaibi

  4. Department of Civil Engineering Technology, Faculty of Engineering Technology, Universiti Tun Hussein Onn Malaysia, Edu Hub Pagoh, 84600, Panchor, Johor, Malaysia

    Amnani Abu Bakar

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  1. Shameer Hisham
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Correspondence to Norazilawati Muhamad Sarih.

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Hisham, S., Salim, M.F.Z., Chaibi, F.Z. et al. Influence of PMVEMA-ES and 4-hydroxycoumarin hydrazone dyes on the physico-optical properties of PMMA coating films. Polym. Bull. 79, 8669–8693 (2022). https://doi.org/10.1007/s00289-021-03925-1

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