Cation disordering in heat-treated anthophyllites through oxidation and dehydrogenation

Abstract 

Oxidation and dehydrogenation processes for heat-treated anthophyllites were investigated using Mössbauer and infrared spectroscopy. At temperatures from 350°C to about 650°C, Fe²⁺ at the M1 and M3 sites oxidizes, yielding Fe³⁺ + one electron. A proton from the (OH)^– is liberated and combines with this electron to form a hydrogen atom; and some Fe²⁺ ions at the M2 and M4 sites exchange with Mg at the M1 and M3 sites and then are oxidized in a similar way; at higher temperature, OH remaining in the (MgMgMg/Fe³⁺)-(OH)-configuration are dehydrogenated by decomposition of the amphibole to orthopyroxene and quartz. During oxidation and dehydrogenation of anthophyllite, there is disordering of Mg and Fe at the M1, M2, M3 and M4 sites in all samples studied. When all Fe²⁺ is oxidized, the site occupancies of at the M4 and M1, M2, M3 sites become identical, indicating that Mg and Fe³⁺ are completely disordered at these sites.