Boron substitution in diopside evaluated through ¹¹B nuclear reaction analysis

Abstract

 Nuclear reaction analyses on boron in flux-grown Me³⁺- and Na⁺-doped diopside crystals utilising the ¹¹B(p,2α)⁴He reaction in conjunction with EMP analyses for major elements and optical absorption spectroscopy for determination of Me-valence state distributions show that appreciable amounts of B may enter the diopside lattice in crystals produced in Na₂B₄O₇ fluxes. The results indicate that the substitution ^[6]Me^3+[4]B^3+[6]Mg²⁺ ₋₁ ^[4]Si⁴⁺ ₋₁ operates in the present diopside samples in addition to the coupled substitution ^[6]Me^3+[8]Na^+[6]Mg²⁺ ₋₁ ^[8]Ca²⁺ ₋₁. The specific NRA technique applied allows for quantitative, high resolution (ca. 5 μm) B analyses at ppm level as well as high-resolution and high-contrast imaging of B-concentration patterns in minerals. The estimated detection limit and relative error of the B analyses are 10 ppm and 5–10%, respectively.