Abstract
In the present review work, it is proposed to carry out a bibliographic analysis about the thermal behaviour of the dolomitic mineral. The state of the art of dolomite currently indicates a growing use as a refractory material due to the cheaper alternative it represents compared to other materials such as magnesium oxide. The importance of dolomite apart from its application in the steel industry lies in the fact that it has expanded to other industrial fields such as the production of catalysts, catalyst supports, and industrial effluent purification materials. In these and other applications, understanding the thermal behaviour of the material is necessary to evaluate the feasibility of application. In this review, the different experimental proposals developed over time in terms of thermal behaviour are studied, emphasizing the reaction mechanisms that have been proposed in different investigations.
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References
Richmond C (2004) Refractories handbook. Marcel Dekker Inc., EUA, pp 183–189
Mehmood M, Yaseen M, Khan EU, Khan MJ (2018) Dolomite and dolomitization model-a short review. Int J Hydrology 2:549–553
Warren J (2000) Dolomite: occurrence, evolution and economically important associations. Earth Sci Rev 52:1–81
Kim J, Kimura Y, Puchala B, Yamazaki T, Becker U, Sun W (2023) Dissolution enables dolomite crystal growth near ambient conditions. Science 382:915–920
Pina CM, Pimentel C (2017) Formation of dolomite analogues at ambient conditions. Dolomite: formation, characteristics and environmental impact. Nova Science Publishers, Incorporated, pp 115–140
Botia PD, Estrada DA (1972) Boletín de la Sociedad Española de Cerámica y Vidrio 11:235–238Estudio de la constitución y propiedades de un sinter a base de circón-dolomía
Zúñiga M, de Novales JL (1989) Evolución De Los revestimientos de dolomía en las cucharas de las acerías españolas. Boletín De La Sociedad Española De Cerámica Y Vidrio 28:371–378
Pokrovsky OS (2017) Dolomite as enigmatic sedimentary mineral and important technological material. Formation, Characteristics and Environmental Impact Nova Science, Incorporated;, Dolomite, pp ix–xiv
Zhang H, Zhao H, Chen J, Li J, Yu J, Nie J (2013) Defect study of MgO-CaO material doped with CeO2. Advances in Materials Science and Engineering. 2013
Qiu G-b, Peng B, Yue C-s, Guo M, Zhang M (2016) Properties of regenerated MgO–CaO refractory bricks: impurity of iron oxide. Ceram Int 42:2933–2940
Peng C, Li N, Han B (2009) Effect of zircon on sintering, composition and microstructure of magnesia powders. Sci Sinter 41:11–17
Lee WE, Rainforth M (1994) Ceramic microstructures: property control by processing. Springer Science & Business Media, pp 453–507
Diwan V, Sar SK, Biswas S, Lalwani R (2020) Adsorptive extraction of uranium (VI) from aqueous phase by dolomite. Groundw Sustainable Dev :100424
Pehlivan E, Özkan AM, Dinç S, Parlayici Ş (2009) Adsorption of Cu2 + and Pb2 + ion on dolomite powder. J Hazard Mater 167:1044–1049
Xu T, Wang X, Xiao B, Liu W (2021) Single-step production of hydrogen-rich syngas from toluene using multifunctional Ni-dolomite catalysts. Chem Eng J 425:131522
Islam MW (2020) A review of dolomite catalyst for biomass gasification tar removal. Fuel 267:117095
Hatmaker P (1931) Utilization of Dolomite and high-magnesium limestone. US Department of the Interior, Bureau of Mines
Luna GCV (2019) Estudio Del Potencial De Rocas carbonáticas dolomíticas en El Departamento Jáchal, San Juan: la perspectiva de desarrollo a través del corredor bioceánico [Tésis De Maestría]. Universidad Nacional de San Juan, San Juan
Sugita K (2008) Historical overview of refractory technology in the steel industry. Shinnittetsu Giho 388:8
Semmeq A, Foucaud Y, El Yamami N, Michailovski A, Lebègue S, Badawi M (2021) Hydration of magnesite and dolomite minerals: new insights from ab initio molecular dynamics. Colloids Surf a 631:127697
Badapalli PK, Kottala RB, Sree PP, Rajasekhar M (2022) Occurrence and structures of dolomites in North Eastern part of Anantapur district, and their use in engineering materials. Materials Today: Proceedings. 50:1005–10
Li Z, Bowman A, Rayniak A, Xu S (2024) Anionic Dye Alizarin Red S removal using heat-treated Dolomite. Crystals 14:187
Darweesh HH (2001) Building materials from siliceous clay and low grade dolomite rocks. Ceram Int 27:45–50
Subagjo, Wulandari W, Adinata PM, Fajrin A (2017) Thermal decomposition of dolomite under CO2-air atmosphere. AIP Conference Proceedings: AIP Publishing LLC; p. 040006
Wiedemann H-G, Bayer G (1987) Note on the thermal decomposition of dolomite. Thermochimica Acta 121:479–485
Engler P, Santana MW, Mittleman ML, Balazs D (1989) Non-isothermal, in situ XRD analysis of dolomite decomposition. Thermochimica Acta 140:67–76
De Aza AH, Rodríguez MA, Rodríguez JL, De Aza S, Pena P, Convert P et al (2002) Decomposition of dolomite monitored by neutron thermodiffractometry. J Am Ceram Soc 85:881–888
Fang QF, Zhang HW, Guo Y (2011) Thermal decomposition of dolomite. Trans Tech Publ, Advanced Materials Research, pp 617–619
Bogahawatta V, Abdul-Jaleel A, Behbehani M (2004) The heat treatment and particle size effects in the thermal decomposition of dolomite for separation of constituents. Mineral Process Extractive Metall 113:111–117
Smith JW, Johnson DR, Müller-Vonmoos M (1974) Dolomite for determining atmosphere control in thermal analysis. Thermochimica Acta 8:45–56
Santani M, Dollimore D, Wilburn F, Alexander K (2001) Isolation and idenfication of the intermediate and final products in the thermal decomposition of dolomite in an atmosphere of carbon dioxide. Thermochim Acta 367:285–295
Otsuka R (1986) Recent studies on the decomposition of the dolomite group by thermal analysis. Thermochimica Acta 100:69–80
McIntosh R, Sharp J, Wilburn F (1990) The thermal decomposition of dolomite. Thermochimica Acta 165:281–296
Sadik C, Moudden O, El Bouari A, El Amrani I-E (2016) Review on the elaboration and characterization of ceramics refractories based on magnesite and dolomite. J Asian Ceam Soc 4:219–233
Fazeli A, Tareen J (1991) Thermal decomposition of rhombohedral double carbonates of dolomite type. J Therm Anal Calorim 37:2605–2611
Ptáček P, Šoukal F, Opravil T (2021) Thermal decomposition of ferroan dolomite: a comparative study in nitrogen, carbon dioxide, air and oxygen. Solid State Sci 122:106778
Kristóf-Makó É, Juhász A (1999) The effect of mechanical treatment on the crystal structure and thermal decomposition of dolomite. Thermochimica Acta 342:105–114
Olszak-Humienik M, Jablonski M (2015) Thermal behavior of natural dolomite. J Therm Anal Calorim 119:2239–2248
Dollimore D, Dunn J, Lee Y, Penrod B (1994) The decrepitation of dolomite and limestone. Thermochimica Acta 237:125–131
Haul R, Markus J (1952) On the thermal decomposition of dolomite. IV. Thermogravimetric investigation of the dolomite decomposition. J Appl Chem 2:298–306
Beruto D, Vecchiattini R, Giordani M (2003) Solid products and rate-limiting step in the thermal half decomposition of natural dolomite in a CO2 (g) atmosphere. Thermochimica Acta 405:183–194
Caceres P, Attiogbe E (1997) Thermal decomposition of dolomite and the extraction of its constituents. Miner Eng 10:1165–1176
Kök M, Smykatz-Kloss W (2008) Characterization, correlation and kinetics of dolomite samples as outlined by thermal methods. J Therm Anal Calorim 91:565–568
Shahraki BK, Mehrabi B, Dabiri R (2009) Thermal behavior of Zefreh Dolomite mine (Central Iran). J Min Metall B: Metall 45:35–44
Gunasekaran S, Anbalagan G (2007) Spectroscopic study of phase transitions in dolomite mineral. Journal of Raman Spectroscopy: An International Journal for Original Work in all aspects of Raman Spectroscopy, including higher order processes, and also Brillouin and. Rayleigh Scattering 38:846–852
Gunasekaran S, Anbalagan G (2007) Thermal decomposition of natural dolomite. Bull Mater Sci 30:339–344
Lavat AE, Grasselli MC, Lovecchio EG (2015) The firing steps and phases formed in Mg–Zr–Al refractory dolomite-based materials. Ceram Int 41:2107–2115
Kashaninia F, Sarpoolaky H, Bagheri A, Naghizadeh R, Zamanipour M, IMPROVING, HYDRATION RESISTANCE OF MAGNESIA-DOLOMA REFRACTORIES BYIRON OXIDE ADDITION (2011) Iran J Mater Sci Eng 8:34–40
Cardarelli F Ceramics, refractories, and glasses. Materials handbook: a concise desktop reference 2008:593–689
McCauley R, Johnson L (1991) Decrepitation and thermal decomposition of dolomite. Thermochimica Acta 185:271–282
Rodriguez-Navarro C, Kudlacz K, Ruiz-Agudo E (2012) The mechanism of thermal decomposition of dolomite: new insights from 2D-XRD and TEM analyses. Am Mineral 97:38–51
Munawaroh F, Baqiya MA, Arifin Z, Triwikantoro T (2023) Thermal Decomposition Analysis of Indonesian Natural Dolomite in Air. Appl Mech Mater 916:19–24
Aliyu WA, Hossain MI, Specht E Numerical Approach in Determination of Thermophysical Material Properties in Decomposition of Lumpy Dolomite Particles. Proceedings of the 9th International Conference on Fluid Flow, Heat and Mass Transfer (FFHMT’22), Niagara Falls, Canada2022
Resio L (2023) Dolomite thermal behaviour: a proposal to establish a definitive decomposition mechanism in a convective air atmosphere. Open Ceram 15:100405
Qian H, Kai W, Hongde X (2019) A novel perspective of dolomite decomposition: elementary reactions analysis by thermogravimetric mass spectrometry. Thermochimica Acta 676:47–51
Carter CB, Norton MG (2007) Ceramic materials: science and engineering. Springer, pp 15–29
Etayo Rillo F, Romeo Giménez LM (2011) Simulación del proceso de carbonatación–calcinación para captura de CO2. Estrategias de mejora del proceso
Housecroft C, Sharpe AG (2005) Inorganic Chemistry. Second edition ed: Prentice Hall
MacKenzie K, Meinhold R (1993) Thermal decomposition of dolomite (calcium magnesium carbonate) studied by 25Mg solid-state nuclear magnetic resonance. Thermochimica Acta 230:331–337
West AR (2022) Solid state chemistry and its applications. Wiley
MacKenzie K, Meinhold R (1994) 25Mg nuclear magnetic resonance spectroscopy of minerals and related and inorganics: a survey study. Am Mineral 79:250–260
Samtani M, Dollimore D, Alexander K (2002) Comparison of dolomite decomposition kinetics with related carbonates and the effect of procedural variables on its kinetic parameters. Thermochimica Acta 392:135–145
Ogilvie JF (2013) La naturaleza del enlace químico 2013¡ No existe tal cosa llamada orbital! Revista de Ciencia y Tecnología Vol 28 Núm 1–2
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L.C. Resio: Conceptualization; Data curation; Formal analysis; Investigation; Methodology; Supervision; Validation; Visualization; Roles/Writing - original draft; Writing - review & editing.
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Resio, L. Dolomite thermal behaviour: A short review. Phys Chem Minerals 51, 19 (2024). https://doi.org/10.1007/s00269-024-01272-x
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DOI: https://doi.org/10.1007/s00269-024-01272-x