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Portable smartphone-assisted ratiometric fluorescent test paper based on one-pot synthesized dual emissive carbon dots for visualization and quantification of mercury ions

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Abstract

Dual-emissive fluorescent carbon dots (CDs) were prepared through the solvothermal method with citric acid and urea as raw materials and dimethylformamide as the solvent. Two emission peaks were observed at 465 nm and 630 nm. Hg2+ could selectively quench the fluorescence at 630 nm, but the fluorescence intensity at 465 nm was less affected. Accordingly, a ratiometric fluorescence sensor for Hg2+ detection was developed, with a linear detection range of 0.5–40 μM and a limit of detection (LOD) of 37 nM. The dual-emissive CDs were loaded on the surface of the filter paper to fabricate Hg2+ detection test paper. The color of the test paper could be changed from pink purple to blue by the addition of Hg2+, and thus the qualitative and quantitative detection of Hg2+ could be realized. The concentration distinguishable by the naked eye reached 50 μM, and the quantitative detection range was 5–10,000 μM. This method shows excellent selectivity for Hg2+ and can be used to detect Hg2+ in real water samples, providing a highly potential sensing platform for rapid on-site detection of mercury ions.

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Funding

This work was supported by the National Natural Science Foundation of China (Nos. 21804117), the Key Scientific and Technological Project of Henan Province (232102310151), the Youth Fund Project of Xinyang Normal University (2022-QN-039), and the Nanhu Scholars Program for Young Scholars of Xinyang Normal University.

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  1. College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China

    Mengyuan He, Bo Zheng, Yuanhang Wei, Yu Xiao, Lixin Kou & Ning Shang

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  1. Mengyuan He
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  2. Bo Zheng
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He, M., Zheng, B., Wei, Y. et al. Portable smartphone-assisted ratiometric fluorescent test paper based on one-pot synthesized dual emissive carbon dots for visualization and quantification of mercury ions. Anal Bioanal Chem 415, 5769–5779 (2023). https://doi.org/10.1007/s00216-023-04858-6

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