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The influence of NbB inoculation on dendritic spacing and grain size of an aluminum 2017 alloy at different cooling rates

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Abstract

The Al-4Cu-Mg 2017 alloy is a significant Al extrusion alloy. As a result, knowing its behavior in terms of grain refining during casting stages becomes critical for the next processing steps. In the face of the shortcomings exhibited by TiB inoculants, the addition of NbB could be tested for this alloy as an alternative. The present article investigates the effects of NbB addition on grain size (GS), on secondary dendrite arm spacing (λ2), and on hardness of centrifugally cast (CC) and directionally solidified (DS) 2017 alloy samples, encompassing a broad range of cooling rates and solidification conditions. The λ2 did not change much as a result of the NbB inoculation, either for DS or CC samples, decreasing from 7.2 to 7.0 μm in the case of the 4-mm-thick CC samples and increasing from 17.0 to 22.5 μm in the case of the DS samples. The average GS, on the other hand, reduced from 293 to 136 μm for the NbB-containing CC samples and from 756 to 313 μm for the DS samples associated with cooling rates of 10 K/s. Both processes can achieve nearly the same GS reduction ratio, namely 2.2 for the CC and 2.5 for the DS. This implies that GS reduction ratio was barely affected if similar cooling rates were compared while taking the experimental range for both processes into account. Moreover, Vickers hardness results revealed that GS had little influence on this property for both alloys studied. The experimentally obtained data translated a variety of solidification condition outlines for the 2017 alloy. Through this data, the understanding of an alternative inoculant in a significant Al alloy series advanced significantly.

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References

  1. Saï K, Taleb L, Cailletaud G (2012) Numerical simulation of the anisotropic behavior of 2017 aluminum alloy. Comput Mater Sci 65:48–57

    Article  Google Scholar 

  2. Giuliano G (2016) On the constitutive equation of AA2017 aluminium alloy at high temperature. Manuf Lett 10:10–13

    Article  Google Scholar 

  3. Akar S, Kinchin C, Kurup P (2022) Techno-economic analysis for shear assisted processing and extrusion (ShAPE) of high-strength aluminum alloys. www.nrel.gov/publications. Accessed 22 August 2022

  4. Casting (2008) Vol 15, ASM Handbook, ASM International, p 2002

  5. Liu Z (2017) Review of grain refinement of cast metals through inoculation: theories and developments. Metall Mater Trans A Phys Metall Mater Sci 48:4755–4776

    Article  Google Scholar 

  6. Turnbull D, Vonnegut B (1952) Ind Eng Chem 44:1292

    Article  Google Scholar 

  7. Crosley PB, Douglas AW, Mondolfo LF (1968) The Solidification of Metals, Iron and Steel Inst. Publ. No. 110, London, p 10

  8. Hellawell A (1979) Solidification and casting of metals, The Metals Society, London

  9. Ding J, Cui C, Sun Y, Shi J, Cui S, Ma Q (2018) Preparation of in Situ Al3Nb-NbB2-NbC/Al inoculant and its effect on microstructures and properties of weldable Al-Cu-Mn alloy. Mater Sci Eng A 738:273–282

    Article  Google Scholar 

  10. Bolzoni L, Nowak M, Hari Babu N (2015) Grain refinement of Al-Si Alloys by Nb-B inoculation Part II: application to commercial alloys. Mater Des 66:376–383

    Article  Google Scholar 

  11. Bolzoni L, Hari Babu N (2020) On the grain refining efficacy of Ti-free hypoeutectic AlSi via AlTiB, AlB and AlNbB chemical inoculation. J Alloys Compd 817:817

    Article  Google Scholar 

  12. de Albuquerque Sousa SM, Saldanha FE, de Gouveia GL, Garcia A, Spinelli JE (2022) NbB refining capability: effects of slow and rapid solidification on dendritic spacings and grain sizes of a 6201 alloy. Mater Lett 315:131960

    Article  Google Scholar 

  13. Li Y, Jiang Y, Liu B, Luo Q, Hu B, Li Q (2021) Understanding grain refining and anti Si-poisoning effect in Al-10Si/Al-5Nb-B system. J Mater Sci Technol 65:190–201

    Article  Google Scholar 

  14. Li J, Hage FS, Ramasse QM, Schumacher P (2021) The nucleation sequence of α-Al on TiB2 particles in Al-Cu Alloys. Acta Mater 206:116652

    Article  Google Scholar 

  15. Ghassemali E, Riestra M, Bogdanoff T, Kumar BS, Seifeddine S (2017) Hall-Petch equation in a hypoeutectic Al-Si cast alloy: grain size vs. secondary dendrite arm spacing. Procedia Eng 207:19–24

    Article  Google Scholar 

  16. Easton M, Davidson C, StJohn D (2011) Grain morphology of As-cast wrought aluminium alloys. Mater Trans, The Japan Institute of Metals and Materials 52:842–847

  17. Gündüz M, Çadirli E (2002) Directional solidification of aluminium–copper alloys. Mater Sci Eng A 327:167–185

    Article  Google Scholar 

  18. ASTM E112–13 (2015) - Standard Test Methods for Determining Average Grain Size, ASTM International, West Conshohocken, PA, https://www.astm.org

  19. Bolzoni L, Hari Babu N (2016) Engineering the heterogeneous nuclei in Al-Si alloys for solidification control. Appl Mater Today 5:255–259

    Article  Google Scholar 

  20. de Albuquerque Sousa SM, de Gouveia GL, Spinelli JE (2022) Evaluating grain size, dendritic scale, and tensile properties of a NbB-inoculated 6201 alloy using solidification rate. Mater Sci Eng A 835:142680

    Article  Google Scholar 

  21. de Gouveia GL, Garcia A, Spinelli JE (2021) Tailoring microstructure and tensile properties of Mg-Si alloys varying solidification cooling rate and Si content. Mater Sci Eng A 825:141905

    Article  Google Scholar 

  22. Bogno AA, Khatibi PD, Henein H et al (2016) Quantification of primary dendritic and secondary eutectic nucleation undercoolings in rapidly solidified hypo-eutectic Al-Cu droplets. Metall Mater Trans A 47:4606–4615

    Article  Google Scholar 

  23. Bedel M et al (2016) Dendrite growth morphologies in rapidly solidified Al-4.5wt.%Cu droplets. IOP Conf Ser: Mater Sci Eng 117:012055

    Article  Google Scholar 

  24. Ferreira AF, Paradela KG, Felipe Junior P, Zilmar AA, Garcia, (2017) Phase-field simulation of microsegregation and dendritic growth during solidification of hypoeutectic Al-Cu alloys. Mater Res 20:423–429

    Article  Google Scholar 

  25. Costa AT, Moreira AL, Moutinho DJ, Dias M, Ferreira IL, Spinelli JE, Rocha OL, Garcia A (2015) Growth direction and Si alloying affecting directionally solidified structures of Al-Cu-Si alloys. Mater Sci Technol 31:1103–1112

    Article  Google Scholar 

  26. Santos CA, Siqueira CA, Garcia A, Quaresma JMV, Spim JA (2004) Metal–mold heat transfer coefficients during horizontal and vertical unsteady-state solidification of Al–Cu and Sn–Pb alloys. Inverse Probl Sci Eng 12:279–296

    Article  Google Scholar 

  27. Kim H, Cho I, Shin J, Lee S, Moon B (2005) Solidification parameters dependent on interfacial heat transfer coefficient between aluminum casting and copper mold. ISIJ Int 45:192–198

    Article  Google Scholar 

  28. Grażyna MN, Gancarczyk K, Nowotnik A, Dychtoń K, Boczkal G (2021) Microstructure and properties of As-cast and heat-treated 2017A aluminium alloy obtained from scrap recycling. Materials 14:89

    Article  Google Scholar 

  29. Kurz W, Fisher DJ (1990) Fundamentals of solidification, 3rd ed. Trans Tech Publications, Aedermannsdorf, Switzerland

  30. Bouchard D, Kirkaldy JS (1997) Prediction of dendrite arm spacings in unsteady-and steady-state heat flow of unidirectionally solidified binary alloys. Metall Mater Trans B 28:651–663

    Article  Google Scholar 

  31. Bouchard D, Kirkaldy JS (1996) Scaling of intragranuiar dendritic microstructure in ingot solidification. Metall Mater Trans B 27B:101–113

    Article  Google Scholar 

  32. Rocha OFL, Siqueira C, Garcia A (2003) Heat flow parameters affecting dendrite spacings during unsteady-state solidification of Sn-Pb and Al-Cu alloys. Metall and Mater Trans A 34A:995–1006

    Article  Google Scholar 

  33. Sharp RM, Hellawell A (1969) The microscopy and composition of quenched solid-liquid interfaces. J Cryst Growth 5:155–161

    Article  Google Scholar 

  34. Gouveia GL, Gomes LF, Cheung N, Garcia A, Spinelli JE (2021) Mechanical properties, microstructural features, and correlations with solidification rates of Al–Cu–Si ultrafine eutectic alloys. Adv Eng Mater 23:2001177

    Article  Google Scholar 

  35. Hunt JD (1984) Steady state columnar and equiaxed growth of dendrites and eutectic. Mater Sci Eng 65:75–83

    Article  Google Scholar 

  36. Quested TE (2004) Understanding mechanisms of grain refinement of aluminium alloys by inoculation. Mater Sci Tech 20:1357–1369

    Article  Google Scholar 

Download references

Funding

The authors acknowledge FAPESP (grants 2019/23673–7 and 2020/02697–2) and CNPq. This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior–Brasil (CAPES)-Finance Code 001.

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J.E.S. elaborated the study conception and design. A.S.S., S.M.A.S., and G.L.G. prepared the materials, collected the data, and analyzed the results. J.E.S. and S.M.A.S. elaborated the first draft of the manuscript, and all authors commented on previous versions of the manuscript. J.E.S and A.G. verified the data analyses and reviewed and edited the final manuscript. All authors read and approved the final manuscript.

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Correspondence to José Eduardo Spinelli.

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Silva, A.S., de Albuquerque Sousa, S.M., de Gouveia, G.L. et al. The influence of NbB inoculation on dendritic spacing and grain size of an aluminum 2017 alloy at different cooling rates. Int J Adv Manuf Technol 125, 5681–5696 (2023). https://doi.org/10.1007/s00170-023-11104-x

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  • DOI: https://doi.org/10.1007/s00170-023-11104-x

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