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The Cr−Si (Chromium-Silicon) system

  • Cr−Si
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Journal of Phase Equilibria

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Cited References

  • 11Fri: R. Frilley, “Alloys of Chromium and Silicon,”Rev. Metall., 8, 476 (1911); quoted by [36And]. (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Article  Google Scholar 

  • 33Bor: B. Boren, “X-Ray Investigation of Alloys of Silicon with Chromium, Manganese, Cobalt and Nickel,”Ark. Kem., Min. Geol. 11A, (10), 2–10 (1933); quoted by [36And]. (Equi Diagram, Crys Structure; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 36And: A.G.H. Andersen and E.R. Jette, “X-Ray Investigation of the Iron-Chromium-Silicon Phase Diagram,”Trans. ASM, 24, 375–419 (1936). (Experimental)

    Google Scholar 

  • 53Kie: R. Kieffer, F. Benesovsky, and H. Schroth, “Contribution to the System Chromium-Silicon and Silicide Mixtures,”Z. Metallkd., 44, 437–442 (1953) in German. (Equi Diagram, Crys Structure; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 53Now: H. Nowotny, H. Schroth, R. Kieffer, and F. Benesovsky, “The Crystallographic Behavior of Some Silicide Systems of Transition Metals,”Monatsh. Chem., 84, 579–584 (1953). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 55Par: E. Parthe, H. Nowotny, and H. Schmid, “Structural Determination of Silicides,”Monatsh. Chem., 86, 385–396 (1955) in German. (Crys Structure; Experimental)

    Article  Google Scholar 

  • 56Dau: C.H. Dauben, D.H. Templeton, and C.E. Myers, “The Crystal Structure of Cr5Si3,”J. Phys. Chem., 60, 443–445 (1956). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 60Gel: P.V. Geld and Y.M. Gertman, “The First Heats of Solution of Molten Transition Metals (4 Series) in Liquid Silicon,”Phys. Met. Metallogr., (U.S.S.R.), 10(2), 137–139 (1960). (Thermo; Experimental)

    Google Scholar 

  • 60Tru: V.P. Trusova, V.S. Kutsev, and B.F. Ormont, “Chromium Disilicide, Its Range of Homogeneity and Electrical Properties,”Russ. J. Inorg. Chem., 5(5), 538–540 (1960). (Crys Structure; Experimental)

    Google Scholar 

  • 61Gol1: H.J. Goldschmidt and J.A. Brand, “The Constitution of the Chromium-Niobium-Silicon System,”J. Less-Common Met., 3, 34–43 (1961). (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Article  Google Scholar 

  • 61Gol2: Yu.M. Golutin and C.K. Liang, “Heats of Formation, Heat Contents, and Heat Capacities of Chromium Silicides,”Russ. J. Phys. Chem., 35(1), 62–67 (1961). (Thermo; Experimental)

    Google Scholar 

  • 61Nik: E.N. Nikitin, “Thermoelectric Properties of the Silicon-Chromium System,”Sov. Phys. Solid State, 2(11), 2389–2392 (1961). (Experimental)

    Google Scholar 

  • 62Dud: L.D. Dudkin and E.S. Kuznettova, “Investigation of the Electrophysical Properties of Alloys Based on Semiconductor Disilicides of Chromium and Manganese,”Sov. Powder Metall. Met. Ceram., 12(6), 20–31 (1962). (Experimental)

    Google Scholar 

  • 63Dub: L.B. Dubrovskaya and P.V. Geld, “Boundaries of the Homogeneity Region and Nature of Chromium Disilicide,”Russ. J. Inorg. Chem., 8(7), 854–857 (1963). (Crys Structure; Experimental)

    Google Scholar 

  • Indicates key paper65Kal: G.I. Kalishevich, P.V. Geld, and R.P. Krentsis, “Standard Heat Capacities, Entropies, and Enthalpies of Silicon, Chromium, and Chromium Silicides,”Russ. J. Phys. Chem., 39 (12), 1602–1603 (1965). (Thermo; Experimental)

    Google Scholar 

  • 67Vor: B.K. Voromov, L.D. Dudkin, N.I. Kuryuchina, and N.N. Trusova, “Investigation of the Cr−Si System in the Disilicide Region,”Sov. Powder Metall. Met. Ceram., 49(1), 73–80 (1967). (Experimental)

    Google Scholar 

  • Indicates key paper68Cha: Y.A. Chang, “Phase Relationships in the System Chromium-Silicon,”Trans. Metall. AIME, 242, 1509–1515 (1968). (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 70Ben: N.T. Bendik, V.S. Garnyk, and L.S. Milerskii, “Precipitation Kinetics of Solid Solutions of Chromium in Silicon,”Sov. Phys. Solid State, 12(1), 150–154 (1970). (Experimental)

    Google Scholar 

  • 71Ere: V.N. Eremenko, G.M. Lukashenko, and V.R. Sidorko, “Thermodynamic Properties of Chromium Disilicide and Monosilicide,”Russ. J. Phys. Chem., 45(8), 1133–1134 (1971). (Thermo; Experimental)

    Google Scholar 

  • 71Koc: Yu.A. Kocherzhinsky, “Differential Thermocouple up to 2450 °C and Thermographic Investigation of Refractory Silicides,”Therm. Anal., Proc. 3rd ICTA DAVOS, 1, 549–559 (1971). (Equi Diagram; Experimental; Indicates presence of a phase diagram)

    Google Scholar 

  • 71Pya: T.M. Pyatkova, V.I. Surikov, A.K. Shtols, V.L. Zagrayazhsky, and P.V. Geld, “Range of Homogeneity of the Beta Phase of the Cr−Si System and Mutual Solubility of Chromium and Vanadium Silicides,”Izv. Akad. Nauk SSSR, Neorg. Mater., 7(10), 1755–1758 (1971) in Russian. (Crys Structure; Experimental)

    Google Scholar 

  • 72Ere: V.N. Eremenko, G.M. Lukashenko, V.R. Sidorko, and A.M. Kharkova, “Thermodynamic Properties of Chromium Silicides,”Poroshk. Metall., 12(7), 61–65 (1972) in Russian. (Thermo; Experimental)

    Google Scholar 

  • 73Rie: J.P. Riegert, A. Vermande, and I. Ansara, “Thermodynamic Properties of Cr−Si Alloys at 1900 °C,”High Temp.-High Pressures, 5, 231–235 (1973) in French. (Thermo; Experimental)

    Google Scholar 

  • 74Wur: W. Wurker, K. Roy, and J. Hesse, “Diffusion and Solid Solubility of Chromium in Silicon,”Mater. Res. Bull., 9, 971–978 (1974). (Experimental)

    Article  Google Scholar 

  • 75Cha: T.G. Chart, “Thermodynamic Properties of the Tungsten-Silicon and Chromium-Silicon Systems,”Met. Sci., 9, 504–509 (1975). (Thermo; Experimental)

    Article  Google Scholar 

  • 75Sur: V.I. Surikov, G.I. Kalishevich, and P.V. Geld, “Thermodynamic Characteristics of Trichromium Silicide, Trichromium Germanide, Trivanadium Silicide, and Trivanadium Germanide,”Russ. J. Phys. Chem., 49(2), 326–327 (1975). (Thermo; Experimental)

    Google Scholar 

  • 76Esi: Yu.O. Esin, P.V. Geld, Yu.V. Gorbunov, V.I. Vasilev, and A.B. Galeznik, “Enthalpies of Formation of Molten Chromium-Silicon Alloys,”Russ. J. Phys. Chem., 50(10), 1584–1585 (1976). (Thermo; Experimental)

    Google Scholar 

  • 77Bar: I. Barin, O. Knacke, and O. Kubaschewski,Thermochemical Properties of Inorganic Substances (Supplement), Springer-Verlag, New York (1977). (Thermo; Compilation)

    Book  Google Scholar 

  • 78Ast: H.U. Astrom, G. Benediktsson, and K.V. Rao, “Latent Heat Studies of Magnetic Transitions in Dilute CrFe and CrSi Alloys,”J. Phys., 39(C6), 785–787 (1978). (Magnetism, Thermo; Experimental)

    Google Scholar 

  • 79Jur: M. Jurisch and G. Behr, “Growth and Perfections of Cr3Si Single Crystals,”Acta Phys. Acad. Sci. Hung., 47(1–3), 201–207 (1979). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 80Col: E.G. Colgan, B.Y. Tsaur, and J.W. Mayer, “Phase Formation in Cr−Si Thin Film Interactions,”Appl. Phys. Lett., 37(10), 938–940 (1980). (Experimental)

    Article  ADS  Google Scholar 

  • 82Ben: G. Benediktsson, L. Hedman, H.U. Astrom, and K.V. Rao, “On Magnetic First-Order Transitions in Cr−Rich Cr−Fe and Cr−Si Alloys: Latent Heat and Susceptibility Studies,”J. Phys. F (Met. Phys.), 12, 1439–1452 (1982). (Magnetism, Thermo; Experimental)

    Article  ADS  Google Scholar 

  • 82Bot: A.P. Botha and R. Pretorius, “Co2Si, CrSi2, ZrSi2, and TiSi2 Formation Studied by a Radioactive31Si Marker Technique,”Thin Solid Films, 93, 127–133, (1982). (Experimental)

    Article  ADS  Google Scholar 

  • 82End: Y. Endoh, J. Mizuki, and Y. Ishikawa, “The First-Order Phase Transition from Paramagnetic to Commensurate S.D.W. State in Dilute CrSi Alloys,”J. Phys. Soc. Jpn., 51(9), 2826–2832 (1982). (Magnetism; Experimental)

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Department of Materials Science and Engineering, University of Florida, 32611, Gainesville, FL

    A. B. Gokhale & G. J. Abbaschian

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  1. A. B. Gokhale
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  2. G. J. Abbaschian
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Additional information

This program was supported by ASM, under Grant No. FG 101-1 to the University of Florida. Thermodynamic calculations were made by using the computer program developed by Drs. A.D. Pelton, W.T. Thompson, and C.W. Bale, at the McGill University, Montréal, Québec. Literature searched through 1983. Professor Abbaschian in the ASM/NBS Data Program Category Editor for binary silicon alloys.

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Gokhale, A.B., Abbaschian, G.J. The Cr−Si (Chromium-Silicon) system. JPE 8, 474–484 (1987). https://doi.org/10.1007/BF02893156

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