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The Ag−S (Silver-Sulfur) system

  • Ag−S
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Bulletin of Alloy Phase Diagrams

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Cited References

  • 06Fri: K. Friedrich and A. Lerouz, “Silver and Silver Sulfide,”Metallurgie, 11, 361–371 (1906) in German (Equi Diagram)

    Google Scholar 

  • 12Jae: F.M. Jaeger and H.S. Van Klooster, “Silver and Sulfur,”Z. Anorg. Chem., 78, 248–252 (1912) in German. (Equi Diagram)

    Article  Google Scholar 

  • 12Tru: W. Truthe, “The System Ag2S-AgCl,”Z. Anorg. Chem., 76, 168–170 (1912) in German. (Equi Diagram)

    Google Scholar 

  • 15Ura: G.G. Urazow, “Equilibrium Diagram of the System Ag+Ag2S and Cu+S,”J. Inst. Met., 14, 234–235 (1915). (Equi Diagram)

    Google Scholar 

  • 20Key: F.G. Keyes and W.A. Felsing, “The Equilibrium Conditions of the Reaction Between Silver Sulfide and Hydrogen,”J. Am. Chem. Soc., 42, 246–251 (1920). (Thermo)

    Article  Google Scholar 

  • 25Jel: K. Jellinek and J. Zakowski, “A Study of the Affinity of Metals to Sulfur,”Z. Anorg. Chem., 142, 1–53 (1925) in German. (Thermo)

    Article  Google Scholar 

  • 33Wat: M. Watanabe, “On the Equilibrium in the Reduction of Silver Sulphide by Hydrogen,”Sci. Rep. Res. Inst. Tohuku Univ., 22, 902–914 (1933). (Thermo)

    Google Scholar 

  • 34Rei: H. Reinhold, “The Determination of the Affinity Free Energy of Formation of Silver Sulfides (Selenides, Tellurides) by emf Method in Solid State,”Z. Elektrochem., 40(7a), 361–364 (1934) in German. (Thermo)

    Google Scholar 

  • 35Kim: G. Kimura, “On the Transition and Thermodynamic Values of Silver Sulfide,”Sci. Rep. Res. Inst. Tohoku Univ., 24, 77–90 (1935). (Thermo)

    Google Scholar 

  • 35Zeu: H. Zeumer and W.A. Roth, “The Heat of Formation of a Few Sulfides,”Z. Phys. Chem. A, 173, 365–382 (1935) in German. (Thermo)

    Google Scholar 

  • 37Bri: P.W. Bridgman, “Polymorphic Transitions of Thirty-Five Substances to 50,000 kg/cm2,”Proc. Am. Acad. Arts Sci., 72, 45–136 (1937). (Pressure)

    Google Scholar 

  • 39Kap: A.F. Kapustinsky and J.A. Makolkin, “A Determination of the Standard Free Energies of Formation of Metallic Sulfides by the Method of Electromotive Forces of Galvanic Cells,”Acta Physicochim. URSS, 10(2), 245–258 (1939). (Thermo)

    Google Scholar 

  • Indicates key paper46Kra: F.C. Kracek, “Phase Relations in the System Sulfur-Silver and the Transitions in Silver Sulfide,”Trans. Am. Geophys. Union, 27(3), 364–374 (1946). (Equi Diagram; Indicates presence of a phase diagram)

    Google Scholar 

  • 49Ros: T. Rosenqvist, “A Thermodynamic Investigation of the System Silver-Silver Sulphide,”Metals Trans., 185, 451–460 (1949). (Equi Diagram, Thermo; Indicates presence of a phase diagram)

    Google Scholar 

  • 51Goa: J.R. Goates, A.G. Cole, E.L. Gray, and N.D. Faux, “Thermodynamic Properties of Silver Sulfide,”J. Am. Chem. Soc., 73, 707–708 (1951). (Thermo)

    Article  Google Scholar 

  • 53Wag: C. Wagner, “Investigations on Silver Sulfide,”J. Chem. Phys., 21(10), 1819–1827 (1953). (Equi Diagram, Thermo)

    Article  ADS  Google Scholar 

  • 55Boe: A. Boettcher, G. Haase, and H. Treupel, “Investigations into the Structure and Structural Transformations of the Sulfides and Selenides of Silver and Copper,”Z. Angew. Phys., 7(10), 478–487 (1955) in German. (Crys Structure)

    Google Scholar 

  • 57Kiu: K. Kiukkola and C. Wagner, “Measurements on Galvanic Cells Involving Solid Electrolytes,”J. Electrochem. Soc., 104(6), 379–387 (1957). (Thermo)

    Article  Google Scholar 

  • 58Dju: S. Djurle, “X-Ray Study of the Cu−S System,”Acta Chem. Scand., 12, 1415–1426 (1958). (Crys Structure)

    Google Scholar 

  • 59Roy: R. Roy, A.J. Majumdar, and C.W. Hulbe, “The Ag2S and Ag2Se Transitions as Geologic Thermometers,”Econ. Geol., 54, 1278–1280 (1959). (Equi Diagram, Pressure)

    Article  Google Scholar 

  • 65Bie: V.H. Bielen, “Sulphur Dissociation Vapor Pressure of Heavy Metal Sulfides,”Z. Anorg. Chem., 338, 185–195 (1965) in German. (Thermo)

    Article  Google Scholar 

  • 67Bar: N. Barbouth, J. Oudar, and J. Cabane, “Solubility of Sulfur in Silver,”C.R. Acad. Sci. Paris, Ser. C, 264, 2120–2122 (1967) in French. (Equi Diagram)

    Google Scholar 

  • 69Per: C.M. Perrott and N.H. Fletcher, “Heat Capacity of Silver Sulfide,”J. Chem. Phys., 50(6), 2344–2350 (1969). (Thermo)

    Article  ADS  Google Scholar 

  • 70Cla: J.B. Clark and E. Rapoport, “Effect of Pressure on Solid-Solid Transitions in Some Silver and Cuprous Chalcogenides,”J. Phys. Chem. Solids, 31, 247–254 (1970). (Equi Diagram, Pressure)

    Article  ADS  Google Scholar 

  • 71Rau: E. Raub and E. Roschel, “Solubility of Sulfur, Selenium, and Tellurium in Solid Silver,”Metall, 25(1), 7–10 (1971) in German. (Equi Diagram)

    Google Scholar 

  • 71Tho: W.T. Thompson and S.N. Flengas, “Drop Calorimetric Measurements on Some Chlorides, Sulfides, and Binary Melts,”Can. J. Chem., 49, 1550–1563 (1971). (Thermo)

    Article  Google Scholar 

  • 74Mil: K.C. MillsThermodynamic Data for Inorganic Sulfides, Selenides, and Tellurides, Butterworths, London (1974).

    Google Scholar 

  • Indicates key paper74Rau: H. Rau, “Defect Equilibria in Silver Sulphide,”J. Phys. Chem. Solids, 35, 1553–1559 (1974). (Equi Diagram, Thermo; Indicates presence of a phase diagram)

    Article  ADS  Google Scholar 

  • 78Bon1: G. Bonnecaze, A. Lichanot, and S. Gromb, “The Study of Electrogalvanic and Electronic Properties of Beta Silver Sulfide,”J. Phys. Chem. Solids, 39, 299–310 (1978) in French. (Equi Diagram, Thermo)

    Article  ADS  Google Scholar 

  • 78Bon2: G. Bonnecaze, A. Lichanot, and S. Gromb, “The Study of Electronic and Electrogalvanic Properties of αAg Sulfide,”J. Phys. Chem. Solids, 39, 813–821 (1978) in French. (Equi Diagram, Thermo)

    Article  ADS  Google Scholar 

  • 78Fue: K. Fueki, K. Ota, and K. Kishio, “Solubility and Diffusion Coefficient of Sulfur in Silver,”Bull. Chem. Soc. Jpn., 51(10), 3067–3068 (1978). (Equi Diagram)

    Article  Google Scholar 

  • 79Dit: A.V. Ditman and I.N. Kulikova, “Investigation of the Dissociation of Solid and Fused Silver Sulfide by the Dew Point Method,”Zh. Fiz. Khim., 53(1), 260–261 (1979) in Russian; TR:Russ. J. Phys. Chem., 53(1) 149 (1979). (Equi Diagram, Thermo)

    Google Scholar 

  • 80Mit: K. Mitteilung, “State Diagram of Ag−S in the Region of the Compound Ag2±σS,”Z. Phys. Chem. Neue Folge (Wies-baden), 119, 251–255 (1980) in German. (Equi Diagram)

    Google Scholar 

  • Indicates key paper81Fuk: N. Fukatsu and Z. Kozuka, “Measurment of the Thermodynamic Quantities for the Ag−S System by the emf Method,”J. Jpn. Inst. Met., 45(12), 1263–1270 (1981) in Japanese. (Equi Diagram, Thermo)

    Google Scholar 

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Authors and Affiliations

  1. Department of Metallurgical and Mineral Engineering, University of Wisconsin-Madison, 1509 University Ave., 53706, Madison, WI

    R. C. Sharma & Y. A. Chang

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  1. R. C. Sharma
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  2. Y. A. Chang
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Additional information

This work was supported by American Society for Metals. Literature searched through 1984. R. C. Sharma is a Visiting Assistant Professor (1984–1986) on leave from the Indian Institute of Technology, Kanpur, India. Professor Chang is the ASM/NBS Data Program Category Editor for binary sulfur alloys.

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Sharma, R.C., Chang, Y.A. The Ag−S (Silver-Sulfur) system. Bulletin of Alloy Phase Diagrams 7, 263–269 (1986). https://doi.org/10.1007/BF02869003

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