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The radical bromination reaction of ethylenecarbonate

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Abstract

The reaction of ethylenecarbonate (I) with bromine was carried out in the presence of benzoylperoxide as radical initiator. The following several different esters being ring opened were obtained; bromoacetyl-bromoformate, (1-hydroxy, 1,2-dibromo)-ethyl bromoformate, (1-hydroxy, 1,2, 2′-tribromo)-diethylcarbonate, 2-bromoethyl-tribromoacetate, (1-acetoxy, 1′-bromomethyl)-bromomalo nate, 2-bromoethyl-bromoacetoxy-tribromoacetate.

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References Cited

  1. Carlson, W.W. and Cretchen, L.H.:J. Amer. Chem. Soc. 69, 1947 (1952).

    Google Scholar 

  2. Bergmann, E.D. and Shahak, I.:J. Chem. Soc. (C), 899 (1966).

    Google Scholar 

  3. Neumann, M.S. and Addor, R.W.:J. Amer. Chem. Soc. 77, 3789 (1955).

    Article  Google Scholar 

  4. Taneda, Y.,Kosei Gagaku Kyckaishi.,17, 783 (1955).

    Google Scholar 

  5. Pryor:Free Radicals. 163–68(1966) McGraw-Hill, Inc.,

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Moon, DW. The radical bromination reaction of ethylenecarbonate. Arch. Pharm. Res. 6, 1–6 (1983). https://doi.org/10.1007/BF02855695

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  • DOI: https://doi.org/10.1007/BF02855695

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