Skip to main content
SpringerLink
Log in

Infrared absorption study of Cr(CN) n−6 complexes doped in KCl crystals

  • Solids
  • Published:
Pramana Aims and scope Submit manuscript

Abstract

Infrared absorption spectrum of Cr(CN) 3−6 doped in KCl crystals show that the site symmetry of the ion is predominantlyC 8 corresponding to one cation vacancy in the nearest neighbour and the other in the next nearest neighbour position with respect to Cr3+ ion. X-irradiation produces complexes of the type Cr(CN) 4−6 and Cr (CN) 5−6 .

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • Caglioti V, Sartori G. and Scrocco M 1958J. Inorg. Nucl. Chem. 8 87

    Article  Google Scholar 

  • Decius J C, Coker E H and Brenna C L 1963Spectrochim Acta 21 1281

    Article  Google Scholar 

  • Jain S C, Warrier A V R and Sehgal H K 1973J. Phys. C. Solid State Phys. 6 193; 19725 1511.

    Article  ADS  Google Scholar 

  • Jain S Cet al 1971Bibliographies on properties of defect centers in Alkali Halides. Report No. NBS-OSRDB-71-1 N B S Washington DC

  • Jones L H 1971Inorganic Vibrational Spectroscopy Vol. 1 (Marcel Dekker, Inc. New York) pp. 117–139

    Google Scholar 

  • Metselaar R and Vander Elsken J 1968Phys. Rev. 165 359

    Article  ADS  Google Scholar 

  • Nakamoto K 1970Infrared spectra of inorganic and coordination compounds 2nd ed. (Wiley-Interscience, New York) pp. 178–185

    Google Scholar 

  • Tosi M P and Airoldi G 1958Nuovo Cim. 8 584

    Article  Google Scholar 

  • Wilson E B, Decius J C and Cross P C 1955Molecular vibrations (McGraw-Hill Book Company)

  • Watkins G D 1959Phys. Rev. 113 79

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Solid State Physics Laboratory, Lucknow Road, 110007, Delhi

    A V R Warrier

Authors
  1. A V R Warrier
    View author publications

    You can also search for this author in PubMed Google Scholar

Consortia

ABHA

Rights and permissions

Reprints and permissions

About this article

Cite this article

ABHA., Warrier, A.V.R. Infrared absorption study of Cr(CN) n−6 complexes doped in KCl crystals. Pramana - J Phys 5, 284–288 (1975). https://doi.org/10.1007/BF02845952

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02845952

Keywords

Search

Navigation