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Preparation and reactivity of metal-containing monomers 53. Synthesis and stability of a cluster monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in solution

  • Organometallic Chemistry
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Abstract

The stability of the complex (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 (1), which contains a free unsaturated functional group in the terminal ligand PPh2CH2CH=CH2, with respect to isomerization, chelation of the ligand, and other transformations in solutions was examined. No transformations of complex1 were observed in the course of synthesis from (μ-H)Os3(μ-OCNMe2)(CO)9NMe3 or upon heating in solution. Complex1 as well as complexes (μ-H)Os3(μ-OCNMe2)(CO)9PHPh2 and (μ-H)Os3(μ-OCNMe2)(CO)9PPh3, which were formed as admixtures, were isolated in the solid state and identified by1H,1H-{31P}, and1H-{1H} NMR, IR, and Raman spectroscopy and mass spectrometry.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent'eva, 630090, Novosibirsk, Russian Federation

    V. A. Ershova, A. V. Golovin, L. A. Sheludyakova & P. P. Semyannikov

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    S. I. Pomogailo & A. D. Pomogailo

Authors
  1. V. A. Ershova
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  2. A. V. Golovin
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  3. L. A. Sheludyakova
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  4. P. P. Semyannikov
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  5. S. I. Pomogailo
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  6. A. D. Pomogailo
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Additional information

For Part 52, see Ref. 1.

Published inIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1455–1460, August, 2000.

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Ershova, V.A., Golovin, A.V., Sheludyakova, L.A. et al. Preparation and reactivity of metal-containing monomers 53. Synthesis and stability of a cluster monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in solution. Russ Chem Bull 49, 1448–1453 (2000). https://doi.org/10.1007/BF02495095

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  • DOI: https://doi.org/10.1007/BF02495095

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