Summary
A new expression which permits the prediction of the net retention volumes in gas chromatography with column packings of coated porous polymers is reported. The porous polymers Chromosorb 101 and Chromosorb 102 were used as supports and squalane, Ethofat and Carbowax 20M as stationary phases at three different column temperatures of 80°C, 100°C and 150°C. Several organic compounds of various polarity were used as test compounds and the net retention volumes, VNtheor, have been calculated according to this new expression. The VNtheor values were compared with the experimental net retention volumes, VNexp, and it was found that the difference between these two values is dependent on the type of compound and column packing. Nevertheless, the elution order could be predicted in most cases.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
H. Masuda, S. Mihara, J. Chromatog.366, 373 (1986).
Z. Suprynowicz, W. M. Buda, M. Mardarowicz, A. Patrikijew, J. Chromatog.333, 11 (1985).
A. Patrykiejew, B. Gawdzik, J. Chromatog.365, 251 (1986).
G. Castello, G. D'Amato, J. Chromatog.366, 51 (1986).
D. Barceló, M. T. Galcerán, L. Eek, Chromatographia12, 72 (1979).
D. Barceló, M. T. Calcerán, L. Eek, Chromatographia14, 1 (1981).
D. Barceló, M. T. Galcerán, L. Eek, Chromatographia21, 8 (1986).
D. Barceló, M. T. Galcerán, L. Eek, Chromatographia21, 16 (1986).
D. Barceló, M. T. Galcerán, L. Eek, in “Chromatography, th State of the Art”,H. Kalasz andL. S. Ettre (eds) Pub. H. Hung. Acad. Sci. (1984).
D. Barceló, L. Eek, in Analytical Techniques in environment chemistry, ed.J. Albaigés, Pergamon Press, Oxford (1980) p. 335
R. Tijsen, H. A. H. Billiet, P. J. Shoenmakers, J. Chromato122, 185 (1976).
C. M. Hansen, Ind. Eng. Chem. Prod. Res. Develop.8, (1976).
A. F. Barton, Chem. Rev.75, 731 (1975).
W. Burns, S. J. Hawkes, J. Chromatog. Sci.15, 185 (1977).
B. L. Karger, L. R. Snyder, C. Eon, J. Chromatog.125, 7 (1976).
B. L. Karger, L. R. Snyder, C. Eon, Anal. Chem.50, 212 (1978).
S. Coppi, A. Betti, J. Chromatog.300, 55 (1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Barceló, D., Galcerán, M.T. & Eek, L. Prediction of the net retention volumes in gas chromatography using porous polymers coated with different stationary phases. Chromatographia 23, 481–486 (1987). https://doi.org/10.1007/BF02309415
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02309415