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Retention characteristics of alcohols and sugars on polysulfone as a stationary phase with an aqueous mobile phase

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Summary

Partition coefficients (Ka) necessary for the understanding of solute-material interactions was experimentally generated by liquid chromatography. Using three commercial polysulfones (Udel, Victrex and Radel) as the stationary phase and water as the mobile phase, retention behavior for a series of alcohols and sugars were determined. The logarithm of the distribution of the solute between the mobile and stationary phase was linearly related to solute descriptors such as octanol-water partition coefficients (KO/W) and molecular connectivity index (κ1). Solubility parameters were used as means of describing the different stationary phases and were related to chromatographic behavior.

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Authors and Affiliations

  1. Process Technology, Institute for Environmental Chemistry, National Research Council of Canada, K1A OR9, Ottawa, Canada

    C. M. Tam & O. Kutowy

  2. Department of Chemical Engineering, University of Ottawa, Ottawa, Canada

    F. D. F. Talbot

Authors
  1. C. M. Tam
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  2. O. Kutowy
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  3. F. D. F. Talbot
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Tam, C.M., Kutowy, O. & Talbot, F.D.F. Retention characteristics of alcohols and sugars on polysulfone as a stationary phase with an aqueous mobile phase. Chromatographia 32, 224–228 (1991). https://doi.org/10.1007/BF02276244

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  • DOI: https://doi.org/10.1007/BF02276244

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