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Resolution of enantiomers and isotopic compositions by selective complexation gas chromatography on metal complexes

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The high selectivity of complexation gas chromatography has been employed for enantiomer resolution and isotope separation. Thus, a chiral olefin, 3-methylcyclopentene, has been resolved analytically on optically active dicarbonyl-rhodium(I)-3-trifluoroacetyl-1R-camphorate in squalane. The deuterated ethylenes C2H4−nDn have been separated on the same rhodium(I)-containing stationary phase. The chiral aliphatic oxiranes epoxypropane andtrans-2,3-epoxybutane have been resolved on optically active nickel(II)-bis-3-trifluoroacetyl-1R-camphorate in squalane.

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  1. Institut für Organische Chemie der Universität, Auf der Morgenstelle 18, D-7400, Tübingen, Federal Republic of Germany

    V. Schurig

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Schurig, V. Resolution of enantiomers and isotopic compositions by selective complexation gas chromatography on metal complexes. Chromatographia 13, 263–270 (1980). https://doi.org/10.1007/BF02265639

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