Abstract
Gamma-ray induced decomposition of solid binary mixtures of KNO3 with halides viz. KCl, KBr and KI has been studied at room temperature. G(NO −2 ) values were found to vary with absorbed dose. Size and electronegativity of anions and molar composition of halides are the other factors influencing radiolysis.
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J. CUNNINGHAM, H. HEAL, Trans Faraday Soc., 54 (1958) 1355.
C. J. HOCHANDEL, T. W. DAVIS, J. Chem. Phys., 27 (1957) 333.
S. F. PATIL, C. G. NALAWADE, Radiochem. Radioanal. Lett., 45 (1980) 133; 46 (1981) 343.
R. J. BATRA, A. N. GARG, Radiochem. Radioanal. Lett., 53 (1982) 177.
S. P. KULKARNI, A. N. GARG, Indian J. Chem., 23A (1984) 724.
S. P. KULKARNI, A. N. GARG, J. Radioanal. Nucl. Chem. Articles, 98 (1986) 65.
A. S. BABERKIN, M. A. PROSKURNIN, Dokl. Akad. Nauk, SSSR, 121 (1958) 492, A. S. BABERKIN, Dokl. Akad. Nauk. USSR., 126 (1959) 591.
D. V. PARWATE, A. N. GARG, J. Radional Nucl. Chem. Lett., 85 (1984) 203.
D. G. GARWAY, D. V. PARWATE, A. N. GARG, Indian J. Chem., 27A (1988) 108.
S. B. SRIVASTAVA, A. S. SARPOTDAR, J. SHANKAR, Indian J. Chem. 8 (1970) 426; 9 (1971) 144.
V. K. PHANSALKAR, L. BAPAT, D. RAVISHANKAR, Radiochem. Radioanal Lett., 51 (1982) 19.
M. SARKAR, Radiolytic Decomposition of Binary Mixtures of Potassium Nitrate with Halides, M. Sc. Dissertation, Nagpur University, Nagpur, 1986.
S. P. KULKARNI, A. N. GARG, Radiat. Phys. Chem., (in press).
B. L. GUPTA, Division of Radiological Protection, BARC, Bombay, Personal communication.
M. B. SHINN, Ind. Engng. Chem. Analyst Edn., 13 (1941) 33.
N. F. KERSHAW, N. S. CHAMBERLIN, Ind. Eng. Chem. Analyt. Edn., 14 (1942) 312.
J. H. HUBBEL, J. Appl. Radiat. Isot., 33 (1982) 1269.
E. R. JOHNSON, The Radiation Induced Decomposition of Inorganic Molecular Ions, Gordon and Breach Scinece Publishers, New York, 1970, pp. 141.
A. M. FULLER, C. E. TORR, J. Chem. Phys., 56 (1971) 438.
D. MUHAMMAD, A. G. MADDOCK, J. Chem. Soc. Faraday Tans. I., 74 (1978) 919.
B. T. DESHMUKH, K. K. BATRA, S. V. MOHARIL, Phys. Rev., B 29 (1984) 3652.
R. B. PODE, Cryst. Latt. Def. and Amporph. Materials, 14 (1987) 1.
M. GRATZEL, A. HENGLEIN, S. TANIGUCHI, Ber. Bunsenges, Phys. Chem., 74 (1970) 292;
M. GRATZEL, A. HENGLEIN, J. LILIE, G. BECK,ibid., 74 (1970) 646.
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Batra, R.J., Garg, A.N. Gamma radiolytic decomposition of solid binary mixtures of potassium nitrate with halides. Journal of Radioanalytical and Nuclear Chemistry, Articles 129, 155–162 (1989). https://doi.org/10.1007/BF02037578
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DOI: https://doi.org/10.1007/BF02037578