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Step-by-step pattern of thermal dissociation of coordination compounds

Thermoanalytical study and theoretical considerations

  • Papers Presented at the Seminar on Modern Application of Thermal Analysis
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Abstract

The problem of the correlation between the initial compound structure (the strengths of the ligand bonds) and the stepwise nature of the thermal decomposition process is discussed from a thermodynamic point of view. The absence of such a direct correlation is shown. This theoretical consideration is verified by experiment.

Zusammenfassung

Vom thermodynamischen Gesichtspunkt her wurde die Frage der Korrelation zwischen der Struktur der Ausgangsverbindung (StÄrke der Ligandenbindung) und der Mehrstufigkeit des thermischen Zersetzungsprozesses erlÄutert. Es wird gezeigt, da\ solch eine Korrelation nicht besteht. Diese theoretische Feststellung wird experimentell bestÄtigt.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the USSR Academy of Sciences, 630090, Novosibirsk, USSR

    V. Logvinenko

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  1. V. Logvinenko
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Logvinenko, V. Step-by-step pattern of thermal dissociation of coordination compounds. Journal of Thermal Analysis 36, 1743–1749 (1990). https://doi.org/10.1007/BF01913420

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  • DOI: https://doi.org/10.1007/BF01913420

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