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Effect of composition of binary palladium alloys on direction of catalytic transformations of 1,2-cyclohexanediol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A study of the binary alloys of Pd with Ni, Ti, Cu, and Rh as regards the transformations of 1, 2-cyclohexanediol disclosed that the character of the products is strongly dependent on the nature of the second component of the alloy. Cyclohexanone and phenol predominate in the products obtained on the binary Pd alloys that contain Ni, Ti, or Cu, while the Pd-Rh alloys are selective catalysts for the dehydrogenation of 1,2-cyclohexanediol to pyrocatechol without forming phenol.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    M. E. Sarylova, A. P. Mishchenko, V. M. Gryaznov & V. S. Smirnov

  2. P. Lumumba Moscow International Friendship University, Moscow

    M. E. Sarylova, A. P. Mishchenko, V. M. Gryaznov & V. S. Smirnov

Authors
  1. M. E. Sarylova
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  2. A. P. Mishchenko
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  3. V. M. Gryaznov
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  4. V. S. Smirnov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 430–432, February, 1977.

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Sarylova, M.E., Mishchenko, A.P., Gryaznov, V.M. et al. Effect of composition of binary palladium alloys on direction of catalytic transformations of 1,2-cyclohexanediol. Russ Chem Bull 26, 389–391 (1977). https://doi.org/10.1007/BF00921862

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  • DOI: https://doi.org/10.1007/BF00921862

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