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Significance of the hydrolysis of some aliphatic and aromatic dicarboxylic acid chlorides in interphase polycondensation

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of the hydrolysis of adipoyl, sebacoyl, isophthaloyl, and terephthaloyl chlorides under the conditions of interphase polycondensation.

  2. 2.

    The amount of acid chloride hydrolyzed increases with increase in reaction time, but the rate of hydrolysis gradually falls.

  3. 3.

    The rate of the hydrolysis of the dicarboxylic acid chlorides investigated increases with rise in reaction temperature and alkali concentration.

  4. 4.

    The tendency for the investigated dicarboxylic acid chloride to hydrolyze diminishes in the following order: adipoyl chloride, sebacoyl chloride, isophthaloyl chloride, terephthaloyl chloride.

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Literature cited

  1. P. W. Morgan, SPEJ.,15, 485 (1959).

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  2. T. M. Frunze, V. V. Kurashev, and L. V. Kozlov, Uspekhi khimii,30, 593 (1961).

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  3. V. V. Korshak, T. M. Frunze, S. V. Vinogradova, V. V. Kurashev, and A. S. Lebedeva, Vysokomolek. soed.,3, 371 (1961).

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  4. V. V. Korshak, S. V. Vinogradova, T. M. Frunze, A. S. Lebedeva, and V. V. Kurashev, Vysokomolek. soed.,3. 984 (1961).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences USSR, USSR

    V. V. Korshak, T. M. Frunze, S. V. Vinogradova, V. V. Kurashev & A. S. Lebedeva

Authors
  1. V. V. Korshak
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  2. T. M. Frunze
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  3. S. V. Vinogradova
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  4. V. V. Kurashev
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  5. A. S. Lebedeva
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Korshak, V.V., Frunze, T.M., Vinogradova, S.V. et al. Significance of the hydrolysis of some aliphatic and aromatic dicarboxylic acid chlorides in interphase polycondensation. Russ Chem Bull 11, 1714–1719 (1962). https://doi.org/10.1007/BF00920266

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  • DOI: https://doi.org/10.1007/BF00920266

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