Abstract
The classification of catalytic reactions to structure sensitive and structure insensitive types has stood up well to the tests of experiments over the past two decades. Model studies using metal single crystal surfaces explored the relationship between the reaction kinetics and the atomic surface structure. These investigations uncovered the adsorbate induced dynamic restructuring of metal surfaces on the timescales of chemisorption, catalytic reactions and on longer times controlled by mass transport. The causes of reaction structure sensitivity and insensitivity are reinterpreted in view of the dynamic restructuring of the metal catalysts.
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References
G.A. Somorjai,Catalyst Design, Progress and Perspectives (John Wiley and Sons, NY, 1987) Ch. 2.
G.A. Somorjai and J. Carrazza, Industrial Eng. Fundamentals 25 (1986) 63.
G.A. Somorjai, N.D. Spencer and R.C. Schoonmaker, J. Catal. 74 (1982) 129.
G.A. Somorjai, M. Asscher, J. Carrazza, M. Khan and K. Lewis, J. Catal. 98 (1986) 277.
G.A. Somorjai and F. Zaera, J. Phys. Chem. 89 (1985) 3211.
G.A. Somorjai and F. Zaera, J. Am. Chem. Soc. 106 (8) (1984) 2288;
G.A. Somorjai, B.E. Koel and B.E. Bent, Surf. Sci. 146 (1) (1984) 211.
G.A. Somorjai, Cat. Rev. Sci. Eng. 23 (1&2) (1981) 189;
G.A. Somorjai, The catalyzed hydrogenation of carbon monoxide: an overview and future directions, in:New Trends in CO Activation, ed. L. Guczi (Elsevier Sci. Publ. Co., Amsterdam, 1990).
G.A. Somorjai, Correlations and differences between homogeneous and heterogeneous catalysis — A surface science view, in:Perspectives in Surface Science, eds. J. Thomas and E. Zamaraez, to be published.
G.A. Somorjai and M.A. Van Hove, Catal. Lett. 1, 12 (1988) 433.
G.A. Somorjai and M.A. Van Hove, Prog, in Surf. Sci. 30 (1989) 201.
G.A. Somorjai, S.W. Wang, D.F. Ogletree and M.A. Van Hove, Adv. in Quantum Chem. 20 (1989) 2.
G.A. Somorjai,Chemistry in two Dimensions (Cornell University Press, 1982).
M.A. Van Hove, W.M. Weinberg and C.M. Chan,Low Energy Electron Diffraction (Springer Verlag, Berlin, 1986).
J.H. Ouerferko, D.P. Woodruff and B.W. Holland, Surf. Sci. 87 (1979) 357.
H.E. Shih, F. Jona, D.W. Jepsen and P.M. Marcus, Phys. Rev. Lett. 46 (1981) 731.
G. Ertl, Ber. Buns. Phys. Chem. 90 (1986) 284.
R.C. Yeates, J.E. Turner, A.J. Gellman and G.A. Somorjai, Surf. Sci. 149 (1985) 175.
G.S. Somorjai, D.R. Strongin, J. Carrazza and S.R. Bare, J. Catal. 103 (1987) 213.
G.A. Somorjai, M.E. Bussell and A.J. Gellman, J. Catal. 110 (1988) 423.
G.A. Somorjai, S.M. Davis, F. Zaera and B.E. Gordon, J. Catal. 92 (2) (1985) 240;
G.A. Somorjai, D. Godbey, F. Zaera and R. Yeates, Surf. Sci. 167 (1986) 150.
G.-M. Schwab, in: Catalysis, Science and Technology, eds. J.R. Anderson and M. Boudart 2 (Springer Verlag, 1981) p. 1.
S.J. Touster and S.C. Fung, J. Catal. 55 (1978) 29.
M.E. Levine, M. Salmeron, A.T. Bell and G.A. Somorjai, J. Catal. 106 (1987) 401.
G.A. Somorjai, K.J. Williams, A.B. Boffa, M.E. Levin, M. Salmeron and A.T. Bell, Catal. Lett. 5 (1990) 385–394.
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Somorjai, G.A. The structure sensitivity and insensitivity of catalytic reactions in light of the adsorbate induced dynamic restructuring of surfaces. Catal Lett 7, 169–182 (1990). https://doi.org/10.1007/BF00764500
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DOI: https://doi.org/10.1007/BF00764500