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129Xe NMR spectroscopy on molecular sieves SAPO-37, AIPO4-5, SAPO-5 and SSZ-24

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Abstract

Xe NMR spectroscopy is used to study SAPO-37, NaY, AlPO4-5, SAPO-5, and SSZ-24. Of these samples, those with FAU topology show that the129Xe chemical shift is dependent upon framework composition while the materials with API topology do not. Values of the129Xe NMR chemical shifts at zero xenon pressure cannot be correlated with the size of the framework void space.

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References

  1. J. Fraissard, T. Ito and M.A. Springuel-Huet, J. Chim. Phys. 62 (1988) 747; and references therein.

    Google Scholar 

  2. L.C. de Menorval, J.P. Fraissard and T. Ito, J. Chem. Soc., Faraday Trans. 1, 78 (1962) 403.

    Google Scholar 

  3. T. Ito, J.L. Bonardet, J. Fraissard, J.B. Nagy, C. André, Z. Gabelica and E.G. Derouane, Appl. Catal. 43 (1988) L5.

    Google Scholar 

  4. M. Boudart, L.C. de Menorval, J. Fraissard and G.P. Valenca, J. Phys. Chem. 92 (1988) 4033.

    Google Scholar 

  5. J. Dermarquay and J. Fraissard, Chem. Phys. Lett. 136 (1987) 314.

    Google Scholar 

  6. K.B. Yoon and J.K. Kochi, J. Am. Chem. Soc. 110 (1988) 6586.

    Google Scholar 

  7. E.G. Derouane, Chem. Phys. Lett. 142 (1987) 200.

    Google Scholar 

  8. E.G. Derouane, J.M. André and A.A. Lucas, J. Catal. 110 (1988) 58.

    Google Scholar 

  9. M.E. Davis, C. Saldarriaga, C. Montes and B.E. Hanson, J. Phys. Chem. 92 (1988) 2557.

    Google Scholar 

  10. E.G. Derouane and M.E. Davis, J. Mol. Catal. 48 (1988) 37.

    Google Scholar 

  11. Q.J. Chen, M.A. Springuel-Huet and J. Fraissard, J. Chem. Phys. Lett. 159 (1989) 117.

    Google Scholar 

  12. N. Dumont, T. Ito and E.G. Derouane, Appl. Catal. 54 (1989) LI.

    Google Scholar 

  13. S.T. Wilson, B.M. Lok, E.M. Flanigen, U.S. Patent 4310440, (1982);

  14. B.M. Lok, C.A. Messina, C.A. Patton, R.T. Gajek, T.R. Cannan, E.M. Flanigen, U.S. Patent 4440871 (1984). (Here, pseudo-boemite was used as the alumina source.)

  15. S.I. Zones, U.S. Patent 4665110 (1987).

  16. F.C.M. Chen and N.L. Benoiton, Can. J. Chem. 54 (1976) 3310.

    Google Scholar 

  17. R. von Ballmoos,Collection of Simulated Powder Patterns for Zeolites, (Butterworth Scientific Limited, Surrey, UK, 1984) 8.

    Google Scholar 

  18. A.K. Jameson, C.J. Jameson and H.S. Gutowsky, J. Chem. Phys. 53 (1970) 2310.

    Google Scholar 

  19. L. Sierra de Saldarraiga, C. Saldarriaga and M.E. Davis, J. Am. Chem. Soc. 109 (1987) 2686.

    Google Scholar 

  20. J.W. Richardson, Jr., J.J. Pluth and J.V. Smith, Acta Cryst. C43 (1987) 1469.

    Google Scholar 

  21. R.A. Van Nordstrand, D.S. Santilli and S.I. Zones,Perspectives in Molecular Sieve Science, ACS Symposium Series 368 (American Chemical Society: Washington, D.C., 1988) 236.

    Google Scholar 

  22. G. Seo and R. Ryoo, J. Catal. 124 (1990) 224.

    Google Scholar 

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Annen, M.J., Davis, M.E. & Hanson, B.E. 129Xe NMR spectroscopy on molecular sieves SAPO-37, AIPO4-5, SAPO-5 and SSZ-24. Catal Lett 6, 331–339 (1990). https://doi.org/10.1007/BF00763999

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  • DOI: https://doi.org/10.1007/BF00763999

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