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Reaction of 2-acyloxiranes with cyclic ketones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

Acyloxiranes react with cyclopentanone and cyclohexanone in the presence of catalytic amounts of boron trifluoride etherate to give the corresponding 2-acyl-1,4-dioxaspiro[4,4]-nonanes and 2-acyl-1,4-dioxaspiro[4,5]decanes. The corresponding cis-2,3-dimethyl-2 acetyl-1,4-dioxaspiroalkanes are formed from trans-2,3-dimethyl-2-acetyloxirane.

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Authors and Affiliations

  1. V. I. Lenin Belorussian State University, Minsk

    I. G. Tishchenko, O. N. Bubel' & G. Z. Stasevich

Authors
  1. I. G. Tishchenko
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  2. O. N. Bubel'
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  3. G. Z. Stasevich
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 885–888, July, 1974.

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Tishchenko, I.G., Bubel', O.N. & Stasevich, G.Z. Reaction of 2-acyloxiranes with cyclic ketones. Chem Heterocycl Compd 10, 769–772 (1974). https://doi.org/10.1007/BF00471349

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  • DOI: https://doi.org/10.1007/BF00471349

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