Abstract
From the quartz porphyry occurrences of Haigerach and Geisberg (Central Schwarzwald), which were dated by minerals and whole-rock samples, the whole-rock samples generally yielded lower ages than the minerals. This result agrees with other studies on apparently rejuvinated whole-rock ages of acid volcanic rocks (compare McKerrow et al. 1980). Petrographic and geochemical observations show that two processes disturbed the Rb-Sr relations:
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1)
fast alterations immediately after extrusion, such as sericitization during autohydrothermal bleaching in the pipe area of the volcanoes, gain of Rb, addition of common Sr.
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2)
loss of radiogenic 87Sr due to long-lasting exchange processes with groundwaters.
The combined result of the two processes is a kind of isochron rotation simulating younger whole-rock ages and higher initial Sr isotope ratios. Our results on the two quartz porphyries indicate that whole-rock dating of such acid volcanics is not succesful.
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Schleicher, H., Lippolt, H.J. & Raczek, I. Rb-Sr systematics of Permian volcanites in the Schwarzwald (SW-Germany). Contr. Mineral. and Petrol. 84, 281–291 (1983). https://doi.org/10.1007/BF00371292
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DOI: https://doi.org/10.1007/BF00371292