Abstract
A swarm of Caledonian microtonalite sheets is host to W-Sn mineralization in SE Ireland. Many but not all mineralized sheets are within a regional shear zone which, however, does not appear to have been a major control on mineralization. Scheelite and arsenopyrite are the dominant minerals within and adjacent veins in greisened tonalite. No wolframite occurs. The intrusions are affected by two alterations, a pervasive one and another which is spatially associated with veins. Both are associated with high metal values. Veining is confined to microtonalite sheets and was initiated at least partly by hydraulic fracturing of the intrusions. Stable isotope analyses indicate that mineral deposition occurred over narrow time and temperature intervals from a hydrothermal fluid of magmatic origin. Methane is important in fluid inclusions in quartz veins and the low oxygen fugacity of the mineralizing fluid was probably critical in concentrating metals and in suppressing wolframite formation.
Similar content being viewed by others
References
Anderson, A.T., Jr.: Probable relations between plagioclase zoning and magma dynamics. Fuego Volcano, Guatemala. Am. Mineral. 69:660–676 (1984)
Anderton, R., Bridges, P.H., Leeder, M.R. and Sellwood, B.W.: A dynamic stratigraphy of the British Isles, Ed. 1, George Allen and Unwin, London (1979)
Angus, S., Armstrong, B. and De Reuck, K.M.: International thermodynamic tables of the fluid state — 3. Carbon dioxide. International Union of Pure and Applied Chemistry. Pergamon Press (1973)
Angus S., Armstrong B. and De Reuck, K.M.: International thermodynamic tables of the fluid state — 5. Methane. International Union of Pure and Applied Chemistry, Chemical Data Series No. 16, Pergamon Press (1976)
Barabanov, V.F.: Geochemistry of tungsten. Internat. Geology Rev. 13:332–344 (1971)
Bateman, P.C.: Scheelite-bearing skarns of the East-Central Sierra Nevada, California, U.S.A. In: Tungsten Geology Symposium, Jiangxi, China. Hepworth, J.V. and Y.H. Zhang (Eds) ESCAP/RMRDC, Bandung, Indonesia and Geological Publishing House, Beijing, China: 23–31 (1982)
Bigeleisen, J., Perlman, M.L. and Prosser, H.C.: Conversion of hydrogenic materials to hydrogen for isotopic analysis. Geochim. Cosmochim. Acta. 27:43–52 (1952)
Blattner, P.: Oxygen isotopic composition of fissure-grown quartz, adularia and calcite from Broadlands geothermal field, New Zealand, with an appendix on quartz-K-feldspar-calcite-muscovite oxygen isotope geothermometers. Am. J. Sci. 275:785–800 (1975)
Bottinga, Y. and Javoy, M.: Oxygen isotope partitioning among the minerals in igneous and metamorphic rocks. Rev. Geophys. Space Phys. 13:401–418 (1975)
Brindley, J.C.: The structural setting of the Leinster Granite, Ireland — a review. Sci. Proc. Roy. Dub. Soc. 5A:27–36 (1973)
Brück, P.M., Colthurst, J.R.J., Feely, M., Gardiner, P.R.R., Penney, S.R., Reeves, T.J., Shannon, P.M., Smith, D.G. and Vanguestaine, M.: Southeast Ireland: Lower Palaeozoic stratigraphy and depositional history. In: The Caledonides of the British Isles — reviewed. Harris, A.L., Holland, C.H. and Leake, B.E. (Eds.). Geol. Soc. Lond. Spec. Pub. 8, London, 533–544 (1979)
Brück, P.M. and O'Connor, P.J.: The Leinster Batholith: geology and geochemistry of the Northern Units: Geol. Surv. Ireland Bull. 2:107–141 (1977)
Burt, D.M.: Acidity-salinity diagrams — application to greisen and porphyry deposits. Econ. Geol. 76:832–843 (1981)
Clarke, M.C.G.: Current Chinese thinking on the South China tungsten province. Trans. Inst. Min. Metall. B92:10–15 (1983)
Clayton, R.N. and Mayeda, T.K.: The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis. Geochim. Cosmochim. Acta 27:43–52 (1963)
Coleman, M.L. and Moore, M.P.: Direct reduction of sulfates to sulfur dioxide for isotopic analysis. Anal. Chemistry 50:1594–1595 (1978)
Dagger, G.W.: Genesis of the Mount Pleasant tungsten-molybdenum-bismuth deposit, New Brunswick, Canada. Inst. Min. Metall. Bull. B81:73–102 (1972)
Davies, G.R., Gledhill, A. and Hawkesworth, C.: Upper crustal recycling in southern Britain: evidence from Nd and Sr isotopes. Earth Planet. Sci. Letts. 75:1–12 (1985)
Elsdon, R. and Kennan, P.S.: Geochemistry of Irish granites. In: The Caledonides of the British Isles — reviewed. Harris, A.L., Holland, C.H., and Leake, B.E. (Eds.). Geol. Soc. London Spec. Pub. 8, London, 713–716 (1979)
Eugster, H.P.: Granites and hydrothermal ore deposits: a geochemical framework. Mineral. Mag. 49:7–23 (1985)
Foster, R.P.: Solubility of scheelite in hydrothermal chloride solutions. Chem. Geol. 20:27–43 (1977)
Foster, R.P., Mann, A.G., Armin, T. and Burmeister, B.B.: Richardson's Kop wolframite deposit: a geochemical model for the hydrothermal behaviour of tungsten. In: Mineralization in metamorphic terranes, Verwoerd, W.J. (Ed.), Geol. Soc. S. Africa Spec. Pub. 4:107–128 (1975)
Frost, B.R.: Mineral equilibria involving mixed-volatiles in a C-O-H fluid phase: the stabilities of graphite and siderite. Am. J. Sci. 279:1033–1059 (1979)
Gallagher, V.: Tourmaline-bearing rocks and granite-related metallogenesis in SE Ireland. Unpub. Ph.D. thesis, Nat. Univ. Ireland (1987)
Hallenstein, C.P. and Pedersen, J.L.: Scheelite mineralization in central east Greenland. Mineral. Deposita 18:315–333 (1983)
Henley, R.W., Norris, R.J. and Paterson, C.J.: Multistage ore genesis in the New Zealand Geosyncline: a history of postmetamorphic lode emplacement. Mineral. Deposita 11:180–196 (1976)
Kelly, W.C. and Rye, R.O.: Geologic, fluid inclusions and stable isotope studies of the tin-tungsten deposits of Panasqueira, Portugal. Econ. Geol. 74:1721–1822 (1979)
Kennan, P.S., McArdle, P., Williams, F.M. and Doyle, E.: A review of metal deposits associated with the Leinster Granite, SE Ireland and a model for their genesis. In: Geology and genesis of Mineral deposits in Ireland, Andrew, C.J., Crowe, R.W.A., Finlay, S., Pennell, W.M., and Pyne, J.F. (Eds.), Irish Assoc. Econ. Geol. Dublin, 201–210 (1986)
Landis, G.P. and Rye, R.O.: Geologic, fluid inclusion and stable isotope studies of the Pasto Buena tungsten-base metal ore deposit, northern Peru. Econ. Geol. 69:1025–1059 (1974)
Lehmann, B.: Formation of the stratabound Kellhuani tin deposits, Bolivia. Mineral. Deposita 20:169–176 (1985)
Lin Chuanxian, Zhan Zheru and Burt, D.M.: Phase equilibria of several tungsten deposits in southern China. Chinese J. Geochem. 4:280–290 (1985)
McArdle, P.: Country rocks flanking the Leinster Granite between Aughrim and Ballymurphy. Geol. Surv. Ireland Bull. 3:85–95 (1981)
McArdle, P.: A study of the geological setting of mineralization associated with the margin of the Tullow Lowlands Unit of the Leinster Granite. Unpub. Ph.D. thesis, Nat. Univ. Ireland (1984)
McArdle, P. and Kennedy, M.J.: The East Carlow Deformation Zone and its regional implications. Geol. Surv. Ireland Bull. 3:237–255 (1985)
Moore, A.J.McM.: Carrock Fell tungsten mine, Cumbria. Jour. Roy. Sch. Mines 26:7–14 (1977)
Ohmoto, H.: Systematics of sulfur and carbon isotopes in hydrothermal ore deposits. Econ. Geol. 67:551–578 (1972)
Ohmoto, H. and Kerrick, D.: Devolatilization equilibria in graphitic systems. Am. J. Sci. 277:1013–1044 (1977)
Ohmoto H. and Rye, R.O.: Isotopes of sulfur and carbon. In: Geochemistry of hydrothermal ore deposits. Barnes, H.L. (Ed.), Ed. 2, Wiley-Interscience, London-New York, 509–567 (1979)
O'Neil, J.R. and Taylor, H.P., Jr.: The oxygen isotope and cation exchange chemistry of feldspars. Am. Mineral. 52:1414–1437 (1967)
O'Neil, J.R. and Taylor, H.P. Jr.: Oxygen isotope equilibrium between muscovite and water. J. Geophys. Res. 74:6012–6022 (1969)
Pélissonnier, H.: Dynamique de mise en place des magmas granitiques et gisements de tungstène. C.R. Acad. Sci. Paris t. 302, serie II, 187–190 (1986)
Penney, S.R.: A new look at the Old Red Sandstone succession of the Comeragh Mountains, Co. Waterford. J. Earth Sci. Roy. Dub. Soc. 3:155–178 (1980)
Sasaki, A. Ishihara, S.: Sulfur isotope composition of the Magnetite-series and Ilmenite-series granitoids in Japan. Contrib. Min. Petrol. 65:107–115 (1979)
Scott, S.D. and Barnes, H.L.: Sphalerite geochemistry and geobarometry. Econ. Geol. 66:653–669 (1971)
Shepherd, T.J., Rankin, A.H. and Alderton, D.H.M.: A practical guide to fluid inclusions. Blackie, Glasgow-London (1985)
Sillitoe, R.H., Halls, C. and Grant, J.N.: Porphyry tin deposits in Bolivia. Econ. Geol. 70:913–927 (1975)
So, C.-S., Shelton, K.L. and Rye, D.M.: Geologic, sulfur isotopic and fluid inclusion study of the Ssang Jeon tungsten mine, Republic of Korea. Econ. Geol. 78:157–163 (1983)
Steiger, R. and Bowden, A.: Tungsten mineralization in southeast Leinster, Ireland. In: Mineral exploration in Ireland, progress and developments 1971–1981, Brown, A.G. and Pyne, J.F. (Eds.), Irish Assoc. Econ. Geol. Dublin, 108–114 (1982)
Streckeisen, A.: To each plutonic rock its proper name. Earth-Sci. Rev. 12:1–33 (1976)
Suzuoki, T. and Epstein, S.: Hydrogen isotope fractionation between OH-bearing minerals and water. Geochim. Cosmochim. Acta 40:1229–1240 (1976)
Taylor, H.P., Jr.: Water/rock interactions and the origin of H2O in granitic batholiths. J. Geol. Soc. London 133:509–558 (1977)
Taylor, H.P.: Oxygen and hydrogen isotope relationships in hydrothermal mineral deposits. In: Geochemistry of hydrothermal ore deposits, Barnes, H.L. (Ed.) Ed. 2, Wiley-Interscience, London-New York, 236–277 (1979)
Wedepohl, K.H.: (Ed.). Handbook of Geochemistry, Ed. 1, Berlin-Heidelberg-New York: Springer 1978
Wesolowski D. and Ohmoto, H.: Calculated oxygen isotope fractionation between water and the minerals scheelite and powellite. Econ. Geol. 81:471–477 (1986)
Williams, F.M. and Kennan, P.S.: Stable isotope studies of sulphide mineralization on the Leinster Granite margin and some observations on its relationship to coticule and tourmalinite rocks in the aureole. Mineral. Deposita 15:399–410 (1983)
Wood, B.J. and Fraser, D.G.: Elementary themodynamics for geologists, Ed. 1, Oxford University Press, Oxford (1976)
Yang Chaoqun: Mineralization of the composite greisen-stock-work-skarn type W (scheelite and wolframite)-Bi-Mo deposit of Shizhuyuan, Dongpo, southern Hunan, China. In: Tungsten Geology Symposium, Jiangxi, China. Hepworth, J.V. and Y.H. Zhang (Eds.), ESCAP/RMRDC, Bandung, Indonesia and Geological Publishing House, Beijing, China, 503–519 (1982)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Gallagher, V. Geological and isotope studies of microtonalite-hosted W-Sn mineralization in SE Ireland. Mineral. Deposita 24, 19–28 (1989). https://doi.org/10.1007/BF00206717
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00206717