Abstract
Sulfide minerals in coal bed III at the Chinook Mine, Indiana, are pyrite, marcasite, and rarely sphalerite. Pyrite occurs as framboids concentrated mainly in exinite, as bands or lenses in vitrinite and clay partings, as cell fillings in fusinite, and in cleats. Marcasite normally occurs in association with clusters of pyrite framboids within micro-organic remains. Sphalerite occurs exclusively in fusinite associated with cleat pyrite. The iron sulfides, which are of authigenic origin, were formed during the biochemical stage of coalification during the accumulation and compaction of peat. The factor that limited their formation in such an environment was the availability and reactivity of iron. Chemical heterogeneity in the peat swamps where the sulfides formed existed even on a microscopic scale. The iron sulfides were commonly precipitated in localized micro-environments that were favorable for their formation. The metamorphic stage of coalification did not affect the iron sulfides significantly, although it may have been responsible for the recrystallization of pyrite framboids and minor deformation of pyrite in fusinite and its local mobilisation.
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References
Allen, E. T., Crenshaw, J. L.: Effect of temperature and acidity in the formation of marcasite (FeS2) and wurtzite (ZnS): A contribution to the genesis of unstable forms. Am. J. Sci. 38, 393–431 (1914)
— Johnston, J., Larsen, E. S.: The mineral sulfides of iron with crystallographic study. Am. J. Sci. 33, 169–236 (1912)
Baas-Becking, L. G., Kaplan, I. R., Moore, D.: Limits of the natural environment in terms of pH and oxidation-reduction potentials. J. Geol. 68, 243–284 (1960)
Berner, R. A.: Iron sulfides formed from aqueous solutions at low temperature and atmospheric pressures. J. Geol. 72, 292–306 (1964a)
— Stability fields of iron minerals in anaerobic marine sediments. J. Geol. 72, 826–834 (1964b)
— The synthesis of framboidal pyrite. Econ. Geol. 64, 383–384 (1969a)
— Migration of iron and sulfur within anaerobic sediments during early diagenesis. Am. J. Sci. 267, 19–42 (1969b)
— Sedimentary iron formation. Am. J. Sci. 268, 1–23 (1970)
— Principals of chemical sedimentology. New York: McGraw-Hill 1971
Bohor, B. F., Gluskoter, H. J.: Boron in illite as an indicator of paleosalinity of Illinois coals. J. Sed. Petrol. 43, 945–956 (1973)
Breger, I. A.: Geochemistry of coal. Econ. Geol. 68, 823–841 (1958)
Buerger, M. J.: The pyrite marcasite relation. Am. Mineral. 19, 37–61 (1934)
Carroll, D.: The role of clay minerals in the transport of iron. Geochim. Cosmochim. Acta 14, 1–27 (1958)
Christopher, J. P., Hegenauer, J. C., Saltman, P. D.: Iron metabolism as a function of chelation. In: Trace Element Metabolism in Animals, H. C. Hoekstra, J. W. Scittie, H. E. Ganther, W. Mertz, Eds., pp. 133–145. University Park Press 1974
Cooper, B.S., Murchison, D.G.: Organic geochemistry of coal. In: Organic Geochemistry, Methods and Results, G. Eglinton, M. T. G. Murphy, Eds., pp. 699–726. Berlin-Heidelberg-New York: Springer-Verlag 1969
Flaig, W.: Biochemical factors in coal formation. In: Coal and Coal Bearing Strata, D. Murchison, T. S. Westall, Eds., pp. 197–232. New York: American Elsevier 1968
Goldhaber, M. B., Kaplan, I. R.: The sedimentary sulfur cycle. In: The Sea, E. D. Goldberg, Ed., Vol. 5, pp. 569–655. New York: John Wiley 1974
Gluskoter, H. J., Hatch, J. R., Lindahl, P. C.: Zinc in coals of the Illinois basin. Abstract, Geological Society of America Meeting, Dallas, 637 (1973)
International Committee for Coal Petrology. International Handbook for Coal Petrography, 2nd ed. Centre National de La Recherche Scientifique, Paris (1963)
Krevelen, D. W. van: Geochemistry of coal. In: Organic Geochemistry, I. A. Breger, Ed, pp. 183–247. New York: Pergamon Press 1963
Love, L. G.: Further studies on microorganisms and the presence of syngenetic pyrite. Paleontology 5, 444–459 (1962)
— Micro-organic material with diagenetic pyrite from the lower Proterozoic Mount Isa shale and a carboniferous shale. Proc. Yorkshire Geol. Soc. 35, 273–309 (1965)
— Early diagenetic iron sulfide in recent sediments of the Wash (England). Sedimentology 9, 327–352 (1967)
— Sulfides of metals in recent sediments. In: Sedimentary Ores, Ancient and Modern, C. H. James, Ed., pp. 31–60. England: University of Leicester Spec. Pub. 1 1969
— Early diagenetic polyframboidal pyrite, primary and redeposited from the Wenlackian Denbigh grit group, Conway, North Wales, U.K. J. Sed. Petro. 41, 1038–1044 (1971)
— Amstutz, G. C.: Review of microscopic pyrite from the Devonian Chattanooga shale and Rammelsberg Banderz. Fortschr. Miner. 43, 273–309 (1966)
— Murray, J. W.: Biogenic pyrite in recent sediments of Christchurch Harbour, England. Am. J. Sci. 261, 433–448 (1963)
Neavel, R. C.: Petrographic and chemical composition of Indiana coals. Indiana Geol. Survey Bull. 22, 1–81 (1961)
Neves, R., Sullivan, J. J.: Modification of fossil spore exines associated with the presence of pyrite crystals. Micropaleontology 10, 443–452 (1964)
Ong, H., Ling, Swanson, V. E.: Adsorption of copper by peat lignite and bituminous coal. Econ. Geol. 61, 1214–1232 (1966)
Papunen, H.: Framboidal texture of the pyritic layer found in a peat bog in S. E. Finland. C. R.Soc. Geol. Finland 38, 117–125 (1966)
Powell, R. L.: Coal strip mined land in Indiana. Indiana Geol. Survey Special Report 6, 1–17 (1972)
Rickard, D. T.: The chemistry of iron sulfide formation at low temperature. Stockholm Contr. Geology 20, 67–95 (1969)
— Limiting conditions for synsedimentary sulfide ore formation. Econ. Geol. 68, 605–677 (1973)
— Kinetics and mechanisms of pyrite formation at low temperatures. Am. J. Sci. 275, 636–652 (1975)
Rising, A. B.: Phase relations among pyrite, marcasite and pyrhotite below 300°C. Ph. D. Dissertation, The Pennsylvania State University (1973)
Schopf, J. M.: Was decay important in origin of coal? J. Sed. Petrology 22, 61–69 (1952)
— Ehlers, E. G., Stiles, D. V., Birle, J. D.: Fossil iron bacteria preserved in pyrite. Proc. Amer. Phil. Soc. 109, 283–308 (1965)
Silverman, M. P., Ehrlich, H. L.: Microbal formation and degradation of minerals. In: “Advances in Applied Microbiology” 6, 153–206 (1964)
Smith, J. W., Batts, B. D.: The distribution and isotopic composition of sulfur in coal. Geochim. Cosmochim. Acta 38, 121–233 (1974)
Sweeney, R. E., Kaplan, I. R.: Pyrite framboidal formation: Laboratory synthesis and marine sediments. Econ. Geol. 68, 618–634 (1973)
Szalay, A., Szilagyi, M.: Accumulation of microelements in peat humic acids and coal. In: Advances in Organic Geochemistry, P. A. Schenck, I. Hovenaar, Eds., pp. 567–576. New York: Pergamon Press 1969
White, D.: Role of water conditions in the formation and differentiation of common (banded) coals. Econ. Geol. 28, 556–570 (1933)
Ziebold, T. O., Ogilvie, R. E.: An empirical method for electron microanalysis. Analytical Chemistry 36, 322–327 (1964)
Zobell, C. E.: Organic geochemistry of sulfur. In: Organic Geochemistry, I. A. Breger, Ed., pp. 543–578. New York: Pergamon Press 1963
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Boctor, N.Z., Kullerud, G. & Sweany, J.L. Sulfide minerals in Seelyville Coal III, Chinook Mine, Indiana. Mineral. Deposita 11, 249–266 (1976). https://doi.org/10.1007/BF00203077
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DOI: https://doi.org/10.1007/BF00203077