Skip to main content
Log in

Geochemical aspects of aluminium in forest soils in Galicia (N.W. Spain)

  • Published:
Biogeochemistry Aims and scope Submit manuscript

Abstract

The aqueous speciation of Al was studied in acid forest soils in N.W. Spain. Aluminum concentrations were 10–70 μmol L−1, with variable proportions oflabile, nonlabile, andacid-soluble Al. Almost all thelabile Al was found complexed with F, Al3+ concentrations being low. The importance of organic matter was seen in the formation of Al-organic complexes in the solid soil fraction and the presence of aqueous alumino-organic complexes in superficial horizons (umbric epipedons) rich in organic matter.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Adams F (1974) Soil solution. In: Carson EV (Ed) The Plant Root and its Environment (pp 441–481). Univ. Virginia Press, Charlottesville, Va

    Google Scholar 

  • Alvarez E & Calvo R (1991) Aplicacion de un metodo de fraccionamiento de especies aluminicas a soluciones de suelos de Galicia. Suelo y Planta (in press)

  • Bache BW (1986) Aluminium mobilization in soils and waters. J. of the Geological Society 143: 699–706

    Google Scholar 

  • Bardseley CE & Landcaster JD (1960) Determination of reserve sulfur and soluble sulfates in soils. Soil Soc. Am. Proc. 24: 265–268

    Google Scholar 

  • Bascomb CL (1986) Distribution of pyrophosphate extractable iron and organic carbon in soils of various groups. J. Soil Sci. 19: 251–256

    Google Scholar 

  • Binkley D, Driscoll CT, Allen HL, Schoeneberger P & McAvoy D (1989) Acidic deposition and forest soils. Context and case studies of the Southeastern United States. Springer-Verlag, New York

    Google Scholar 

  • Blakemore LC (1978) Exchange complex dominated by amorphous material (ECDAM). In: Smith GD (Ed) The Andisol proposal (pp 21–22). Soil Bureau, DSIR, New Zealand

    Google Scholar 

  • Buurman P (1988) pH-Dependent character of complexation in podzols. In: Righi D & Chauvel A (Eds) Podzols et Podzolisation (pp 181–186). INRA, Paris

    Google Scholar 

  • Calvo R, Paz A & Diaz-Fierros F (1979a) Nuevos datos sobre la influencia de la vegetaión en la formación del suelo en Galicia. III. Aportes por hojarasca, pérdidas por drenaje y escorrentía. An. Edaf. Agrobiol. 38: 1983–2000

    Google Scholar 

  • Calvo R, Paz A & Diaz-Fierros F (1979b) Contributión al estudio de los sistemas forestales: actividad biológica en suelos desarrollados bajo Q. robur y P. radiata. Trab. Comp. de Biología. 8: 145–154

    Google Scholar 

  • Calvo R, Fernandez ML & Veiga A (1987) Composición de la solución del suelo en medios naturales de Galicia. An. Edaf. Agrobiol. 46: 621–641

    Google Scholar 

  • Calvo R & Alvarez E (1987) Problemas de caracterización del complejo de cambio en suelos de Galicia. An. Edaf. Agrobiol. 46: 1221–1237

    Google Scholar 

  • Corey RB & Jackson MC (1953) Silicate analysis by rapid semichromochemical system. Anal. Chem. 25: 1233–1238

    Google Scholar 

  • David MB & Driscoll CT (1984) Aluminum speciation and equilibria in soil solutions of a Haplorthod in the Adirondack Mountains (New York, USA). Geoderma. 33: 297–318

    Google Scholar 

  • Dougan WK & Wilson AL (1974) The absorptiometric determination of aluminium in water. A comparison of some chromogenic reagents and development of an improved method. Analyst. 99: 413–430

    Google Scholar 

  • Driscoll CT (1984) A procedure for the fractionation of aqueous aluminum in dilute acidic waters. Int. J. Environ. Ana. Chem. 16: 267–283

    Google Scholar 

  • Driscoll CT (1985) Aluminum in acidic surface waters: Chemistry, Transport and Effects. Environmental Health Perspective, 63: 93–104

    Google Scholar 

  • Farmer VC & Fraser AR (1982) Chemical and colloidal stability of soils in the Al2O3 −1Fe2O3 SiO2 H2O system: Their role in podzolisation. J. Soil Sci. 33: 737–742

    Google Scholar 

  • Garcia-Rodeja E & Macias F (1984) Caracterización de suelos ácidos (Podzoles, Andosoles-Suelos alumínicos) de Galicia. Relación con los procesos edafogeoquímicos. Actas 1° Congr. Nac. Ciencia del Suelo. Madrid: 589–602

  • Garcia-Rodeja E, Silva B & Macias F (1987) Andosols developed from non-volcanic materials in Galicia, N.W. Spain. Journal of Soil Science. 38: 573–591

    Google Scholar 

  • Hargrove W & Thomas GW (1981). Extraction of aluminum from aluminum-organic matter complexes. Soil Sci. Soc. Am. J. 45: 151–153

    Google Scholar 

  • Hem JD & Roberson CE (1967) Form and stability of aluminum hydroxide complexes in dilute solutions. U.S. Geol. Surv. Water Suppl. Pap. 1827-A

  • Juo AS & Kamprath EJ (1979) Copper chloride as an extract for estimating the potentially reactive aluminum pool in acid soils. Soil Sci. Soc. Am. J. 43: 35–38

    Google Scholar 

  • Kharaka Y, Gunter W, Aggarwal P, Perkins E & Debraal J (1989) Solmineq.88: A Computer Program for Geochemical Modelling of water-Rock interactions. U.S. Geological Survey. Menlo Park, California

    Google Scholar 

  • Martinez A (1987) Zonas agroecológicas de Galicia. Zonas climáticas FAO. An. Edaf. Agrobiol. 46: 521–538

    Google Scholar 

  • Merino A, Monterroso C & Garcia-Rodeja E (1989) Contenido de azufre total en muestras superficiales de suelos de la provincia de La Coruña. An. Edaf. Agrob. 48: 615–626

    Google Scholar 

  • Pratt PF & Bair FL (1961) A comparison of three reagents for the extraction of aluminum from soils. Soil Sci. 9: 357–359

    Google Scholar 

  • Robie RA, Hemingway BS & Fisher JR (1978) Thermodynamic properties of minerals and related substances at 298. 15K and 1 bar. U.S. Geol. Surv. Bull. 1452

  • Romero R, García C & Macías F (1991) Utilización del test de la formamida en la identificación de los filosilicatos 1:1 de suelos de la provincia de La Coruña. Suelo y Planta 1: 33–48

    Google Scholar 

  • Soil Conservation Service (1972) Soil Survey laboratory methods and procedures for collecting soil samples. USDA, Washington DC

    Google Scholar 

  • Soil Survey Staff (1990) Keys to Soil Taxonomy, fourth edition. SMSS technical monograph.6. Blacksburg, Virginia

  • Ugolini FC & Dahlgren R (1987) The mechanism of podzolization as revealed by soil solution studies. In: Righi D & Chauvel A (Eds) Podzols et Podzolization (pp 195–203). INRA

  • Urrutia M, Garcia-Rodeja E & Macias F (1988) Aplicación de disoluciones no tamponadas para la extracción de Al “activo” ligado a la materia orgánica en suelos de Galicia. An. Edaf. Agrobiol. 47: 1289–1301

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Alvarez, E., Martinez, A. & Calvo, R. Geochemical aspects of aluminium in forest soils in Galicia (N.W. Spain). Biogeochemistry 16, 167–180 (1992). https://doi.org/10.1007/BF00002817

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00002817

Key words

Navigation