Abstract
The aqueous speciation of Al was studied in acid forest soils in N.W. Spain. Aluminum concentrations were 10–70 μmol L−1, with variable proportions oflabile, nonlabile, andacid-soluble Al. Almost all thelabile Al was found complexed with F−, Al3+ concentrations being low. The importance of organic matter was seen in the formation of Al-organic complexes in the solid soil fraction and the presence of aqueous alumino-organic complexes in superficial horizons (umbric epipedons) rich in organic matter.
Similar content being viewed by others
References
Adams F (1974) Soil solution. In: Carson EV (Ed) The Plant Root and its Environment (pp 441–481). Univ. Virginia Press, Charlottesville, Va
Alvarez E & Calvo R (1991) Aplicacion de un metodo de fraccionamiento de especies aluminicas a soluciones de suelos de Galicia. Suelo y Planta (in press)
Bache BW (1986) Aluminium mobilization in soils and waters. J. of the Geological Society 143: 699–706
Bardseley CE & Landcaster JD (1960) Determination of reserve sulfur and soluble sulfates in soils. Soil Soc. Am. Proc. 24: 265–268
Bascomb CL (1986) Distribution of pyrophosphate extractable iron and organic carbon in soils of various groups. J. Soil Sci. 19: 251–256
Binkley D, Driscoll CT, Allen HL, Schoeneberger P & McAvoy D (1989) Acidic deposition and forest soils. Context and case studies of the Southeastern United States. Springer-Verlag, New York
Blakemore LC (1978) Exchange complex dominated by amorphous material (ECDAM). In: Smith GD (Ed) The Andisol proposal (pp 21–22). Soil Bureau, DSIR, New Zealand
Buurman P (1988) pH-Dependent character of complexation in podzols. In: Righi D & Chauvel A (Eds) Podzols et Podzolisation (pp 181–186). INRA, Paris
Calvo R, Paz A & Diaz-Fierros F (1979a) Nuevos datos sobre la influencia de la vegetaión en la formación del suelo en Galicia. III. Aportes por hojarasca, pérdidas por drenaje y escorrentía. An. Edaf. Agrobiol. 38: 1983–2000
Calvo R, Paz A & Diaz-Fierros F (1979b) Contributión al estudio de los sistemas forestales: actividad biológica en suelos desarrollados bajo Q. robur y P. radiata. Trab. Comp. de Biología. 8: 145–154
Calvo R, Fernandez ML & Veiga A (1987) Composición de la solución del suelo en medios naturales de Galicia. An. Edaf. Agrobiol. 46: 621–641
Calvo R & Alvarez E (1987) Problemas de caracterización del complejo de cambio en suelos de Galicia. An. Edaf. Agrobiol. 46: 1221–1237
Corey RB & Jackson MC (1953) Silicate analysis by rapid semichromochemical system. Anal. Chem. 25: 1233–1238
David MB & Driscoll CT (1984) Aluminum speciation and equilibria in soil solutions of a Haplorthod in the Adirondack Mountains (New York, USA). Geoderma. 33: 297–318
Dougan WK & Wilson AL (1974) The absorptiometric determination of aluminium in water. A comparison of some chromogenic reagents and development of an improved method. Analyst. 99: 413–430
Driscoll CT (1984) A procedure for the fractionation of aqueous aluminum in dilute acidic waters. Int. J. Environ. Ana. Chem. 16: 267–283
Driscoll CT (1985) Aluminum in acidic surface waters: Chemistry, Transport and Effects. Environmental Health Perspective, 63: 93–104
Farmer VC & Fraser AR (1982) Chemical and colloidal stability of soils in the Al2O3 −1Fe2O3 −SiO2 −H2O system: Their role in podzolisation. J. Soil Sci. 33: 737–742
Garcia-Rodeja E & Macias F (1984) Caracterización de suelos ácidos (Podzoles, Andosoles-Suelos alumínicos) de Galicia. Relación con los procesos edafogeoquímicos. Actas 1° Congr. Nac. Ciencia del Suelo. Madrid: 589–602
Garcia-Rodeja E, Silva B & Macias F (1987) Andosols developed from non-volcanic materials in Galicia, N.W. Spain. Journal of Soil Science. 38: 573–591
Hargrove W & Thomas GW (1981). Extraction of aluminum from aluminum-organic matter complexes. Soil Sci. Soc. Am. J. 45: 151–153
Hem JD & Roberson CE (1967) Form and stability of aluminum hydroxide complexes in dilute solutions. U.S. Geol. Surv. Water Suppl. Pap. 1827-A
Juo AS & Kamprath EJ (1979) Copper chloride as an extract for estimating the potentially reactive aluminum pool in acid soils. Soil Sci. Soc. Am. J. 43: 35–38
Kharaka Y, Gunter W, Aggarwal P, Perkins E & Debraal J (1989) Solmineq.88: A Computer Program for Geochemical Modelling of water-Rock interactions. U.S. Geological Survey. Menlo Park, California
Martinez A (1987) Zonas agroecológicas de Galicia. Zonas climáticas FAO. An. Edaf. Agrobiol. 46: 521–538
Merino A, Monterroso C & Garcia-Rodeja E (1989) Contenido de azufre total en muestras superficiales de suelos de la provincia de La Coruña. An. Edaf. Agrob. 48: 615–626
Pratt PF & Bair FL (1961) A comparison of three reagents for the extraction of aluminum from soils. Soil Sci. 9: 357–359
Robie RA, Hemingway BS & Fisher JR (1978) Thermodynamic properties of minerals and related substances at 298. 15K and 1 bar. U.S. Geol. Surv. Bull. 1452
Romero R, García C & Macías F (1991) Utilización del test de la formamida en la identificación de los filosilicatos 1:1 de suelos de la provincia de La Coruña. Suelo y Planta 1: 33–48
Soil Conservation Service (1972) Soil Survey laboratory methods and procedures for collecting soil samples. USDA, Washington DC
Soil Survey Staff (1990) Keys to Soil Taxonomy, fourth edition. SMSS technical monograph.6. Blacksburg, Virginia
Ugolini FC & Dahlgren R (1987) The mechanism of podzolization as revealed by soil solution studies. In: Righi D & Chauvel A (Eds) Podzols et Podzolization (pp 195–203). INRA
Urrutia M, Garcia-Rodeja E & Macias F (1988) Aplicación de disoluciones no tamponadas para la extracción de Al “activo” ligado a la materia orgánica en suelos de Galicia. An. Edaf. Agrobiol. 47: 1289–1301
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Alvarez, E., Martinez, A. & Calvo, R. Geochemical aspects of aluminium in forest soils in Galicia (N.W. Spain). Biogeochemistry 16, 167–180 (1992). https://doi.org/10.1007/BF00002817
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00002817