Abstract
The nanocrystalline zinc ferrite (ZnFe2 O 4) thin films were grown on the fused quartz substrate using pulsed laser deposition. The effects of atmospheric conditions on structural, magnetic, and morphological properties have been systematically studied using X-ray diffraction, vibrating sample magnetometry, and atomic force microscopy. The films showed textured growth of zinc ferrite for the substrate temperatures at ≥ 600 °C irrespective of the ambient environment. Interestingly, thin films of zinc ferrite showed a magnetic hysteresis loop in contrast to the paramagnetic nature of their bulk counterpart. The value of saturation magnetization (4π M s) increased from 130 to 360 G when the substrate temperature was increased from room temperature (RT) to 800 °C in the oxygen atmosphere. In the absence of oxygen pressure, the value of 4π M s is observed to be 330 G for the film deposited at RT and found to increase to a value of 670 G when the film is deposited at 400 °C and the maximum value of 2580 G is observed for the film deposited at 700 °C. However, the value of 4π M s of 800 °C dropped down to 2000 G.
Similar content being viewed by others
References
Cullity, B.D.: Introduction to magnetic materials. Addison-Wesley, New York (1972)
Gupta, R.K., Yakuphanoglu, F.: Epitaxial growth of tin ferrite thin films using pulsed laser deposition technique. J. Alloys. Compd. 509, 9523–9527 (2011)
Sultan, M., Singh, R.: FMR studies on nanocrystalline zinc ferrite thin film. J. Phys.: Conf. Ser. 200, 072090(1)–072090(4) (2010)
Nakashima, S., Fujita, K., Tanaka, K., Hirao, K.: High magnetization and the high-temperature superparamagnetic transition with intercluster interaction in disordered zinc ferrite thin film. J. Phys.: Condens. Matter 17(1), 137–49 (2005)
Sultan, M., Singh, R.: Magnetic and optical properties of rf-sputtered zinc ferrite thin films. J. Appl. Phys. 105, 07A512–07A512-3 (2009)
Bohra, M., Prasad, S., Kumar, N., Misra, D.S., Sahoo, S.C., Venkataramani, N., Krishnan, R.: Large room temperature magnetization in nanocrystalline zinc ferrite thin films. Appl. Phys. Lett. 88, 262506–262508 (2006)
Wakiya, N., Muraoka, K., Kadowaki, T., Kiguchi, T., Mizutani, N., Suzuki, H., Shinozaki, K.: Preparation of ferromagnetic zinc-ferrite thin film by pulsed laser deposition in the magnetic field. J. Magn. Magn. Mater. 310, 2546–2548 (2007)
Ogale, S.B., Nawathey, R.: Deposition of zinc ferrite (ZnxFe3−x O 4) films by pulsed laser evaporation process. J. Appl. Phys. 65, 1367–1369 (1989)
Koing, U., Bertaut, E.F., Gros, Y., Mitrikov, M., Chol, G.: Models of the magnetic structure of zinc ferrite. Solid State Commun. 8(10), 759–764 (1970)
Dash, J., Prasad, S., Venkataramani, N., Krishnan, R., Kishan, P., Kumar, N., Date, S.K., Kulkarni, S.D.: Study of magnetization and crystallization in sputter deposited LiZn ferrite thin films. J. Appl. Phys. 86, 3303–3311 (1999)
Desai, M., Dash, J., Samajdar, I., Venkataramani, N., Prasad, S., Kishan, P., Kumar, N.: Annealing induced structural change in sputter deposited copper ferrite thin films and its impact on magnetic properties. J. Appl. Phys. 91(4), 2220–2227 (2002)
Singh, S.: Ph.D. Thesis, Investigations on magnetodielectric effect in BaTiO3/AFe2O4[A = Fe2+, Zn2+] core/shell nanoparticles and studies of PLD grown zinc ferrite thin films. Department of Physics, MNNIT Allahabad (2015)
Caltun, O.F.: Pulsed laser deposition of Ni-Zn ferrite thin films. J. Optoelectron. Adv. Mater. 7(2), 739–744 (2005)
Joseph, J., Tangsali, R.B., Choudhary, R.J., Phase, D.M., Ganeshan, V.: Magnetic properties of textured nanocrystalline Mn-Zn ferrite thin films fabricated by pulsed laser deposition. Int. J. Thin Fil. Sci. Tec. 3(3), 81–87 (2014)
Joseph, J., Tangsali, R.B., Pillai, V.P.M., Choudhary, R.J., Phase, D.M., Ganeshan, V.: Microstructure and magnetic properties of patterned nano crystalline zinc ferrite thin film fabricated by pulse laser deposition. Mater. Res. Bull. 61, 475–480 (2014)
Chikazumi, Charap, S.H.: Physics of magnetism. Wiley, New York (1964)
Kumar, N.: Ph.D. Thesis. Fabrication and optimization of pulsed laser deposition system and study of YIG and SrM ferrite thin films. Department of Physics, IIT Bombay (2005)
Acknowledgments
The authors acknowledge the Centre for Interdisciplinary Research at MNNIT Allahabad for the experimental facilities. NK also acknowledges DST for the financial support (SR/S2/HEP-07/2010).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jha, A., Kumar, N., Sahni, M. et al. Magnetization in Nanocrystalline PLD Zinc Ferrite Thin Films Deposited on Fused Quartz Substrate. J Supercond Nov Magn 31, 107–116 (2018). https://doi.org/10.1007/s10948-017-4177-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-017-4177-3