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Green synthesis strategy of chabazite membrane and its CO2/N2 separation performance

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Abstract

In this study, non-poisonous and eco-friendly raw chemicals were employed to synthesize a chabazite membrane by seed-induced secondary growth method. With an assistance of porous alumina ceramics support, the prepared membrane was utilized for excellent CO2/N2 separation. The results of structural and morphological characterization of the synthetic chabazite membrane signify that a dense and consistent membrane layer of chabazite was successfully formed on the surface of the alumina ceramic support. The single-component gas permeation experiment was carried out on the synthetic chabazite membrane, and the results showed that the calculated ideal CO2 and N2 separation coefficient reached 3.5. Whereas, the separation experiment of the mixed components showed the CO2 and N2 separation coefficient of 4.05 which might be due to the competition of diffusion between the mixed gas molecules and the selective adsorption characteristics of chabazite. At last, the separation stability experiments results show that the chabazite membrane prepared in this study owns excellent cycle stability and excellent separation performance. This demonstrates that chabazite membrane is an outstanding potential membrane for the separation of CO2 in industrial flue gas.

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Acknowledgements

This work was funded by the National Natural Science Foundation of China (No. 51904073, No.22078054), National Key Research and Development Project (No. 2019YFC1905200), the Natural Science Foundation of Liaoning Province (No. 2020-BS-053), the Postdoctoral Research Foundation of Northeastern University in China (No. 20190304) and the Fundamental Research Funds for the Central Universities (N182508027).

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Authors and Affiliations

  1. State Environmental Protection Key Laboratory of Eco-Industry, Northeastern University, Shenyang, 110819, China

    He Gong, Nitin Goyal, Liying Liu, Yisong Wang, Xin Fang, He Jia, Gang Li & Tao Du

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  1. He Gong
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  2. Nitin Goyal
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  3. Liying Liu
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  4. Yisong Wang
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  5. Xin Fang
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  7. Gang Li
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Correspondence to Liying Liu or Tao Du.

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Gong, H., Goyal, N., Liu, L. et al. Green synthesis strategy of chabazite membrane and its CO2/N2 separation performance. J Porous Mater 28, 1401–1410 (2021). https://doi.org/10.1007/s10934-021-01069-1

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