Abstract
Conventional neutron activation procedures rely on cycles of equal length to test samples of fluorspar concentrate. This paper proposes a new procedure using “asymmetrical” cycles, in which the duration of the first cycle is different from that of the subsequent activation cycles, which are conducted once the radioactive concentration of the element of interest has been partly reduced through radioactive decay. A comparison is made between the two procedures, and the advantages of the new technique over the conventional one are examined.
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References
Filby R.H.: Isotopic and nuclear analytical techniques in biological systems: a critical study. Neutron activation analysis. Pure Appl. Chem. 67(11), 1929–1941 (1995)
Maki Y., Nojiri T., Masilungan B.A.: The determination of fluorine by cyclic activation analysis method using 241Am-Be neutron source. Radioisotopes 23, 149–154 (1974)
Nonie S.E.B., Randle K., Blackband A.G.: Development of a computer-based system for fast neutron cyclic activation analysis. J. Radioanal. Nucl. Chem. 167, 89–95 (1993)
Croudace I.W., Randle K.: A rapid and non-destructive method of fluorine determination using fast-neutron activation analysis. Chem. Geol. 67, 165–170 (1988)
Croudace I.W.: Fluorine abundances of twenty nine geological and other reference samples using fast-neutron activation analysis. Geostand. Newsl. 127(2), 127–218 (1993)
Chatt A., DeSilva K.N., Holzbecher J., Stuart D.C., Tout R.E., Ryan D.E.: Cyclic neutron activation analysis of biological and metallurgical samples. Can. J. Chem. 59, 1660–1664 (1981)
M.A. Rey-Ronco, Desarrollo de unmétodo rápido basado en técnicas de activación neutrónica para la determinación del contenido en flúor de muestras de mineral de fluorita. Universidad de Oviedo. Doctoral thesis. Avalaible from http://www.tesisenred.net/TDR-0802107-133201/index_cs.html (2007)
Alonso-Sánchez T., Rey-Ronco M.A., Castro-García M.P.: A neutron activation technique for the analysis for fluorine in fluorspar samples. Int. J. Miner. Process. 94, 1–13 (2011)
A. Sonzogni, Nucl. Struct. Decay Data (NuDat). Available from www.nndc.bnl.gov (2011)
M. Herman, Experimental nuclear reaction data (EXFOR / CSISRS). Available from www.nndc.bnl.gov (2007)
Spyrou N.M.: Cyclic activation analysis a review. J. Radioanal. Chem. 61, 211–242 (1981)
Givens W.W., Mills W.R, Caldwell R.L.: Cyclic activation analysis. Nucl. Instrum. Methods 80, 95–103 (1970)
X. Hou, in Cyclic activation analysis, ed. by R.A. Meyers. Encyclopedia of analytical chemistry (John Wiley & Sons Ltd, Wiley, Chichester, 2000), pp. 12447–12459
Rey-Ronco M.A., Alonso-Sánchez T., Castro-García M.P.: Mathematical study to improve the sensitivity in the neutron activation analysis of fluorspar. J. Math. Chem. 48, 165–174 (2010)
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Alonso-Sánchez, T., Rey-Ronco, M.A., Castro-García, M.P. et al. Design for an asymmetrical cyclic neutron activation process for determining fluorite grade in fluorspar concentrate. J Math Chem 50, 394–409 (2012). https://doi.org/10.1007/s10910-011-9918-0
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DOI: https://doi.org/10.1007/s10910-011-9918-0